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Refractive index
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===Principal refractive index wavelength ambiguity=== Because of dispersion, it is usually important to specify the vacuum wavelength of light for which a refractive index is measured. Typically, measurements are done at various well-defined spectral [[emission line]]s. Manufacturers of optical glass in general define principal index of refraction at yellow spectral line of helium ({{val|587.56|u=nm}}) and alternatively at a green spectral line of mercury ({{val|546.07|u=nm}}), called {{mvar|d}} and {{mvar|e}} lines respectively. [[Abbe number]] is defined for both and denoted {{mvar|V<sub>d</sub>}} and {{mvar|V<sub>e</sub>}}. The spectral data provided by glass manufacturers is also often more precise for these two wavelengths.<ref>{{cite web |author= Schott Company |date= <!-- undated --> |title= Interactive Abbe Diagram |url= https://www.schott.com/en-pl/interactive-abbe-diagram |access-date= 2023-08-13 |website= Schott.com}}</ref><ref>{{cite web |author= Ohara Corporation |date= <!-- undated --> |title= Optical Properties |url= https://www.oharacorp.com/o2.html |access-date= 2022-08-15 |website= Oharacorp.com }}</ref><ref>{{cite web |author= Hoya Group |date= <!-- undated --> |title= Optical Properties |url= https://www.hoya-opticalworld.com/english/technical/002.html |access-date= 2023-08-13 |website=Hoya Group Optics Division}}</ref><ref>{{cite book |last1= Lentes |first1= Frank-Thomas |last2= Clement |first2= Marc K. Th. |last3= Neuroth |first3= Norbert |last4= Hoffmann |first4= Hans-Jürgen |last5= Hayden |first5= Yuiko T. |last6= Hayden |first6= Joseph S. |last7= Kolberg |first7= Uwe |last8= Wolff |first8= Silke |editor-last1= Bach |editor-first1= Hans |editor-last2= Neuroth |editor-first2= Norbert |date= 1998 |title=The Properties of Optical Glass |chapter= Optical Properties |series=Schott Series on Glass and Glass Ceramics |page= 30 |language=en |doi= 10.1007/978-3-642-57769-7 |isbn= 978-3-642-63349-2 }}</ref> Both, {{mvar|d}} and {{mvar|e}} spectral lines are singlets and thus are suitable to perform a very precise measurements, such as spectral goniometric method.<ref>{{cite conference |last1= Krey |first1= Stefan |last2= Off |first2= Dennis |last3= Ruprecht |first3= Aiko |editor-last1= Soskind |editor-first1= Yakov G. |editor-last2= Olson |editor-first2= Craig |date= 2014-03-08 |title= Measuring the Refractive Index with Precision Goniometers: A Comparative Study |url= https://www.spiedigitallibrary.org/conference-proceedings-of-spie/8992/89920D/Measuring-the-refractive-index-with-precision-goniometers--a-comparative/10.1117/12.2041760.full |conference= SPIE OPTO, 2014 |location= San Francisco, California |book-title= Proc. SPIE 8992, Photonic Instrumentation Engineering |publisher= SPIE |volume= 8992 |pages= 56–65 |doi= 10.1117/12.2041760 |bibcode= 2014SPIE.8992E..0DK |s2cid= 120544352 |url-access= subscription }}</ref><ref>{{Cite book |last1=Rupp |first1=Fabian |last2=Jedamzik |first2=Ralf |last3=Bartelmess |first3=Lothar |last4=Petzold |first4=Uwe |title=Optical Fabrication, Testing, and Metrology VII |chapter=The modern way of refractive index measurement of optical glass at SCHOTT |journal=Optical Fabrication |editor-first1=Reinhard |editor-first2=Roland |editor-first3=Deitze |editor-last1=Völkel |editor-last2=Geyl |editor-last3=Otaduy |date=2021-09-12 |chapter-url=https://www.spiedigitallibrary.org/conference-proceedings-of-spie/11873/1187308/The-modern-way-of-refractive-index-measurement-of-optical-glass/10.1117/12.2597023.full |publisher=SPIE |volume=11873 |pages=15–22 |doi=10.1117/12.2597023|bibcode=2021SPIE11873E..08R |isbn=9781510645905 |s2cid=240561530 }}</ref> In practical applications, measurements of refractive index are performed on various refractometers, such as [[Abbe refractometer]]. Measurement accuracy of such typical commercial devices is in the order of 0.0002.<ref>{{Cite web |title=Abbe Refractometer{{!}} ATAGO CO., LTD. |url=https://www.atago.net/en/products-abbe-top.php |access-date=2022-08-15 |website=www.atago.net}}</ref><ref>{{Cite web |title=Abbe Multi-Wavelength Refractometer |url=https://www.novatech-usa.com/1412-DR-M2-1550_2 |access-date=2022-08-15 |website=Nova-Tech International |language=en-US}}</ref> Refractometers usually measure refractive index {{mvar|n<sub>D</sub>}}, defined for sodium doublet {{mvar|D}} ({{val|589.29|u=nm}}), which is actually a midpoint between two adjacent yellow spectral lines of sodium. Yellow spectral lines of helium ({{mvar|d}}) and sodium ({{mvar|D}}) are {{val|1.73|u=nm}} apart, which can be considered negligible for typical refractometers, but can cause confusion and lead to errors if accuracy is critical. All three typical principle refractive indices definitions can be found depending on application and region,<ref>{{Cite book |url=https://link.springer.com/book/10.1007/978-3-642-57769-7 |title=The Properties of Optical Glass |series=Schott Series on Glass and Glass Ceramics |year=1998 |pages=267 |language=en |doi=10.1007/978-3-642-57769-7|isbn=978-3-642-63349-2 |editor1=Bach, Hans |editor2=Neuroth, Norbert }}</ref> so a proper subscript should be used to avoid ambiguity.
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