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{{Short description|Description of physical properties at the atomic and subatomic scale}} {{Pp|small=yes}} {{CS1 config|mode=CS1}} {{Good article}} {{For introduction}} [[File:Hydrogen Density Plots.png|thumb|upright=1.35|[[Wave function]]s of the [[electron]] in a hydrogen atom at different energy levels. Quantum mechanics cannot predict the exact location of a particle in space, only the probability of finding it at different locations.<ref name=Born1926>{{cite journal |author-link1=Max Born |last=Born |first=M. |title=Zur Quantenmechanik der Stoßvorgänge |trans-title=On the Quantum Mechanics of Collision Processes |journal=Zeitschrift für Physik |volume=37 |pages=863–867 |year=1926 |doi=10.1007/BF01397477 |bibcode=1926ZPhy...37..863B |issue=12 |s2cid=119896026 |issn=1434-6001 |language=de}}</ref> The brighter areas represent a higher probability of finding the electron.]] {{Quantum mechanics}} '''Quantum mechanics''' is the fundamental physical [[Scientific theory|theory]] that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of [[atom]]s.<ref name="Feynman">{{cite book |last1=Feynman |first1=Richard |last2=Leighton |first2=Robert |last3=Sands |first3=Matthew |title=The Feynman Lectures on Physics |volume=3 |publisher=California Institute of Technology |date=1964 |url=https://feynmanlectures.caltech.edu/III_01.html |access-date=19 December 2020}} Reprinted, Addison-Wesley, 1989, {{isbn|978-0-201-50064-6}}</ref>{{rp|1.1}} It is the foundation of all '''quantum physics''', which includes [[quantum chemistry]], [[quantum field theory]], [[quantum technology]], and [[quantum information science]]. Quantum mechanics can describe many systems that [[classical physics]] cannot. Classical physics can describe many aspects of nature at an ordinary ([[macroscopic]] and [[Microscopic scale|(optical) microscopic]]) scale, but is not sufficient for describing them at very small [[submicroscopic]] (atomic and [[subatomic]]) scales. Classical mechanics can be derived from quantum mechanics as an approximation that is valid at ordinary scales.<ref>{{cite journal |last1=Jaeger |first1=Gregg |title=What in the (quantum) world is macroscopic? |journal=American Journal of Physics |date=September 2014 |volume=82 |issue=9 |pages=896–905 |doi=10.1119/1.4878358 |bibcode=2014AmJPh..82..896J}}</ref> Quantum systems have [[Bound state|bound]] states that are [[Quantization (physics)|quantized]] to [[Discrete mathematics|discrete values]] of [[energy]], [[momentum]], [[angular momentum]], and other quantities, in contrast to classical systems where these quantities can be measured continuously. Measurements of quantum systems show characteristics of both [[particle]]s and [[wave]]s ([[wave–particle duality]]), and there are limits to how accurately the value of a physical quantity can be predicted prior to its measurement, given a complete set of initial conditions (the [[uncertainty principle]]). Quantum mechanics [[History of quantum mechanics|arose gradually]] from theories to explain observations that could not be reconciled with classical physics, such as [[Max Planck]]'s solution in 1900 to the [[black-body radiation]] problem, and the correspondence between energy and frequency in [[Albert Einstein]]'s [[Annus Mirabilis papers#Photoelectric effect|1905 paper]], which explained the [[photoelectric effect]]. These early attempts to understand microscopic phenomena, now known as the "[[old quantum theory]]", led to the full development of quantum mechanics in the mid-1920s by [[Niels Bohr]], [[Erwin Schrödinger]], [[Werner Heisenberg]], [[Max Born]], [[Paul Dirac]] and others. The modern theory is formulated in various [[mathematical formulations of quantum mechanics|specially developed mathematical formalisms]]. In one of them, a mathematical entity called the [[wave function]] provides information, in the form of [[probability amplitude]]s, about what measurements of a particle's energy, momentum, and other physical properties may yield. == Overview and fundamental concepts == Quantum mechanics allows the calculation of properties and behaviour of [[physical systems]]. It is typically applied to microscopic systems: [[molecules]], [[atoms]] and [[subatomic particle]]s. It has been demonstrated to hold for complex molecules with thousands of atoms,<ref>{{cite journal |author=Fein |first1=Yaakov Y. |last2=Geyer |first2=Philipp |last3=Zwick |first3=Patrick |last4=Kiałka |first4=Filip |last5=Pedalino |first5=Sebastian |last6=Mayor |first6=Marcel |last7=Gerlich |first7=Stefan |last8=Arndt |first8=Markus |date=September 2019 |title=Quantum superposition of molecules beyond 25 kDa |journal=Nature Physics |volume=15 |issue=12 |pages=1242–1245 |bibcode=2019NatPh..15.1242F |doi=10.1038/s41567-019-0663-9 |s2cid=203638258}}</ref> but its application to human beings raises philosophical problems, such as [[Wigner's friend]], and its application to the universe as a whole remains speculative.<ref>{{cite journal |last1=Bojowald |first1=Martin |title=Quantum cosmology: a review |journal=Reports on Progress in Physics |date=2015 |volume=78 |issue=2 |page=023901 |doi=10.1088/0034-4885/78/2/023901 |pmid=25582917 |arxiv=1501.04899 |bibcode=2015RPPh...78b3901B |s2cid=18463042}}</ref> Predictions of quantum mechanics have been verified experimentally to an extremely high degree of [[accuracy]]. For example, the refinement of quantum mechanics for the interaction of light and matter, known as [[quantum electrodynamics]] (QED), has been [[Precision tests of QED|shown to agree with experiment]] to within 1 part in 10<sup>12</sup> when predicting the magnetic properties of an electron.<ref>{{cite journal |first1=X. |last1=Fan |first2=T. G. |last2=Myers |first3=B. A. D. |last3=Sukra |first4=G. |last4=Gabrielse |title=Measurement of the Electron Magnetic Moment |journal=Physical Review Letters |volume=130 |pages=071801 |date=2023-02-13 |issue=7 |doi=10.1103/PhysRevLett.130.071801 |pmid=36867820 |arxiv=2209.13084 |bibcode=2023PhRvL.130g1801F}}</ref> A fundamental feature of the theory is that it usually cannot predict with certainty what will happen, but only give probabilities. Mathematically, a probability is found by taking the square of the absolute value of a [[complex number]], known as a probability amplitude. This is known as the [[Born rule]], named after physicist [[Max Born]]. For example, a quantum particle like an [[electron]] can be described by a wave function, which associates to each point in space a probability amplitude. Applying the Born rule to these amplitudes gives a [[probability density function]] for the position that the electron will be found to have when an experiment is performed to measure it. This is the best the theory can do; it cannot say for certain where the electron will be found. The [[Schrödinger equation]] relates the collection of probability amplitudes that pertain to one moment of time to the collection of probability amplitudes that pertain to another.<ref name="Zwiebach2022" />{{rp|67–87}} One consequence of the mathematical rules of quantum mechanics is a tradeoff in predictability between measurable quantities. The most famous form of this [[uncertainty principle]] says that no matter how a quantum particle is prepared or how carefully experiments upon it are arranged, it is impossible to have a precise prediction for a measurement of its position and also at the same time for a measurement of its [[momentum]].<ref name="Zwiebach2022" />{{rp|427–435}} [[File:Double-slit.svg|thumb|left|upright=1.2|An illustration of the [[double-slit experiment]]]] Another consequence of the mathematical rules of quantum mechanics is the phenomenon of [[quantum interference]], which is often illustrated with the [[double-slit experiment]]. In the basic version of this experiment, a [[Coherence (physics)|coherent light source]], such as a [[laser]] beam, illuminates a plate pierced by two parallel slits, and the light passing through the slits is observed on a screen behind the plate.