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First principle
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== In physics == {{Expand section|date=July 2023}} In [[physics]], a calculation is said to be ''from first principles'', or ''[[ab initio]]'', if it starts directly at the level of established laws of physics and does not make assumptions such as empirical [[Physical model|model]] and [[Curve fitting|fitting]] parameters. For example, calculation of [[electronic structure]] using the [[Schrödinger equation]] within a set of approximations that do not include fitting the model to experimental data is an [[ab initio quantum chemistry methods|''ab initio'' approach]].
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