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Lewis structure
(section)
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== Example == The formula of the [[nitrite]] ion is {{chem2|NO2−}}. # Nitrogen is the least electronegative atom of the two, so it is the central atom by multiple criteria. # Count valence electrons. Nitrogen has 5 valence electrons; each oxygen has 6, for a total of (6 × 2) + 5 = 17. The ion has a charge of −1, which indicates an extra electron, so the total number of electrons is 18. # Connect the atoms by single bonds. Each oxygen must be bonded to the nitrogen, which uses four electrons—two in each bond. # Place lone pairs. The 14 remaining electrons should initially be placed as 7 lone pairs. Each oxygen may take a maximum of 3 lone pairs, giving each oxygen 8 electrons including the bonding pair. The seventh lone pair must be placed on the nitrogen atom. # Satisfy the octet rule. Both oxygen atoms currently have 8 electrons assigned to them. The nitrogen atom has only 6 electrons assigned to it. One of the lone pairs on an oxygen atom must form a double bond, but either atom will work equally well. Therefore, there is a resonance structure. # Tie up loose ends. Two Lewis structures must be drawn: Each structure has one of the two oxygen atoms double-bonded to the nitrogen atom. The second oxygen atom in each structure will be single-bonded to the nitrogen atom. Place brackets around each structure, and add the charge (−) to the upper right outside the brackets. Draw a double-headed arrow between the two resonance forms. [[File:Nitrite-ion-lewis-canonical.svg|class=skin-invert-image|center|500px]]
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