<ref name="Lederman">{{cite book |last1=Lederman |first1=Leon M. |url=https://books.google.com/books?id=qY_yOwHg_WYC&pg=PA102 |title=Quantum Physics for Poets |first2=Christopher T. |last2=Hill |publisher=Prometheus Books |year=2011 |isbn=978-1-61614-281-0 |location=US}}</ref>{{rp|102–111}}<ref name="Feynman" />{{rp|1.1–1.8}} The wave nature of light causes the light waves passing through the two slits to [[Interference (wave propagation)|interfere]], producing bright and dark bands on the screen – a result that would not be expected if light consisted of classical particles.<ref name="Lederman" /> However, the light is always found to be absorbed at the screen at discrete points, as individual particles rather than waves; the interference pattern appears via the varying density of these particle hits on the screen. Furthermore, versions of the experiment that include detectors at the slits find that each detected [[photon]] passes through one slit (as would a classical particle), and not through both slits (as would a wave).<ref name="Lederman" />{{rp|109}}<ref name="Müller-Kirsten">{{cite book |last=Müller-Kirsten |first=H. J. W. |url=https://books.google.com/books?id=p1_Z81Le58MC&pg=PA14 |title=Introduction to Quantum Mechanics: Schrödinger Equation and Path Integral |publisher=World Scientific |year=2006 |isbn=978-981-256-691-1 |location=US |page=14}}</ref><ref name="Plotnitsky">{{cite book |last=Plotnitsky |first=Arkady |url=https://books.google.com/books?id=dmdUp97S4AYC&pg=PA75 |title=Niels Bohr and Complementarity: An Introduction |publisher=Springer |year=2012 |isbn=978-1-4614-4517-3 |location=US |pages=75–76}}</ref> However, [[Double-slit experiment#Which way|such experiments]] demonstrate that particles do not form the interference pattern if one detects which slit they pass through. This behavior is known as [[wave–particle duality]]. In addition to light, [[electrons]], [[atoms]], and [[molecules]] are all found to exhibit the same dual behavior when fired towards a double slit.<ref name="Feynman" /> [[File:QuantumTunnel.jpg|left|thumb|upright=1.2|A simplified diagram of [[quantum tunneling]], a phenomenon by which a particle may move through a barrier which would be impossible under classical mechanics]] Another non-classical phenomenon predicted by quantum mechanics is [[quantum tunnelling]]: a particle that goes up against a [[potential barrier]] can cross it, even if its kinetic energy is smaller than the maximum of the potential.<ref>{{cite book |first=David J. |last=Griffiths |author-link=David J. Griffiths |title=Introduction to Quantum Mechanics |title-link=Introduction to Quantum Mechanics (book) |date=1995 |publisher=Prentice Hall |isbn=0-13-124405-1}}</ref> In classical mechanics this particle would be trapped. Quantum tunnelling has several important consequences, enabling [[radioactive decay]], [[nuclear fusion]] in stars, and applications such as [[scanning tunnelling microscopy]], [[tunnel diode]] and [[tunnel field-effect transistor]].<ref name="Trixler2013">{{cite journal |last=Trixler |first=F. |title=Quantum tunnelling to the origin and evolution of life |journal=Current Organic Chemistry |date=2013 |volume=17 |number=16 |pages=1758–1770 |doi=10.2174/13852728113179990083 |pmid=24039543 |pmc=3768233}}</ref><ref>{{Cite news |last=Phifer |first=Arnold |date=2012-03-27 |title=Developing more energy-efficient transistors through quantum tunneling |url=https://news.nd.edu/news/developing-more-energy-efficient-transistors-through-quantum-tunneling/ |access-date=2024-06-07 |work=Notre Dame News}}</ref> When quantum systems interact, the result can be the creation of [[quantum entanglement]]: their properties become so intertwined that a description of the whole solely in terms of the individual parts is no longer possible. Erwin Schrödinger called entanglement "...<em>the</em> characteristic trait of quantum mechanics, the one that enforces its entire departure from classical lines of thought".