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Chloroform
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===Deuterochloroform=== {{Main|Deuterated chloroform}} [[Deuterated chloroform]] is an [[isotopologue]] of chloroform with a single [[deuterium]] atom. {{chem2|CDCl3}} is a common solvent used in [[NMR spectroscopy]]. Deuterochloroform is produced by the reaction of [[hexachloroacetone]] with [[heavy water]].<ref>{{cite journal |last1=Paulsen |first1=P. J. |last2=Cooke |first2=W. D. |title=Preparation of Deuterated Solvents for Nuclear Magnetic Resonance Spectrometry. |journal=Analytical Chemistry |date=1 September 1963 |volume=35 |issue=10 |page=1560 |doi=10.1021/ac60203a072}}</ref> The haloform process is now obsolete for production of ordinary chloroform. Deuterochloroform can also be prepared by reacting [[sodium deuteroxide]] with [[chloral hydrate]].<ref>{{cite journal|doi=10.1021/ja01314a058|title=Chloroform-d (Deuteriochloroform)1|journal=Journal of the American Chemical Society|volume=57|issue=11|pages=2236β2237|year=1935|last1=Breuer|first1=F. W.}}</ref><ref>{{cite journal|doi=10.1021/jo01030a526|title=A Convenient Preparation of Chloroform-d1|journal=The Journal of Organic Chemistry|volume=29|issue=7|pages=2045β2046|year=1964|last1=Kluger|first1=Ronald}}</ref>
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