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Microcline
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{{Short description|Igneous rock-forming tectosilicate mineral}} {{Infobox mineral | name = Microcline | boxwidth = | boxbgcolor = | image = Microcline-199473.jpg | imagesize = | alt = | caption = | struct image = | struct caption = | struct imagesize = | struct2 image = | struct2 caption = | struct2 imagesize= | SMILES = | Jmol = | category = [[Tectosilicate]] [[minerals]], [[feldspar]] [[Mineral group|group]], [[Alkali feldspar|alkali]] series | formula = KAlSi<sub>3</sub>O<sub>8</sub> | IMAsymbol = Mcc<ref>{{Cite journal|author=L.N. Warr|date=2021|title=IMA–CNMNC approved mineral symbols|journal=Mineralogical Magazine|volume=85|issue=3|pages=291–320|doi=10.1180/mgm.2021.43|bibcode=2021MinM...85..291W|s2cid=235729616|doi-access=free}}</ref> | molweight = | strunz = | dana = | system = [[Triclinic]] | class = | symmetry = P{{overline|1}} (no. 2) | unit cell = | color = White, grey, greyish yellow, yellowish, tan, salmon-pink, bluish green, green. | colour = | habit = Can be anhedral or euhedral. Grains are commonly elongate with a tabular appearance. May contain lamellae which formed from exsolved albite. | twinning = Typically displays [[albite twinning]] and [[pericline twinning]]. This combination leads to a grid pattern, hence microcline displays [[gridiron twinning]]. Can also display [[carlsbad twinning]], simple twins, or lack twinning altogether. Lamellae in microcline are discontinuous and "pinch and swell". [[Image:Microcline.jpg|thumb|200px|[[Photomicrograph]] of [[thin section]] of microcline showing crosshatched [[crystal twinning]] (in cross [[Polarization (waves)|polarized]] light)]] | cleavage = Has perfect cleavage parallel to {001} and good cleavage on {010}. Cleavages intersect at 90°41'. It can be difficult to see cleavage in thin section due to microcline's low relief. | fracture = Uneven | tenacity = Brittle | toughness = | mohs = 6–6.5 | luster = Vitreous | streak = White | diaphaneity = Transparent, translucent | gravity = 2.5–2.6 | density = | polish = | opticalprop = Biaxial negative | refractive = nα = 1.514 – 1.529 nβ = 1.518 – 1.533 nγ = 1.521 – 1.539 | birefringence = Up to first order white (roughly 0.007) | pleochroism = N/A | 2V = 65–88° | dispersion = | extinction = Inclined extinction to cleavage | length fast/slow = | fluorescence = | absorption = | melt = | Curie temp = | fusibility = | diagnostic = Gridiron twinning distinguishes microcline from other feldspars. Distinguishable from plagioclase because the lamellae in plagioclase are continuous and do not "pinch and swell." | solubility = | impurities = | alteration = Commonly alters to sericite or clay. | other = | prop1 = Relief | prop1text = Low negative relief | references = | var1 = | var1text = | var2 = Optical sign | var2text = Biaxial negative | var3 = Color in [[Plane polarized light|PPL]] | var3text = Colorless | var4 = | var4text = | var5 = | var5text = | var6 = | var6text = }} '''Microcline''' (KAlSi<sub>3</sub>O<sub>8</sub>) is an important [[igneous rocks|igneous rock]]-forming [[tectosilicate]] [[mineral]]. It is a [[potassium]]-rich [[alkali feldspar]]. Microcline typically contains minor amounts of [[sodium]]. It is common in [[granite]] and [[pegmatite]]s. Microcline forms during slow cooling of [[orthoclase]]; it is more stable at lower temperatures than orthoclase. [[Sanidine]] is a [[Polymorphism (materials science)|polymorph]] of alkali feldspar stable at yet higher temperature. Microcline may be clear, white, pale-yellow, brick-red, or green; it is generally characterized by cross-hatch twinning that forms as a result of the transformation of [[monoclinic]] orthoclase into [[triclinic]] microcline. The chemical compound name is potassium aluminium silicate, and it is known as [[E number]] reference '''E555'''. ==Geology== Microcline may be chemically the same as [[monoclinic]] orthoclase, but because it belongs to the [[triclinic]] crystal system, the prism angle is slightly less than right angles; hence the name "microcline" from the [[Greek