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Thermogravimetric analysis
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==Operation in combination with other instruments== Thermogravimetric analysis is often combined with other processes or used in conjunction with other analytical methods. For example, the TGA instrument continuously weighs a sample as it is heated to temperatures of up to 2000 °C for coupling with [[Fourier-transform infrared spectroscopy]] (FTIR) and [[mass spectrometry]] gas analysis. As the temperature increases, various components of the sample are decomposed and the weight percentage of each resulting mass change can be measured. {| class="wikitable" |+<big>'''Comparison of Thermal gravimetric analysis and Differential thermal analysis techniques:'''</big> !'''<big>Sr.No.</big>''' !'''<big>Thermal gravimetric analysis (TGA)</big>''' !<big>'''Differential thermal analysis (DTA)'''</big> |- |1 |In TGA the weight loss or gain is measured as a function of temperature or time. |In DTA the temperature difference between a sample and reference is measured as a function of temperature. |- |2 |The TGA curve appears as steps involving horizontal and curved portions. |The DTA curve shows upward and downward peaks. |- |3 |Instrument used in TGA is a thermobalance. |Instrument used in DTA is a DTA Apparatus. |- |4 |TGA gives information only for substances which show a change in mass on heating or cooling. |DTA does not require a change in mass of the sample in order to obtain meaningful information. DTA can be used to study any process in which heat is absorbed or liberated. |- |5 |The upper temperature used for TGA is normally 1000 °C. |The upper temperature used for DTA is often higher than TGA (As high as 1600 °C). |- |6 |Quantitative analysis is done from the thermal curve by measuring the loss in mass <math>\bigtriangleup</math>m. |Quantitative analysis is done by measuring the peak areas and peak heights. |- |7 |The data obtained in TGA is useful in determining purity and composition of materials, drying and ignition temperatures of materials and knowing the stability temperatures of compounds. |The data obtained in DTA is used to determine temperatures of transitions, reactions and melting points of substances. |}
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