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Leavening agent
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{{Short description|Substance which liberates gas and thereby increases the volume of a dough or batter}} {{For|the village|Leavening, North Yorkshire}} {{broader|Bread#Leavening{{!}}Bread leavening}} {{more citations needed|date=July 2014}} In [[cooking]], a '''leavening agent''' ({{IPAc-en|ˈ|l|ɛ|v|ən|ɪ|ŋ}}) or '''raising agent''', also called a '''leaven''' ({{IPAc-en|ˈ|l|ɛ|v|ən}}) or '''leavener''', is any one of a number of substances used in [[dough]]s and [[batter (cooking)|batters]] that cause a [[Effervescence|foaming action]] (gas bubbles) that lightens and softens the mixture. An alternative or supplement to leavening agents is mechanical action by which air is incorporated (i.e. [[kneading]]). Leavening agents can be biological or synthetic [[chemical compound]]s. The gas produced is often [[carbon dioxide]], or occasionally [[hydrogen]].<ref>{{Cite book |last=Jacobs |first=Morris Boris |title=The Chemistry and Technology of Food and Food Products |publisher=Interscience Publishers |year=1951 |location=Hoboken, NJ |pages=1932 |language=en}}</ref> When a dough or batter is mixed, the [[starch]] in the flour and the water in the dough form a [[Matrix (biology)|matrix]]<ref>{{Cite book |last=Hanft |first=Steven L. |title=Fachenglisch für Laborberufe |publisher=John Wiley & Sons |year=2016 |isbn=978-3-527-33512-1 |location=Weinheim |pages=208 |language=en}}</ref> (often supported further by [[protein]]s like [[gluten]] or [[polysaccharides]], such as [[pentosan]]s or [[xanthan gum]]). The starch then [[starch gelatinization|gelatinizes]] and sets, leaving gas bubbles that remain. == Biological leavening agents == * ''[[Saccharomyces cerevisiae]]'' producing [[carbon dioxide]] found in: ** [[baker's yeast]] ** [[Beer barm]] (unpasteurised—live yeast) ** [[ginger beer]] ** [[kefir]] ** [[sourdough|sourdough starter]] * ''[[Clostridium perfringens]]'' producing [[hydrogen]] found in [[salt-rising bread]] == Chemical leavening agents == Chemical leavens are mixtures or compounds that release gases when they react with each other, with moisture, or with heat. Most are based on a combination of acid (usually a low molecular weight organic acid) and a [[salt (chemistry)|salt]] of [[bicarbonate]] {{chem|(HCO<sub>3</sub><sup>−</sup>)}}. After they act, these compounds leave behind a chemical salt. Chemical leavens are used in [[quick bread]]s and [[cake]]s, as well as [[cookie]]s and numerous other applications where a long biological [[food fermentation|fermentation]] is impractical or undesirable. ===History=== Chemical leavening using [[pearl ash]] as a leavening agent was mentioned by [[Amelia Simmons (author)|Amelia Simmons]] in her ''[[American Cookery]]'',<ref>{{cite book|last=Simmons|first=Amelia|author2=Mary Tolford Wilson|title=The First American Cookbook|edition=1984 reprint|orig-year=1958|year=1984|publisher=Dover|location=Mineola, NY|isbn=0-486-24710-4|url-access=registration|url=https://archive.org/details/firstamericancoo00simm}}</ref> published in 1796.<ref>{{Cite book |last=Smith |first=Andrew F. |url=https://books.google.com/books?id=GZVweuXhZlkC&dq=amelia+simmons+american+cookery+1796+albany+new+york&pg=PT565 |title=The Oxford Companion to American Food and Drink |date=2007-05-01 |publisher=Oxford University Press |isbn=978-0-19-988576-3 |language=en}}</ref> Since chemical expertise is required to create a functional chemical leaven without producing off-flavors from the chemical precursors involved, such substances are often mixed into premeasured combinations for maximum results. These are generally referred to as [[baking powder]]s. Sour milk and carbonates were used in the 1800s. The breakthrough in chemical leavening agents occurred in the 1930s with the introduction of [[monocalcium phosphate]]s {{chem|(Ca(H<sub>2</sub>PO<sub>4</sub>)<sub>2</sub>)}}. Other leavening agents developed include [[sodium aluminium sulfate]] {{chem|(NaAl(SO<sub>4</sub>)<sub>2</sub>·12H<sub>2</sub>O)}}, [[disodium pyrophosphate]] {{chem|(Na<sub>2</sub>H<sub>2</sub>P<sub>2</sub>O<sub>7</sub>)}}, and [[sodium aluminium phosphate]]s {{chem|(NaH<sub>14</sub>Al<sub>3</sub>(PO<sub>4</sub>)<sub>8</sub>·4H<sub>2</sub>O and Na<sub>3</sub>H<sub>15</sub>Al<sub>2</sub>(PO<sub>4</sub>)<sub>8</sub>)}}. These compounds combine with sodium bicarbonate to give [[carbon dioxide]] in a predictable manner.<ref>John Brodie, John Godber "Bakery Processes, Chemical Leavening Agents" in Kirk-Othmer Encyclopedia of Chemical Technology 2001, John Wiley & Sons. {{doi|10.1002/0471238961.0308051303082114.a01.pub2}}</ref> == Other leavens == [[Steam]] and [[air]] are used as leavening agents when they expand upon heating.<ref>{{Cite book |last1=Ensminger |first1=Marion Eugene |title=Foods & Nutrition Encyclopedia, Two Volume Set |last2=Ensminger |first2=Audrey H. |publisher=CRC Press |year=1993 |isbn=0-8493-8980-1 |location=Boca Raton, FL |pages=249 |language=en}}</ref> To take advantage of this style of leavening, the baking must be done at high enough temperatures to flash the water to steam, with a batter that is capable of holding the steam in until set. This effect is typically used in products having one large cavity, such as [[popover]]s, [[Yorkshire pudding]]s, [[pita]], and most preparations made from [[choux pastry]]. The effect is also seen to a lesser extent in [[tempura]]. == Mechanical leavening == {{Unreferenced section|date=February 2020}} Using a [[whisk]] on certain liquids, notably [[cream]] or [[egg white]]s, can also create foams through mechanical action. This is the method employed in the making of [[sponge cake]]s, where an egg protein matrix produced by vigorous whipping provides almost all the structure of the finished product. The [[Chorleywood bread process]] uses a mix of biological and mechanical leavening to produce bread; while it is considered by food processors{{who|date=February 2020}} to be an effective way to deal with the soft wheat flours characteristic of British Isles agriculture, it is controversial{{according to whom|date=February 2020}} due to a perceived lack of quality in the final product. The process has nevertheless been adapted by industrial bakers in other parts of the world. ==See also== {{Portal|Food}} * [[Aerated Bread Company]], bakeries started in 1862 in the UK that made carbon dioxide leavened bread * [[Baking powder]] * [[Chametz]] * [[Parable of the Leaven]] * [[Passover]] * [[Unleavened bread]] == References == {{Reflist}} == Further reading == * Matz, S (1972). "Bakery Technology and Engineering", AVI Publishing Co. == External links == {{EB1911 Poster|Leaven}} * [[Wikibooks]] [[:wikibooks:Cookbook|Cookbook]] has a recipe/module on ''[[:wikibooks:Cookbook:Leavening Agent|Leavening agent]]'' {{Bread}} {{Authority control}} {{DEFAULTSORT:Leavening Agent}} [[Category:Leavening agents| ]] [[Category:Fermentation in food processing]]
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