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Kraft process
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===Cooking=== The wood chips are then cooked in pressurized digesters. Some digesters operate in a batch manner and some in a continuous process. Digesters producing 1,000 tonnes or more of pulp per day are common, with the largest producing more than 3,500 tonnes per day.<ref name="epa">{{cite web |url = https://nepis.epa.gov/Exe/ZyPURL.cgi?Dockey=9100PTP2.txt |title=Pollution Prevention Technologies for the Bleached Kraft Segment of the U.S. Pulp and Paper Industry|access-date=2022-02-06 |last=Woodman |first=Jocelyn |year=1993 |publisher=U.S. Environmental Protection Agency|page = 66}}</ref> Typically, delignification requires around two hours<ref>{{cite web |url=http://biorefinery.utk.edu/technical_reviews/Basics%20of%20Kraft%20Pulping.pdf |title=Basics of Kraft Pulping |publisher=University of Tennessee Knoxville - Department of Chemical and Biomolecular Engineering |access-date=2021-10-23 |archive-date=2021-10-23 |archive-url=https://web.archive.org/web/20211023194838/http://biorefinery.utk.edu/technical_reviews/Basics%20of%20Kraft%20Pulping.pdf |url-status=dead }}</ref> at {{convert|170|to|176|Β°C|Β°F}}. Under digesting conditions, lignin and [[hemicellulose]] degrade to give fragments that are soluble in the strongly basic liquid. The solid pulp (about 50% by weight of the dry wood chips) is collected and washed. At this point the pulp is known as ''brown stock'' because of its color. The combined liquids, known as [[black liquor]] (because of its color), contain lignin fragments, [[carbohydrate]]s from the breakdown of hemicellulose, [[sodium carbonate]], [[sodium sulfate]] and other inorganic salts. [[Image:KraftEq.png|250px|thumb|right|net reaction in depolymerization of lignin by SH<sup>β</sup> (Ar = [[aromaticity|aryl]], R = [[alkyl]] groups).]] One of the main chemical reactions that underpin the kraft process is the scission of ether bonds by the [[nucleophilic]] [[sulfide]] (S<sup>2β</sup>) or [[bisulfide]] (HS<sup>β</sup>) ions.<ref name="eero"/>
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