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Group 4 element
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===Physical=== The trends in group 4 follow those of the other early d-block groups and reflect the addition of a filled f-shell into the core in passing from the fifth to the sixth period. All the stable members of the group are silvery [[refractory metal]]s, though impurities of [[carbon]], [[nitrogen]], and oxygen make them brittle.<ref name=Greenwood956>Greenwood and Earnshaw, pp. 956–8</ref> They all crystallize in the [[hexagonal close-packed]] structure at room temperature,<ref name=Greenwood946>Greenwood and Earnshaw, pp. 946–8</ref> and rutherfordium is expected to do the same.<ref name=hcp>{{cite journal|doi=10.1103/PhysRevB.84.113104|title=First-principles calculation of the structural stability of 6d transition metals|year=2011|last1=Östlin|first1=A.|last2=Vitos|first2=L.|journal=Physical Review B|volume=84|issue=11|page=113104|bibcode=2011PhRvB..84k3104O }}</ref> At high temperatures, titanium, zirconium, and hafnium transform to a [[body-centered cubic]] structure. While they are better conductors of heat and electricity than their group 3 predecessors, they are still poor compared to most metals. This, along with the higher melting and boiling points, and enthalpies of fusion, vaporization, and atomization, reflects the extra d electron available for metallic bonding.<ref name=Greenwood946/> The table below is a summary of the key physical properties of the group 4 elements. The four question-marked values are extrapolated.<ref name=Haire>{{cite book| title=The Chemistry of the Actinide and Transactinide Elements| editor1-last=Morss|editor2-first=Norman M.| editor2-last=Edelstein| editor3-last=Fuger|editor3-first=Jean| last1=Hoffman|first1=Darleane C. |last2=Lee |first2=Diana M. |last3=Pershina |first3=Valeria |chapter=Transactinides and the future elements| publisher= [[Springer Science+Business Media]]| year=2006| isbn=1-4020-3555-1| location=Dordrecht, The Netherlands| edition=3rd| ref=CITEREFHaire2006}}</ref> {| class="wikitable centered" style="text-align:center;" |+Properties of the group 4 elements| Properties of the group 4 elements ! Name ! Ti, [[titanium]] ! Zr, [[zirconium]] ! Hf, [[hafnium]] ! Rf, [[rutherfordium]] |- | style="background:lightgrey; text-align:left;"|[[Melting point]] | 1941 K (1668 °C) || 2130 K (1857 °C) || 2506 K (2233 °C) || 2400 K (2100 °C)? |- | style="background:lightgrey; text-align:left;"|[[Boiling point]] | 3560 K (3287 °C) || 4682 K (4409 °C) || 4876 K (4603 °C) || 5800 K (5500 °C)? |- | style="background:lightgrey; text-align:left;"|[[Density]] | 4.507 g·cm<sup>−3</sup> || 6.511 g·cm<sup>−3</sup> || 13.31 g·cm<sup>−3</sup> || 17 g·cm<sup>−3</sup>? |- | style="background:lightgrey; text-align:left;"|Appearance | silver metallic || silver white || silver gray|| ? |- | style="background:lightgrey; text-align:left;"|[[Atomic radius]] | 140 pm || 155 pm || 155 pm || 150 pm? |} ====Titanium==== {{transcluded section|Titanium}} {{#section:Titanium|properties}} ====Zirconium==== {{transcluded section|Zirconium}} {{#section:Zirconium|properties}} ====Hafnium==== {{transcluded section|Hafnium}} {{#section:Hafnium|properties}} ====Rutherfordium==== {{transcluded section|Rutherfordium}} {{#section:Rutherfordium|properties}}
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