Open main menu
Home
Random
Recent changes
Special pages
Community portal
Preferences
About Wikipedia
Disclaimers
Incubator escapee wiki
Search
User menu
Talk
Dark mode
Contributions
Create account
Log in
Editing
Rubidium
(section)
Warning:
You are not logged in. Your IP address will be publicly visible if you make any edits. If you
log in
or
create an account
, your edits will be attributed to your username, along with other benefits.
Anti-spam check. Do
not
fill this in!
==Applications== [[File:USNO rubidium fountain.jpg|thumb|left|upright|A rubidium fountain [[atomic clock]] at the [[United States Naval Observatory]]]] Rubidium compounds are sometimes used in [[fireworks]] to give them a purple color.<ref>{{Cite journal |first = E.-C. |last = Koch |title = Special Materials in Pyrotechnics, Part II: Application of Caesium and Rubidium Compounds in Pyrotechnics |journal = Journal Pyrotechnics |date = 2002 |volume = 15 |pages = 9–24 |url = http://www.jpyro.com/wp/?p=179 |access-date = 2010-01-29 |archive-date = 2011-07-13 |archive-url = https://web.archive.org/web/20110713122322/http://www.jpyro.com/wp/?p=179 |url-status = dead }}</ref> Rubidium has also been considered for use in a [[thermoelectric generator]] using the [[magnetohydrodynamics|magnetohydrodynamic]] principle, whereby hot rubidium ions are passed through a [[magnetic field]].<ref>{{cite book |url = https://books.google.com/books?id=59XvAAAAMAAJ&q=%22rubidium%22+%22magnetohydrodynamic%22 |page = 193 |title = Chemical principles |isbn = 978-0-06-040808-4 |author1 = Boikess, Robert S |author2 = Edelson, Edward |date = 1981|publisher = Harper & Row }}</ref> These conduct electricity and act like an [[armature (electrical engineering)|armature]] of a generator, thereby generating an [[electric current]]. Rubidium, particularly vaporized <sup>87</sup>Rb, is one of the most commonly used atomic species employed for [[laser cooling]] and [[Bose–Einstein condensation]]. Its desirable features for this application include the ready availability of inexpensive [[diode laser]] light at the relevant [[wavelength]] and the moderate temperatures required to obtain substantial vapor pressures.<ref>{{cite journal |journal = Journal of Research of the National Institute of Standards and Technology |url = http://nvl.nist.gov/pub/nistpubs/jres/101/4/cnt101-4.htm |title = Bose-Einstein condensation (all 20 articles) |date = 1996 |volume = 101 |issue = 4 |pages = 419–618 |author = Eric Cornell |display-authors = etal |doi = 10.6028/jres.101.045 |pmid = 27805098 |pmc = 4907621 |access-date = 2015-09-14 |archive-url = https://web.archive.org/web/20111014234040/http://nvl.nist.gov/pub/nistpubs/jres/101/4/cnt101-4.htm |archive-date = 2011-10-14 |url-status = dead }}</ref><!--All the 20 article are valid because they all describe the use of rubidium for Bose-Einstein condensation --><ref>{{cite journal | doi = 10.1088/0953-4075/32/12/322 | title = Output coupling of a Bose-Einstein condensate formed in a TOP trap | date = 1999 | last1 = Martin | first1 = J. L. | last2 = McKenzie | first2 = C. R. | last3 = Thomas | first3 = N. R. | last4 = Sharpe | first4 = J. C. | last5 = Warrington | first5 = D. M. | last6 = Manson | first6 = P. J. | last7 = Sandle | first7 = W. J. | last8 = Wilson | first8 = A. C. | journal = Journal of Physics B: Atomic, Molecular and Optical Physics | volume = 32 | issue = 12 | pages = 3065|arxiv = cond-mat/9904007 |bibcode = 1999JPhB...32.3065M | s2cid = 119359668 }}</ref> For cold-atom applications requiring tunable interactions, <sup>85</sup>Rb is preferred for its rich [[Feshbach resonance|Feshbach spectrum]].<ref>{{Cite journal |last1=Chin |first1=Cheng |last2=Grimm |first2=Rudolf |last3=Julienne |first3=Paul |last4=Tiesinga |first4=Eite |date=2010-04-29 |title=Feshbach resonances in ultracold gases |journal=Reviews of Modern Physics |volume=82 |issue=2 |pages=1225–1286 |doi=10.1103/RevModPhys.82.1225 |bibcode=2010RvMP...82.1225C |arxiv=0812.1496|s2cid=118340314 }}</ref> Rubidium has been used for polarizing [[Helium-3|<sup>3</sup>He]], producing volumes of magnetized <sup>3</sup>He gas, with the nuclear spins aligned rather than random. Rubidium vapor is optically pumped by a laser, and the polarized Rb polarizes <sup>3</sup>He through the [[hyperfine structure|hyperfine]] interaction.