Open main menu
Home
Random
Recent changes
Special pages
Community portal
Preferences
About Wikipedia
Disclaimers
Incubator escapee wiki
Search
User menu
Talk
Dark mode
Contributions
Create account
Log in
Editing
Gas chromatography
(section)
Warning:
You are not logged in. Your IP address will be publicly visible if you make any edits. If you
log in
or
create an account
, your edits will be attributed to your username, along with other benefits.
Anti-spam check. Do
not
fill this in!
===Gas adsorption chromatography precursors=== German physical chemist [[Erika Cremer]] in 1947 together with Austrian graduate student Fritz Prior developed what could be considered the first gas chromatograph that consisted of a carrier gas, a column packed with silica gel, and a thermal conductivity detector. They exhibited the chromatograph at ACHEMA in Frankfurt, but nobody was interested in it.<ref name="Ettre">{{cite book |last1=Ettre |first1=Leslie S. |title=Chapters in the evolution of chromatography |date=2008 |publisher=Imperial College Press |location=London |isbn=978-1860949432}}</ref> N.C. Turner with the Burrell Corporation introduced in 1943 a massive instrument that used a charcoal column and mercury vapors. Stig Claesson of [[Uppsala University]] published in 1946 his work on a charcoal column that also used mercury.<ref name="Ettre"/> Gerhard Hesse, while a professor at the [[University of Marburg]]/Lahn decided to test the prevailing opinion among German chemists that molecules could not be separated in a moving gas stream. He set up a simple glass column filled with starch and successfully separated bromine and iodine using nitrogen as the carrier gas. He then built a system that flowed an inert gas through a glass condenser packed with silica gel and collected the eluted fractions.<ref name="Ettre"/> Courtenay S.G Phillips of Oxford University investigated separation in a charcoal column using a thermal conductivity detector. He consulted with Claesson and decided to use displacement as his separating principle. After learning about the results of James and Martin, he switched to partition chromatography.<ref name="Ettre"/>
Edit summary
(Briefly describe your changes)
By publishing changes, you agree to the
Terms of Use
, and you irrevocably agree to release your contribution under the
CC BY-SA 4.0 License
and the
GFDL
. You agree that a hyperlink or URL is sufficient attribution under the Creative Commons license.
Cancel
Editing help
(opens in new window)