<ref>{{cite encyclopedia |url=https://plato.stanford.edu/entries/qt-entangle/ |first=Jeffrey |last=Bub |author-link=Jeffrey Bub |title=Quantum entanglement |encyclopedia=Stanford Encyclopedia of Philosophy |title-link=Stanford Encyclopedia of Philosophy |publisher=Metaphysics Research Lab, Stanford University |editor-first=Edward N. |editor-last=Zalta |year=2019}}</ref> Quantum entanglement enables [[quantum computing]] and is part of quantum communication protocols, such as [[quantum key distribution]] and [[superdense coding]].<ref name="Caves">{{cite book |first=Carlton M. |last=Caves |author-link=Carlton M. Caves |chapter=Quantum Information Science: Emerging No More |title=OSA Century of Optics |publisher=[[The Optical Society]] |arxiv=1302.1864 |bibcode=2013arXiv1302.1864C |year=2015 |isbn=978-1-943580-04-0 |pages=320–323 |editor-first1=Paul |editor-last1=Kelley |editor-first2=Govind |editor-last2=Agrawal |editor-first3=Mike |editor-last3=Bass |editor-first4=Jeff |editor-last4=Hecht |editor-first5=Carlos |editor-last5=Stroud}}</ref> Contrary to popular misconception, entanglement does not allow sending signals [[faster than light]], as demonstrated by the [[no-communication theorem]].<ref name="Caves" /> Another possibility opened by entanglement is testing for "[[hidden variable theory|hidden variables]]", hypothetical properties more fundamental than the quantities addressed in quantum theory itself, knowledge of which would allow more exact predictions than quantum theory provides. A collection of results, most significantly [[Bell's theorem]], have demonstrated that broad classes of such hidden-variable theories are in fact incompatible with quantum physics. According to Bell's theorem, if nature actually operates in accord with any theory of <em>local</em> hidden variables, then the results of a [[Bell test]] will be constrained in a particular, quantifiable way. Many Bell tests have been performed and they have shown results incompatible with the constraints imposed by local hidden variables.<ref name="wiseman15">{{Cite journal |last=Wiseman |first=Howard |author-link=Howard M. Wiseman |date=October 2015 |title=Death by experiment for local realism |journal=[[Nature (journal)|Nature]] |volume=526 |issue=7575 |pages=649–650 |doi=10.1038/nature15631 |pmid=26503054 |issn=0028-0836 |doi-access=free}}</ref><ref name="wolchover17">{{Cite magazine |url=https://www.quantamagazine.org/20170207-bell-test-quantum-loophole/ |title=Experiment Reaffirms Quantum Weirdness |last=Wolchover |first=Natalie |author-link=Natalie Wolchover |date=7 February 2017 |magazine=[[Quanta Magazine]] |access-date=8 February 2020}}</ref> It is not possible to present these concepts in more than a superficial way without introducing the mathematics involved; understanding quantum mechanics requires not only manipulating complex numbers, but also [[linear algebra]], [[differential equation]]s, [[group theory]], and other more advanced subjects.<ref>{{cite web |url=https://math.ucr.edu/home/baez/books.html |title=How to Learn Math and Physics |date=20 March 2020 |website=University of California, Riverside |access-date=19 December 2020 |first=John C. |last=Baez |author-link=John C. Baez |quote=there's no way to understand the interpretation of quantum mechanics without also being able to <em>solve quantum mechanics problems</em> – to understand the theory, you need to be able to use it (and vice versa)}}</ref><ref>{{cite book |first=Carl |last=Sagan |author-link=Carl Sagan |title=The Demon-Haunted World: Science as a Candle in the Dark |page=249 |publisher=Ballantine Books |year=1996 |isbn=0-345-40946-9 |title-link=The Demon-Haunted World |quote="For most physics students, (the "mathematical underpinning" of quantum mechanics) might occupy them from, say, third grade to early graduate school{{snd}}roughly 15 years. ... The job of the popularizer of science, trying to get across some idea of quantum mechanics to a general audience that has not gone through these initiation rites, is daunting. Indeed, there are no successful popularizations of quantum mechanics in my opinion{{snd}}partly for this reason.