Editing Humidity (section)

== Pressure dependence ==
The relative humidity of an air–water system is dependent not only on the temperature but also on the absolute pressure of the system of interest. This dependence is demonstrated by considering the air–water system shown below. The system is closed (i.e., no matter enters or leaves the system).

[[File:Changes in Relative Humidity.png|thumb|upright=1.75]]

If the system at State A is isobarically heated (heating with no change in system pressure), then the relative humidity of the system decreases because the equilibrium vapor pressure of water increases with increasing temperature. This is shown in State B.

If the system at State A is isothermally compressed (compressed with no change in system temperature), then the relative humidity of the system increases because the partial pressure of water in the system increases with the volume reduction. This is shown in State C. Above 202.64 kPa, the RH would exceed 100% and water may begin to condense.

If the pressure of State A was changed by simply adding more dry air, without changing the volume, the relative humidity would not change.

Therefore, a change in relative humidity can be explained by a change in system temperature, a change in the volume of the system, or change in both of these system properties.

=== Enhancement factor ===
The enhancement factor <math> (f_w) </math> is defined as the ratio of the saturated vapor pressure of water in moist air <math> (e'_w) </math> to the saturated vapor pressure of pure water:
<math display="block"> f_W = \frac{e'_w}{e^*_w}. </math>

The enhancement factor is equal to unity for ideal gas systems. However, in real systems the interaction effects between gas molecules result in a small increase of the equilibrium vapor pressure of water in air relative to equilibrium vapor pressure of pure water vapor. Therefore, the enhancement factor is normally slightly greater than unity for real systems.

The enhancement factor is commonly used to correct the equilibrium vapor pressure of water vapor when empirical relationships, such as those developed by Wexler, Goff, and Gratch, are used to estimate the properties of psychrometric systems.

Buck has reported that, at sea level, the vapor pressure of water in saturated moist air amounts to an increase of approximately 0.5% over the equilibrium vapor pressure of pure water.{{sfn|Buck|1981|pp=1527–1532}}