<ref>{{Cite journal |url=http://www.ncnr.nist.gov/equipment/he3nsf/SEOP/nistSlowNeutronconf2005.pdf |journal=Journal of Research of the National Institute of Standards and Technology |title=Polarized <sup>3</sup>He spin filters for slow neutron physics |volume=110 |issue=3 |pages=299–304 |first1=T. R. |last1=Gentile |first2=W. C. |last2=Chen |first3=G. L. |last3=Jones |first4=E. |last4=Babcock |first5=T. G. |last5=Walker |doi=10.6028/jres.110.043 |pmid=27308140 |pmc=4849589 |year=2005 |access-date=2015-08-06 |archive-date=2016-12-21 |archive-url=https://web.archive.org/web/20161221234735/https://ncnr.nist.gov/equipment/he3nsf/SEOP/nistSlowNeutronconf2005.pdf |url-status=dead }}</ref> Such [[spin polarization|spin-polarized]] <sup>3</sup>He cells are useful for neutron polarization measurements and for producing polarized neutron beams for other purposes.<ref>{{Cite web |url=http://www.ncnr.nist.gov/AnnualReport/FY2002_html/pages/neutron_spin.htm |publisher=NIST Center for Neutron Research 2002 Annual Report |title=Neutron spin filters based on polarized helium-3 |access-date=2008-01-11}}</ref> The resonant element in [[atomic clock]]s utilizes the [[hyperfine structure]] of rubidium's energy levels, and rubidium is useful for high-precision timing. It is used as the main component of secondary frequency references (rubidium oscillators) in cell site transmitters and other electronic transmitting, networking, and test equipment. These [[rubidium standard]]s are often used with [[GNSS]] to produce a "primary frequency standard" that has greater accuracy and is less expensive than caesium standards.<ref>{{cite book |chapter-url = https://books.google.com/books?id=jmfkJYdEANEC&pg=PA32 |page = 32 |chapter = GPS |title = Measurement, control, and communication using IEEE 1588 |isbn = 978-1-84628-250-8 |author1 = Eidson, John C |date = 2006-04-11|publisher = Springer }}</ref><ref name="Clock">{{cite book |chapter-url = https://books.google.com/books?id=ttYt5bZqX0AC&pg=PA300 |page = 300 |chapter = Rubidium and crystal oscillators |title = Data network engineering |isbn = 978-0-7923-8594-3 |author1 = King, Tim |author2 = Newson, Dave |date = 1999-07-31|publisher = Springer }}</ref> Such rubidium standards are often mass-produced for the [[telecommunications industry]].<ref>{{cite book |chapter-url = https://books.google.com/books?id=LesrjSVQMPQC&pg=PA72 |chapter = Rubidium Vapor Cell |title = Advances in electronics and electron physics |isbn = 978-0-12-014644-4 |author1 = Marton, L. |date = 1977-01-01|publisher = Academic Press }}</ref> Other potential or current uses of rubidium include a working fluid in vapor turbines, as a [[getter]] in [[vacuum tube]]s, and as a [[photocell]] component.<ref>{{cite book |url = https://books.google.com/books?id=GEVt3kpFw64C&pg=PA274 |page = 274 |title = Introduction To Nuclear And Particle Physics |isbn = 978-81-203-3610-0 |author1 = Mittal |date = 2009|publisher = Prentice-Hall Of India Pvt. Limited }}</ref> Rubidium is also used as an ingredient in special types of glass, in the production of [[superoxide]] by burning in [[oxygen]], in the study of [[potassium]] [[ion channel]]s in biology, and as the vapor in atomic [[magnetometer]]s.<ref name="MAG">{{Cite journal |title=Parametric modulation of an atomic magnetometer |journal=Applied Physics Letters| volume=89| date=2006 |issue=13 |pages=23575531–23575533 |doi=10.1063/1.2357553 |last1=Li |first1=Zhimin |last2=Wakai |first2=Ronald T. |last3=Walker |first3=Thad G. |bibcode = 2006ApPhL..89m4105L |pmc=3431608 |pmid=22942436}}</ref> In particular, <sup>87</sup>Rb is used with other alkali metals in the development of spin-exchange relaxation-free [[SERF|(SERF) magnetometers]].