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Atacamite
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{{Short description|Halide evaporite mineral}} {{Infobox mineral | name = Atacamite | boxwidth = | boxbgcolor = | image = Atacamite on malachite - Mt Gunson mines, South Australia.jpg | imagesize = 260px | alt = | caption = Atacamite from Mt. Gunson mines, South Australia | category = [[Halide mineral]] | formula = Cu<sub>2</sub>Cl(OH)<sub>3</sub> |IMAsymbol=Ata<ref>{{Cite journal|last=Warr|first=L.N.|date=2021|title=IMA–CNMNC approved mineral symbols|journal=Mineralogical Magazine|volume=85|issue=3|pages=291–320|doi=10.1180/mgm.2021.43|bibcode=2021MinM...85..291W|s2cid=235729616|doi-access=free}}</ref> | molweight = | strunz = 3.DA.10a | dana = | system = [[Orthorhombic]] | class = Dipyramidal (mmm) <br/>[[H-M symbol]]: (2/m 2/m 2/m) | symmetry = ''Pnma'' | unit cell = a = 6.03, b = 9.12 <br/>c = 6.865 [Å]; Z = 4 | color = Bright green, dark emerald-green to blackish green | colour = | habit = Slender prismatic crystals, fibrous, granular to compact, massive | twinning = Contact and penetration with complex twinned groupings | cleavage = Perfect on {010}, fair on {101} | fracture = Conchoidal | tenacity = Brittle | mohs = 3–3.5 | luster = Adamantine to vitreous | streak = Apple green | diaphaneity = Transparent to translucent | gravity = 3.745–3.776 | density = | polish = | opticalprop = Biaxial (−) | refractive = n<sub>α</sub> = 1.831 n<sub>β</sub> = 1.861 n<sub>γ</sub> = 1.880 | birefringence = δ = 0.049 | pleochroism = X = pale green; Y = yellow-green; Z = grass-green | 2V = Calculated: 74° | dispersion = r < v, strong | extinction = | length fast/slow = | fluorescence = | absorption = | melt = | fusibility = | diagnostic = | solubility = | impurities = | alteration = | other = | prop1 = | prop1text = | references = <ref name=Mindat>[http://www.mindat.org/min-406.html Atacamite on Mindat.org]</ref><ref name=HBM>[http://rruff.geo.arizona.edu/doclib/hom/atacamite.pdf Handbook of Mineralogy]</ref><ref name=Webmin>[http://www.webmineral.com/data/Atacamite.shtml Atacamite on Webmineral]</ref><ref>[https://www.mineralienatlas.de/lexikon/index.php/MineralData?mineral=Atacamite Mineralienatlas]</ref> }} '''Atacamite''' is a [[copper]] [[halide mineral]]: a [[Dicopper chloride trihydroxide|copper(II) chloride hydroxide]] with formula Cu<sub>2</sub>Cl(OH)<sub>3</sub>. It was first described for deposits in the [[Atacama Desert]] of [[Chile]] in 1802 by [[Dmitri Alekseyevich Gallitzin|Dmitri de Gallitzin]].<ref name="Mindat" /> The Atacama Desert is also the namesake of the mineral. == Occurrence == Atacamite is [[Polymorphism (materials science)|polymorphous]] with [[botallackite]], [[clinoatacamite]], and [[paratacamite]].<ref name="Mindat" /> Atacamite is a comparatively rare mineral, formed from primary copper minerals in the [[oxidation]] or [[weathering]] zone of arid climates. It has also been reported as a [[volcanic sublimate]] from [[fumarole]] deposits, as sulfide alteration products in [[black smoker]]s.<ref name="HBM" /> The mineral has also been found naturally on oxidized copper deposits in Chile, [[China]], [[Russia]], [[Czech Republic]], [[Arizona]], and [[Australia]].<ref name=":0" /> It occurs in association with [[cuprite]], [[brochantite]], [[linarite]], [[caledonite]], [[malachite]], [[chrysocolla]] and its polymorphs.<ref name="HBM" /> === Synthetic Occurrence === Atacamite has been discovered in the patina of the [[Statue of Liberty]], and as alteration of ancient [[bronze]] and copper [[Artifact (archaeology)|artifacts]]. The bronze of the [[Antikythera mechanism]] had turned to atacamite under the sea.<ref>{{cite journal |last1=Alex Wilkins |title=Ancient computer's gears may not have been able to turn |journal=New Scientist |date=Apr 17, 2025 |url=https://www.newscientist.com/article/2476675-ancient-computers-gears-may-not-have-been-able-to-turn/}}</ref> The mineral has been found as a pigment in [[sculpture]], [[Manuscript|manuscripts]], [[Map|maps]], and [[Fresco|frescoes]] discovered in [[Eurasia]], [[Russia]], and [[Persia]].<ref name=":0">{{Cite web|url=http://cameo.mfa.org/wiki/Atacamite|title=Atacamite – CAMEO|website=cameo.mfa.org|language=en|access-date=2017-10-15}}</ref> === Biomineral === Atacamite occurs as a biomineral in the jaws of [[Glycera (genus)|bloodworms]].<ref name="Lichtenegger">{{cite journal|date=October 2002|title=High abrasion resistance with sparse mineralization: copper biomineral in worm jaws|journal=Science|volume=298|issue=5592|pages=389–92|bibcode=2002Sci...298..389L|doi=10.1126/science.1075433|pmid=12376695|vauthors=Lichtenegger HC, Schöberl T, Bartl MH, Waite H, Stucky GD|s2cid=14001250}}</ref><ref name="Stucky2003">{{cite journal |vauthors=Lichtenegger HC, Schöberl T, Ruokolainen JT, etal |title=Zinc and mechanical prowess in the jaws of Nereis, a marine worm |journal=Proc. Natl. Acad. Sci. U.S.A. |volume=100 |issue=16 |pages=9144–9 |date=August 2003 |pmid=12886017 |pmc=170886 |doi=10.1073/pnas.1632658100 |bibcode=2003PNAS..100.9144L |doi-access=free }}</ref> <gallery> Atacamite-235102.jpg|Atacamite prisms from Chile Harvard Museum of Natural History. Atacamite. Miraflores Mine, Tierra Amarilla, Atacama, Chile (DerHexer) 2012-07-20.jpg|Atacamite from Chile displayed in the [[Harvard Museum of Natural History]] Atacamite-168148.jpg|Atacamite from Mt. Gunson, South Australia </gallery> {{clear}} ==References== {{commons category|Atacamite}} {{reflist}} ==External links== *[https://web.archive.org/web/20050911055400/http://mineral.galleries.com/minerals/halides/atacamit/atacamit.htm Mineral galleries] [[Category:Copper(II) minerals]] [[Category:Chloride minerals]] [[Category:Hydroxide minerals]] [[Category:Orthorhombic minerals]] [[Category:Minerals in space group 62]] [[Category:Minerals described in 1802]] {{Halide-mineral-stub}}
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