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Di-tert-butyl ether
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{{DISPLAYTITLE:Di-''tert''-butyl ether}} {{Chembox | Watchedfields = changed | verifiedrevid = 414433035 | Name =Di-''tert''-butyl ether | ImageFile = Di-tert-butyl ether chemical structure.svg | ImageSize = 170 | ImageAlt = Skeletal formula of di-tert-butyl ether | ImageFile1 = Di-tert-butyl-ether-3D-balls.png | ImageSize1 = 180 | ImageAlt1 = Ball-and-stick model of the di-tert-butyl ether molecule | PIN = 2-Methyl-2-[(2-methylpropan-2-yl)oxy]propane | OtherNames = 2-''tert''-Butoxy-2-methylpropane<br />Di-''tert''-butyl ether | Reference = <ref name="hand"> {{cite book | last = Lide | first = David R. | year = 1998 | title = Handbook of Chemistry and Physics | edition = 87 | volume = | location = Boca Raton, Florida | publisher = CRC Press | isbn = 0-8493-0594-2 | pages = 3–162, 5–52}}</ref> |Section1={{Chembox Identifiers | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 21138 | InChI = 1/C8H18O/c1-7(2,3)9-8(4,5)6/h1-6H3 | InChIKey = AQEFLFZSWDEAIP-UHFFFAOYAT | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/C8H18O/c1-7(2,3)9-8(4,5)6/h1-6H3 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = AQEFLFZSWDEAIP-UHFFFAOYSA-N | CASNo_Ref = {{cascite|correct|??}} | CASNo = 6163-66-2 | UNII_Ref = {{fdacite|correct|FDA}} | UNII = C3A9UPP65H | PubChem = 22541 | SMILES = O(C(C)(C)C)C(C)(C)C }} |Section2={{Chembox Properties | C=8 | H=18 | O=1 | Formula = | MolarMass = | Appearance = colorless liquid | Density = 0.7658 g/cm<sup>3</sup><ref name="CRC_3"/> | MeltingPtC = -61 | MeltingPt_ref = <ref>Alquist; Tower: Nation. Advis. Comm. Aeronautics Rep. MR Nr.E 5 A 04 (1945), Chem. Abstr. 1948, 4736</ref> | BoilingPtC = 107.2 | BoilingPt_ref = <ref name="CRC_3">David R. Lide (Hrsg.): ''[[CRC Handbook of Chemistry and Physics]]'', (90 ed.), CRC Press, Boca Raton, Florida (2009), {{ISBN|978-1-4200-9084-0}}, S. 3-148.</ref> | Solubility = | SolubleOther = | VaporPressure = 3730 Pa (at 22 °C)<ref name="Smutny">E. J. Smutny, A. Bondi: "DI-t-BUTYL ETHER: STRAIN ENERGY AND PHYSICAL PROPERTIES", in: ''[[The Journal of Physical Chemistry|J. Phys. Chem.]]'', '''1961''', ''65 (3)'', S. 546–550; {{doi|10.1021/j100821a038}}.</ref> }} |Section3={{Chembox Structure | CrystalStruct = | Coordination = | MolShape = | Dipole = }} |Section4={{Chembox Thermochemistry | DeltaHf = −399.6 kJ·mol<sup>−1</sup> | DeltaHc = | Entropy = | HeatCapacity = 276.1 J·mol<sup>−1</sup>·K<sup>−1</sup> }} |Section7={{Chembox Hazards | ExternalSDS = | MainHazards = | NFPA-H = | NFPA-F = | NFPA-R = | NFPA-S = | FlashPtC = -3 | AutoignitionPtC = 365 | ExploLimits = >0.4% | PEL = }} }} '''Di-''tert''-butyl ether''' is a tertiary [[ether]], primarily of theoretical interest as the simplest member of the class of di-tertiary ethers. ==See also== * [[Ether]] * [[Methyl tert-butyl ether]] * [[Dimethyl ether]] * [[Diethyl ether]] * [[Diisopropyl ether]] ==References== {{reflist}} [[Category:Dialkyl ethers]] [[Category:Ether solvents]] [[Category:Tert-butyl compounds]] [[Category:Symmetrical ethers]] {{Ether-stub}}
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