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Germanite
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{{Short description|Rare copper iron germanium sulfide mineral}} {{Infobox mineral | name = Germanite | category = [[Sulfide mineral]] | boxwidth = | boxbgcolor = | image = Germanite-231229.jpg | imagesize = 260 | caption = Germanite, probably from the [[Tsumeb]] Mine, [[Oshikoto Region]], Namibia. | formula = Cu<sub>26</sub>Ge<sub>4</sub>Fe<sub>4</sub>S<sub>32</sub><ref>American Mineralogist (1984) 69:943-947</ref> | IMAsymbol = Ger<ref>{{Cite journal|last=Warr|first=L.N.|date=2021|title=IMA–CNMNC approved mineral symbols|journal=Mineralogical Magazine|volume=85|issue=3|pages=291–320|doi=10.1180/mgm.2021.43|bibcode=2021MinM...85..291W|s2cid=235729616|doi-access=free}}</ref> | molweight = | strunz = 2.CB.30 | dana = 2.9.4.2 | system = Isometric | class = Hextetrahedral ({{overline|4}}3m) <br/>[[H-M symbol]]: ({{overline|4}} 3m) | symmetry = ''P''{{overline|4}}3n | color = Reddish grey tarnishing to dark brown | habit = Usually massive; rarely as minute cubic crystals | cleavage = None | tenacity = Brittle | mohs = 4 | luster = Metallic | streak = Dark grey to black | gravity = 4.4 to 4.6 | density = | diaphaneity = Opaque | other = Cell data: a = 10.585 [[Ångstrom|Å]] Z = 1<ref name=Mindat/> | references = <ref name=Webmin>http://webmineral.com/data/Germanite.shtml Webmineral</ref><ref name=Handbook>http://rruff.geo.arizona.edu/doclib/hom/germanite.pdf Handbook of Mineralogy</ref> }} '''Germanite''' is a rare [[copper]] [[iron]] [[germanium]] [[sulfide mineral]], Cu<sub>26</sub>Fe<sub>4</sub>Ge<sub>4</sub>S<sub>32</sub>. It was first discovered in 1922, and named for its germanium content.<ref name=Mindat/> It is only a minor source of this important semiconductor element, which is mainly derived from the processing of the zinc sulfide mineral [[sphalerite]].<ref>U.S. Geological Survey (2008), "Germanium—Statistics and Information", U.S. Geological Survey, Mineral Commodity Summaries http://minerals.usgs.gov/minerals/pubs/commodity/germanium/</ref> Germanite contains [[gallium]], [[zinc]], [[molybdenum]], [[arsenic]], and [[vanadium]] as impurities.<ref name=Mindat/> Its [[Type locality (geology)|type locality]] is the Tsumeb Mine in [[Namibia]] where it occurs in a [[hydrothermal]] [[polymetallic]] [[ore deposit]] in [[Dolomite (rock)|dolomite]] in association with [[renierite]], [[pyrite]], [[tennantite]], [[enargite]], [[galena]], [[sphalerite]], [[digenite]], [[bornite]] and [[chalcopyrite]].<ref name=Handbook/> It has also been reported from [[Argentina]], [[Armenia]], [[Bulgaria]], [[Cuba]], [[Democratic Republic of Congo]] (Zaire), [[Finland]], [[France]], [[Greece]], [[Japan]], [[Republic of Congo]] (Brazzaville), [[Russia]] and the [[United States]].<ref name=Mindat>http://www.mindat.org/min-1681.html Mindat.org</ref> {| class="wikitable" |- ! X-Ray Powder Diffraction<ref>Dana's New Mineralogy, 8th edition, Gaines et al., Wiley</ref> |- | d spacing | 3.05 | 2.65 | 1.87 | 1.60 | 1.32 | 1.21 | 1.08 | 1.02 |- | relative intensity | 10 | 1 | 7 | 4 | 1 | 2 | 2 | 1 |} ==References== {{Reflist}} {{Commons category}} [[Category:Copper minerals]] [[Category:Iron minerals]] [[Category:Sulfide minerals]] [[Category:Germanium minerals]] [[Category:Cubic minerals]] [[Category:Minerals in space group 218]] {{sulfide-mineral-stub}}
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