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Atomic units
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== Units == Three of the defining constants (reduced Planck constant, elementary charge, and electron rest mass) are atomic units themselves β of [[action (physics)|action]],<ref>{{cite web |title=atomic unit of action |work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?Ahbar }}</ref> [[electric charge]],<ref>{{cite web |title=atomic unit of charge |work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?Ae }}</ref> and [[mass]],<ref>{{cite web |title=atomic unit of mass |url=http://physics.nist.gov/cgi-bin/cuu/Value?Ame |work={{harvnb|CODATA}} }}</ref> respectively. Two named units are those of [[length]] ([[Bohr radius]] {{tmath|1= a_0 \equiv 4 \pi \epsilon_0 \hbar^2 / m_\text{e} e^2 }}) and [[energy]] ([[hartree]] {{tmath|1= E_\text{h} \equiv \hbar^2 / m_\text{e} a_0^2 }}). {|class="wikitable" |+ Defined atomic units |- !scope="col"| Atomic unit of !scope="col"| Expression !scope="col"| Value in SI units !scope="col"| Other equivalents |- | [[charge density|electric charge density]] || <math> e/a_0^3 </math> | {{physconst|auecd|ref=no}} <ref> {{cite web |title=atomic unit of charge density |work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?aucd }}</ref> | |- | [[electric current]] || <math> e E_\text{h} / \hbar </math> | {{physconst|aucur|ref=no}} <ref> {{cite web |title=atomic unit of current |work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?aucur }}</ref> | |- | [[electric charge]] || <math>e</math> | {{physconst|auec|ref=no}} <ref> {{cite web |title=atomic unit of charge | work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?Ae }}</ref> | |- | [[electric dipole moment]] || <math> e a_0 </math> | {{physconst|auedm|ref=no}} <ref> {{cite web |title=atomic unit of electric dipole moment |work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?auedm }}</ref> | {{math|β}} {{val|2.541746473|u=[[debye|D]]}} |- | [[electric quadrupole]] moment || <math> e a_0^2 </math> | {{physconst|aueqm|ref=no}} <ref> {{cite web |title=atomic unit of electric quadrupole moment |work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?aueqm }}</ref> | |- | [[electric potential]] || <math> E_\text{h} / e </math> | {{physconst|auepot|ref=no}} <ref> {{cite web |title=atomic unit of electric potential |work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?auep }}</ref> | |- | [[electric field]] || <math>E_\text{h} / e a_0 </math> | {{physconst|auef|ref=no}} <ref> {{cite web |title=atomic unit of electric field |work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?auefld }}</ref> | |- | [[electric field gradient]] || <math>E_\text{h} / e a_0^2 </math> | {{physconst|auefg|ref=no}} <ref> {{cite web |title=atomic unit of electric field gradient |work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?auefg }}</ref> | |- | [[permittivity]] || <math> e^2 / a_0 E_\text{h} </math> | {{physconst|auperm|ref=no}} <ref name="auperm"> {{cite web |title=atomic unit of permittivity |work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?auperm }}</ref> | {{tmath|1= 4 \pi \epsilon_0 }} |- | [[electric polarizability]] || <math> e^2 a_0^2 / E_\text{h} </math> | {{physconst|auepol|ref=no}} <ref> {{cite web |title=atomic unit of electric polarizability |work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?auepol }}</ref> | |- | 1st [[hyperpolarizability]] || <math>e^3 a_0^3 / E_\text{h}^2</math> | {{physconst|au1hypol|ref=no}} <ref> {{cite web |title=atomic unit of 1st hyperpolarizability | work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?auhypol }}</ref> | |- | 2nd hyperpolarizability || <math>e^4 a_0^4 / E_\text{h}^3</math> |{{physconst|au2hypol|ref=no}} <ref> {{cite web |title=atomic unit of 2nd hyperpolarizability | work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?au2hypol }}</ref> | |- | [[magnetic dipole moment]] || <math> \hbar e / m_\text{e} </math> | {{physconst|aumdm|ref=no}} <ref> {{cite web |title=atomic unit of magnetic dipole moment |work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?aumdm }}</ref> | {{tmath|1= 2 \mu_\text{B} }} |- | [[magnetic flux density]] || <math> \hbar/e a_0^2 </math> | {{physconst|aumfd|ref=no}} <ref> {{cite web |title=atomic unit of magnetic flux density |work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?aumfd }}</ref> | {{math|β}} {{val|2.3505|e=9|ul=G}} |- | [[magnetizability]] || <math> e^2 a_0^2 / m_\text{e}</math> | {{physconst|aumag|ref=no}} <ref> {{cite web |title=atomic unit of magnetizability |work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?aumag }}</ref> | |- | [[action (physics)|action]] || <math>\hbar</math> | {{physconst|auact|ref=no}} <ref> {{cite web |title=atomic unit of action | work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?Ahbar }}</ref> | |- | [[energy]] || <math> E_\text{h} </math> | {{physconst|auener|ref=no}} <ref> {{cite web |title=atomic unit of energy |work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?Ahr }}</ref> | {{tmath|1= 2 h c R_\infty }}, {{tmath|1= \alpha^2 m_\text{e} c^2 }}, {{val|27.211386245988|(53)|ul=eV}} <ref> {{cite web |title=Hartree energy in eV |work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?hrev }}</ref> |- | [[force]] || <math>E_\text{h} / a_0 </math> | {{physconst|auforce|ref=no}} <ref> {{cite web |title=atomic unit of force |work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?auforce }}</ref> | {{val|82.387|u=nN}}, {{val|51.421|u=eVΒ·Γ <sup>β1</sup>}} |- | [[length]] || <math> a_0 </math> | {{physconst|aulen|ref=no}} <ref> {{cite web |title=atomic unit of length |work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?Abohrrada0 }}</ref> | {{tmath|1= \hbar / \alpha m_\text{e} c }}, {{val|0.529177|ul=Γ }} |- | [[mass]] || <math>m_\text{e}</math> | {{physconst|aumass|ref=no}} <ref> {{cite web |title=atomic unit of mass |work={{harvnb|CODATA}} | url=http://physics.nist.gov/cgi-bin/cuu/Value?Ame }}</ref> | |- | [[momentum]] || <math> \hbar/a_0 </math> | {{physconst|aumom|ref=no}} <ref> {{cite web |title=atomic unit of momentum |work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?aumom }}</ref> | |- | [[time]] || <math>\hbar / E_\text{h}</math> | {{physconst|autime|ref=no}} <ref> {{cite web |title=atomic unit of time |work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?aut }}</ref> | |- | [[velocity]] || <math> a_0 E_\text{h} / \hbar </math> | {{physconst|auvel|ref=no}} <ref> {{cite web |title=atomic unit of velocity |work={{harvnb|CODATA}} |url=http://physics.nist.gov/cgi-bin/cuu/Value?auvel }}</ref> | {{tmath|1= \alpha c }} |- | colspan=4 | {{tmath|1= c }}: [[speed of light]], {{tmath|1= \epsilon_0 }}: [[vacuum permittivity]], {{tmath|1= R_\infty }}: [[Rydberg constant]], {{tmath|1= h }}: [[Planck constant]], {{tmath|1= \alpha }}: [[fine-structure constant]], {{tmath|1= \mu_\text{B} }}: [[Bohr magneton]], {{math|β}}: ''correspondence'' |- |}
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