Open main menu
Home
Random
Recent changes
Special pages
Community portal
Preferences
About Wikipedia
Disclaimers
Incubator escapee wiki
Search
User menu
Talk
Dark mode
Contributions
Create account
Log in
Editing
Synchrotron light source
(section)
Warning:
You are not logged in. Your IP address will be publicly visible if you make any edits. If you
log in
or
create an account
, your edits will be attributed to your username, along with other benefits.
Anti-spam check. Do
not
fill this in!
===Diffraction and scattering=== [[X-ray diffraction]] (XRD) and [[scattering]] experiments are performed at synchrotrons for the structural analysis of [[crystalline]] and [[amorphous]] materials. These measurements may be performed on [[Powder diffraction|powders]], [[single crystals]], or [[thin films]]. The high resolution and intensity of the synchrotron beam enables the measurement of scattering from dilute phases or the analysis of [[residual stress]]. Materials can be studied at [[high pressure]] using [[diamond anvil cell]]s to simulate extreme geologic environments or to create exotic forms of matter.{{Citation needed|date=January 2021}} [[Image:010 large subunit-1FFK.gif|thumb|200px|left| Structure of a [[ribosome]] subunit solved at high resolution using synchrotron X-ray crystallography.<ref name=Ban2000>{{cite journal | last1=Ban | first1=N. |first2=P. |last2=Nissen|first3=J. |last3=Hansen |first4=P. |last4=Moore|first5= T. |last5=Steitz |title=The Complete Atomic Structure of the Large Ribosomal Subunit at 2.4 Å Resolution | journal=Science | volume=289 | issue=5481 | date=2000-08-11 | doi=10.1126/science.289.5481.905 | pmid=10937989 | pages=905–920| bibcode=2000Sci...289..905B }}</ref>]] [[X-ray crystallography]] of [[proteins]] and other macromolecules (PX or MX) are routinely performed. Synchrotron-based crystallography experiments were integral to solving the structure of the [[ribosome]];<ref name=Ban2000 /><ref>The Royal Swedish Academy of Sciences, [https://www.nobelprize.org/nobel_prizes/chemistry/laureates/2009/popular-chemistryprize2009.pdf "The Nobel Prize in Chemistry 2009: Information for the Public"], accessed 2016-06-20</ref> this work earned the [https://www.nobelprize.org/nobel_prizes/chemistry/laureates/2009/ Nobel Prize in Chemistry in 2009]. The size and shape of [[nanoparticles]] are characterized using [[small angle X-ray scattering]] (SAXS). Nano-sized features on surfaces are measured with a similar technique, [[Grazing-incidence small-angle scattering|grazing-incidence small angle X-ray scattering]] (GISAXS).<ref>{{cite journal | last1=Renaud | first1=Gilles | last2=Lazzari | first2=Rémi | last3=Leroy | first3=Frédéric | title=Probing surface and interface morphology with Grazing Incidence Small Angle X-Ray Scattering | journal=Surface Science Reports | volume=64 | issue=8 | year=2009 | doi=10.1016/j.surfrep.2009.07.002 | pages=255–380| bibcode=2009SurSR..64..255R }}</ref> In this and other methods, surface sensitivity is achieved by placing the crystal surface at a small angle relative to the incident beam, which achieves [[total external reflection]] and minimizes the X-ray penetration into the material.{{Citation needed|date=January 2021}} The atomic- to nano-scale details of [[Surface science|surfaces]], interfaces, and [[thin films]] can be characterized using techniques such as [[X-ray reflectivity]] (XRR) and [[X-ray crystal truncation rod|crystal truncation rod]] (CTR) analysis.<ref>{{cite journal | last1=Robinson | first1=I K | last2=Tweet | first2=D J | title=Surface X-ray diffraction | journal=Reports on Progress in Physics | volume=55 | issue=5 | date=1992-05-01 | doi=10.1088/0034-4885/55/5/002 | pages=599–651| bibcode=1992RPPh...55..599R | s2cid=250899816 }}</ref> [[X-ray standing wave]] (XSW) measurements can also be used to measure the position of atoms at or near surfaces; these measurements require high-resolution optics capable of resolving [[dynamical diffraction]] phenomena.<ref>{{cite journal | last1=Golovchenko | first1=J. A. | last2=Patel | first2=J. R. | last3=Kaplan | first3=D. R. | last4=Cowan | first4=P. L. |author5-link=Michael Bedzyk | last5=Bedzyk | first5=M. J. | title=Solution to the Surface Registration Problem Using X-Ray Standing Waves | journal=Physical Review Letters | volume=49 | issue=8 | date=1982-08-23 | doi=10.1103/physrevlett.49.560 | pages=560–563| bibcode=1982PhRvL..49..560G | url=https://dash.harvard.edu/bitstream/1/29407052/1/SolutionToTheSurfaceRegistrationProblem.pdf }}</ref> Amorphous materials, including liquids and melts, as well as crystalline materials with local disorder, can be examined using X-ray [[pair distribution function]] analysis, which requires high energy X-ray scattering data.<ref>T. Egami, S.J.L. Billinge, "Underneath the Bragg Peaks: Structural Analysis of Complex Materials", [https://books.google.com/books?id=ek2ymu7_NfgC&pg=PP2 ''Pergamon'' (2003)]</ref> By tuning the beam energy through the [[absorption edge]] of a particular element of interest, the scattering from atoms of that element will be modified. These so-called resonant anomalous X-ray scattering methods can help to resolve scattering contributions from specific elements in the sample.{{Citation needed|date=January 2021}} Other scattering techniques include [[EDXRD|energy dispersive X-ray diffraction]], [[resonant inelastic X-ray scattering]], and magnetic scattering.{{Citation needed|date=January 2021}}
Edit summary
(Briefly describe your changes)
By publishing changes, you agree to the
Terms of Use
, and you irrevocably agree to release your contribution under the
CC BY-SA 4.0 License
and the
GFDL
. You agree that a hyperlink or URL is sufficient attribution under the Creative Commons license.
Cancel
Editing help
(opens in new window)