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Nitroamine
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{{Short description|Organic compounds of the form >NβNOβ}} {{Distinguish|Nitrosamine}} [[Image:Nitroamine General Structure A V1.svg|thumb|right|150px|Structure of the nitroamino group, >{{chem2|N\sNO2}}, here bonded to two R groups]] In [[organic chemistry|organic]] and [[inorganic chemistry]], '''nitroamines''' or '''nitramides''' are [[chemical compound]]s with the general [[chemical structure]] {{chem2|R^{1}R^{2}N\sNO2}}. They consist of a [[Nitro compound|nitro]] group ({{chem2|\sNO2}}) bonded to the [[nitrogen]] of an [[amine]].<ref name="Clayden1st">{{cite book |last1=Clayden |first1=J. |last2=Greeves |first2=N. |last3=Warren |first3=S. |last4=Wothers |first4=P. |title=Organic Chemistry |publisher=Oxford University Press |location=Oxford, Oxfordshire |year=2001 |isbn=0-19-850346-6 |url=https://archive.org/details/organicchemistry00clay_0 |url-access=registration}}</ref><ref name="March6th">{{March6th}}</ref> The R groups can be any group, typically [[hydrogen]] (e.g., methylnitroamine {{chem2|CH3\sNH\sNO2}}) and [[organyl]] (e.g., diethylnitroamine {{chem2|(CH3CH2\s)2N\sNO2}}). An example of inorganic nitroamine is [[Chloronitramide anion|chloronitroamine]], {{chem2|Cl\sNH\sNO2}}.<ref name=pubchem>{{cite web | url=https://pubchem.ncbi.nlm.nih.gov/compound/22497266 | title=N-chloronitramide }}</ref> The [[Parent structure|parent]] [[inorganic compound]], where both R [[substituent]]s are hydrogen, is [[nitramide]] or nitroamine, {{chem2|H2N\sNO2}}. ''N''-Nitroaniline rearranges in the presence of acid to give [[2-Nitroaniline|2-nitroaniline]].<ref>{{March6th|page=738}} </ref> ==References== {{Reflist}} == Further reading == *{{Cite encyclopedia |title=Nitramines |encyclopedia=Encyclopedia of Liquid Fuels |publisher=De Gruyter |last=Schmidt |first=Eckart W. |date=2022 |pages=4203β4413 |doi=10.1515/9783110750287-035 |isbn=978-3-11-075028-7}} [[Category:Nitroamines|*]] [[Category:Functional groups]] {{Orgchem-stub}}
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