language|Greek]] "small slope". It is a fully ordered [[triclinic]] modification of [[potassium]] [[feldspar]] and is [[Polymorphism (materials science)|dimorphous]] with [[orthoclase]]. Microcline is identical to orthoclase in many physical properties, and can be distinguished by x-ray or optical examination. When viewed under a [[Petrographic microscope|polarizing microscope]], microcline exhibits a minute multiple [[Crystal twinning|twinning]] which forms a grating-like structure that is unmistakable. [[Image:Amazonita1.jpeg|left|thumb|Feldspar (amazonite)]] [[Perthite]] is either microcline or orthoclase with thin lamellae of exsolved albite. Amazon stone, or [[amazonite]], is a green variety of microcline. It is not found anywhere in the [[Amazon Basin]], however. The [[Spain|Spanish]] explorers who named it apparently confused it with another green mineral from that region. The largest documented single crystals of microcline were found in Devil's Hole Beryl Mine, [[Colorado]], US and measured ~50 × 36 × 14 m. This could be one of the largest crystals of any material found so far.<ref>{{cite journal| url = http://www.minsocam.org/ammin/AM66/AM66_885.pdf| journal = American Mineralogist| volume = 66| pages = 885–907| year= 1981| title= The largest crystals| author = P.C. Rickwood}}</ref> Microcline is exceptionally active ice-nucleating agent in the atmosphere.<ref>{{cite journal| url = https://www.nature.com/articles/nature12278| journal = Nature| volume = 498| pages = 355–358| year= 2013| title= The importance of feldspar for ice nucleation by mineral dust in mixed-phase clouds| author = J.D. Atkinson, B.J. Murray, M.T. Woodhouse, T.F. Whale, K.J. Baustian, K.S. Carslaw, S. Dobbie, D. O'Sullivan, T.L. Malkin| issue = 7454| doi = 10.1038/nature12278| pmid = 23760484| bibcode = 2013Natur.498..355A}}</ref> Recently it has been possible to understand how water binds to the microcline surface.<ref>{{cite journal| journal = Journal of Physical Chemistry Letters| volume = 15| issue = 1| pages = 15–22| year= 2024| title= How Water Binds to Microcline Feldspar (001)| author = G. Franceschi, A. Conti, L. Lezuo, R. Abart, F. Mittendorfer, M. Schmid, U. Diebold| doi = 10.1021/acs.jpclett.3c03235| pmid = 38156776| pmc = 10788961}}</ref> ==As food additive== The chemical compound name is potassium aluminium silicate, and it is known as [[E number]] reference '''E555'''. It was the subject in 2018 of a Call for technical and toxicological data from the [[EFSA]].<ref>{{cite web |title=Call for technical and toxicological data on sodium aluminium silicate (E 554) and potassium aluminium silicate (E 555) authorised as food additives in the EU |date=7 November 2018 |url=https://www.efsa.europa.eu/en/consultations/call/181107 |publisher=EFSA}}</ref> In 2008, it (along with other Aluminum compounds) was the subject of a Scientific Opinion of the Panel on Food Additives, Flavourings, Processing Aids and Food Contact Materials from the EFSA.<ref>{{cite journal |last1=F. Aguilar, H. Autrup, S. Barlow, L. Castle, R. Crebelli, W. Dekant, K.-H. Engel, N. Gontard, D. Gott, S. Grilli, R. Gürtler, J.-C. Larsen, C. Leclercq, J.-C. Leblanc, F.-X. Malcata, W. Mennes, M.-R. Milana, I. Pratt, I. Rietjens, P. Tobback, F. Toldrá. |title=Safety of aluminium from dietary intake[1] – Scientific Opinion of the Panel on Food Additives, Flavourings, Processing Aids and Food Contact Materials (AFC) |journal=EFSA Journal |date=2008 |volume=6 |issue=7 |page=754 |doi=10.2903/j.efsa.2008.754 |url=https://www.efsa.europa.eu/en/efsajournal/pub/754|doi-access=free |pmid=37213837 |pmc=10193631 }}</ref> ==See also== *[[List of minerals]] ==References== {{reflist}} *[http://www.utexas.edu/tmm/npl/mineralogy/science_of_minerals/alkalffeldsparseries.html Alkali feldspars U. Texas] *[http://www.mindat.org/min-2704.html Mindat] [[Category:Potassium minerals]] [[Category:Aluminium minerals]] [[Category:Tectosilicates]] [[Category:Triclinic minerals]] [[Category:Feldspar]] [[Category:Luminescent minerals]] [[Category:E-number additives]] [[Category:Minerals in space group 2]]
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