<ref name="MAG" /> [[Rubidium-82]] is used for [[positron emission tomography]]. Rubidium is very similar to potassium, and tissue with high potassium content will also accumulate the radioactive rubidium. One of the main uses is [[myocardial perfusion imaging]]. As a result of changes in the [[blood–brain barrier]] in brain tumors, rubidium collects more in brain tumors than normal brain tissue, allowing the use of radioisotope rubidium-82 in [[nuclear medicine]] to locate and image brain tumors.<ref>{{cite journal |last1 = Yen |first1 = C. K. |last2 = Yano |first2 = Y. |last3 = Budinger |first3 = T. F. |last4 = Friedland |first4 = R. P. |last5 = Derenzo |first5 = S. E. |last6 = Huesman |first6 = R. H. |last7 = O'Brien |first7 = H. A. |title = Brain tumor evaluation using Rb-82 and positron emission tomography |journal = Journal of Nuclear Medicine |volume = 23 |issue = 6 |pages = 532–7 |date = 1982 |pmid = 6281406}}</ref> Rubidium-82 has a very short half-life of 76 seconds, and the production from decay of [[strontium-82]] must be done close to the patient.<ref>{{cite book |chapter-url = https://books.google.com/books?id=FhkLE8MC71IC&pg=PA59 |page = 59 |chapter = Rubidium-82 |title = Clinical PET and PET/CT |isbn = 978-1-85233-838-1 |last1= Jadvar |first1= H. |last2 = Anthony Parker | first2 = J. |date = 2005|publisher = Springer }}</ref> Rubidium was tested for the influence on manic depression and depression.<ref name="manic" /><ref>{{cite journal |last1 = Malekahmadi |first1 = P. |title = Rubidium in psychiatry: Research implications |journal = Pharmacology Biochemistry and Behavior |volume = 21 |pages = 49–50 |date = 1984 |doi = 10.1016/0091-3057(84)90162-X |pmid = 6522433 |last2 = Williams |first2 = John A.|s2cid = 2907703 }}</ref> Dialysis patients suffering from depression show a depletion in rubidium, and therefore a supplementation may help during depression.<ref>{{cite journal| last1 = Canavese| first1 = Caterina| last2 = Decostanzi| first2 = Ester| last3 = Branciforte| first3 = Lino| last4 = Caropreso| first4 = Antonio| last5 = Nonnato| first5 = Antonello| last6 = Sabbioni| first6 = Enrico| title = Depression in dialysis patients: Rubidium supplementation before other drugs and encouragement?| journal = Kidney International| volume = 60| issue = 3| pages = 1201–2| date = 2001| doi = 10.1046/j.1523-1755.2001.0600031201.x| pmid=11532118| doi-access = free}}</ref> In some tests the rubidium was administered as rubidium chloride with up to 720 mg per day for 60 days.<ref name="isbn1-58890-299-4">{{cite book | last = Lake | first = James A. | title = Textbook of Integrative Mental Health Care | publisher = Thieme Medical Publishers | location = New York | date = 2006 | pages =164–165 | isbn = 978-1-58890-299-3 |url = https://books.google.com/books?id=Bt5euqMwbpYC&pg=PA165}}</ref><ref>{{cite journal |pmid=8412574 |date=1993 |last1=Torta |first1=R. |last2=Ala |first2=G. |last3=Borio |first3=R. |last4=Cicolin |first4=A. |last5=Costamagna |first5=S. |last6=Fiori |first6=L. |last7=Ravizza |first7=L. |title=Rubidium chloride in the treatment of major depression |volume=34 |issue=2 |pages=101–110 |journal=Minerva Psichiatrica}}</ref> {{Chembox | container_only = yes |Section7={{Chembox Hazards | ExternalSDS = | GHSPictograms = {{GHS02}}{{GHS05}} | GHSSignalWord = Danger | HPhrases = {{H-phrases|260|314}} | PPhrases = {{P-phrases|223|231+232|280|305+351+338|370+378|422}}<ref>{{Cite web|url=https://www.sigmaaldrich.com/catalog/product/aldrich/276332|title=Rubidium 276332|website=Sigma-Aldrich}}</ref> | NFPA-H = 3 | NFPA-F = 4 | NFPA-R = 2 | NFPA-S = w | NFPA_ref = }} }}
Edit summary
(Briefly describe your changes)
By publishing changes, you agree to the
Terms of Use
, and you irrevocably agree to release your contribution under the
CC BY-SA 4.0 License
and the
GFDL
. You agree that a hyperlink or URL is sufficient attribution under the Creative Commons license.
Cancel
Editing help
(opens in new window)