}}</ref> Accordingly, this article will present a mathematical formulation of quantum mechanics and survey its application to some useful and oft-studied examples. == Mathematical formulation == {{Main|Mathematical formulation of quantum mechanics}} In the mathematically rigorous formulation of quantum mechanics, the state of a quantum mechanical system is a vector <math>\psi</math> belonging to a ([[Separable space|separable]]) complex [[Hilbert space]] <math>\mathcal H</math>. This vector is postulated to be normalized under the Hilbert space inner product, that is, it obeys <math>\langle \psi,\psi \rangle = 1</math>, and it is well-defined up to a complex number of modulus 1 (the global phase), that is, <math>\psi</math> and <math>e^{i\alpha}\psi</math> represent the same physical system. In other words, the possible states are points in the [[projective space]] of a Hilbert space, usually called the [[complex projective space]]. The exact nature of this Hilbert space is dependent on the system – for example, for describing position and momentum the Hilbert space is the space of complex [[square-integrable]] functions <math>L^2(\mathbb C)</math>, while the Hilbert space for the [[Spin (physics)|spin]] of a single proton is simply the space of two-dimensional complex vectors <math>\mathbb C^2</math> with the usual inner product. Physical quantities of interest{{snd}}position, momentum, energy, spin{{snd}}are represented by observables, which are [[Hermitian adjoint#Hermitian operators|Hermitian]] (more precisely, [[self-adjoint operator|self-adjoint]]) linear [[Operator (physics)|operators]] acting on the Hilbert space. A quantum state can be an [[eigenvector]] of an observable, in which case it is called an [[eigenstate]], and the associated [[eigenvalue]] corresponds to the value of the observable in that eigenstate. More generally, a quantum state will be a linear combination of the eigenstates, known as a [[quantum superposition]]. When an observable is measured, the result will be one of its eigenvalues with probability given by the [[Born rule]]: in the simplest case the eigenvalue <math>\lambda</math> is non-degenerate and the probability is given by <math>|\langle \vec\lambda,\psi\rangle|^2</math>, where <math> \vec\lambda</math> is its associated unit-length eigenvector. More generally, the eigenvalue is degenerate and the probability is given by <math>\langle \psi,P_\lambda\psi\rangle</math>, where <math>P_\lambda</math> is the projector onto its associated eigenspace. In the continuous case, these formulas give instead the [[probability density]]. After the measurement, if result <math>\lambda</math> was obtained, the quantum state is postulated to [[Collapse of the wavefunction|collapse]] to <math> \vec\lambda</math>, in the non-degenerate case, or to <math display=inline>P_\lambda\psi\big/\! \sqrt{\langle \psi,P_\lambda\psi\rangle}</math>, in the general case. The [[probabilistic]] nature of quantum mechanics thus stems from the act of measurement. This is one of the most difficult aspects of quantum systems to understand. It was the central topic in the famous [[Bohr–Einstein debates]], in which the two scientists attempted to clarify these fundamental principles by way of [[thought experiment]]s. In the decades after the formulation of quantum mechanics, the question of what constitutes a "measurement" has been extensively studied. Newer [[interpretations of quantum mechanics]] have been formulated that do away with the concept of "[[wave function collapse]]" (see, for example, the [[many-worlds interpretation]]). The basic idea is that when a quantum system interacts with a measuring apparatus, their respective wave functions become [[Quantum entanglement|entangled]] so that the original quantum system ceases to exist as an independent entity (see ''[[Measurement in quantum mechanics]]''<ref name="google215">{{cite book |title=The Quantum Challenge: Modern Research on the Foundations of Quantum Mechanics |edition=2nd |first1=George |last1=Greenstein |first2=Arthur |last2=Zajonc |publisher=Jones and Bartlett |date=2006 |isbn=978-0-7637-2470-2 |page=215 |chapter-url=https://books.google.com/books?id=5t0tm0FB1CsC&pg=PA215 |chapter=8 Measurement |archive-url=https://web.archive.org/web/20230102102134/https://books.google.com/books?id=5t0tm0FB1CsC&pg=PA215 |archive-date=2023-01-02}}</ref>). === Time evolution of a quantum state === The time evolution of a quantum state is described by the Schrödinger equation: <math display=block>i\hbar {\frac {\partial}{\partial t}} \psi (t) =H \psi (t). </math> Here <math>H</math> denotes the [[Hamiltonian (quantum mechanics)|Hamiltonian]], the observable corresponding to the [[total energy]] of the system, and <math>\hbar</math> is the reduced [[Planck constant]]. The constant <math>i\hbar</math> is introduced so that the Hamiltonian is reduced to the [[Hamiltonian mechanics|classical Hamiltonian]] in cases where the quantum system can be approximated by a classical system; the ability to make such an approximation in certain limits is called the [[correspondence principle]]. The solution of this differential equation is given by <math display=block> \psi(t) = e^{-iHt/\hbar }\psi(0). </math> The operator <math>U(t) = e^{-iHt/\hbar } </math> is known as the time-evolution operator, and has the crucial property that it is [[Unitarity (physics)|unitary]]. This time evolution is [[deterministic]] in the sense that – given an initial quantum state <math>\psi(0)</math> – it makes a definite prediction of what the quantum state <math>\psi(t)</math> will be at any later time.<ref>{{cite book |title=Dreams Of A Final Theory: The Search for The Fundamental Laws of Nature |first1=Steven |last1=Weinberg |publisher=Random House |year=2010 |isbn=978-1-4070-6396-6 |page=[https://books.google.com/books?id=OLrZkgPsZR0C&pg=PT82 82] |url=https://books.google.com/books?id=OLrZkgPsZR0C}}</ref> {{anchor|fig1}} [[File:Atomic-orbital-clouds spd m0.png|thumb|upright=1.25|Fig. 1: [[Probability density function|Probability densities]] corresponding to the wave functions of an electron in a hydrogen atom possessing definite energy levels (increasing from the top of the image to the bottom: ''n'' = 1, 2, 3, ...) and angular momenta (increasing across from left to right: ''s'', ''p'', ''d'', ...). Denser areas correspond to higher probability density in a position measurement.{{pb}}Such wave functions are directly comparable to [[Chladni's figures]] of [[acoustics|acoustic]] modes of vibration in classical physics and are modes of oscillation as well, possessing a sharp energy and thus, a definite frequency. The [[angular momentum]] and energy are [[quantization (physics)|quantized]] and take <em>only</em> discrete values like those shown – as is the case for [[resonant frequencies]] in acoustics.]] Some wave functions produce probability distributions that are independent of time, such as [[eigenstate]]s of the Hamiltonian.<ref name="Zwiebach2022">{{cite book |first=Barton |last=Zwiebach |title=Mastering Quantum Mechanics: Essentials, Theory, and Applications |author-link=Barton Zwiebach |publisher=MIT Press |year=2022 |isbn=978-0-262-04613-8}}</ref>{{rp|133–137}} Many systems that are treated dynamically in classical mechanics are described by such "static" wave functions. For example, a single electron in an unexcited atom is pictured classically as a particle moving in a circular trajectory around the [[atomic nucleus]], whereas in quantum mechanics, it is described by a static wave function surrounding the nucleus. For example, the electron wave function for an unexcited hydrogen atom is a spherically symmetric function known as an [[atomic orbital|''s'' orbital]] ([[#fig1|Fig. 1]]). Analytic solutions of the Schrödinger equation are known for [[List of quantum-mechanical systems with analytical solutions|very few relatively simple model Hamiltonians]] including the [[quantum harmonic oscillator]], the [[particle in a box]], the [[dihydrogen cation]], and the [[hydrogen atom]]. Even the [[helium]] atom – which contains just two electrons – has defied all attempts at a fully analytic treatment, admitting no solution in [[Closed-form expression|closed form]].<ref>{{Cite journal |last1=Zhang |first1=Ruiqin |last2=Deng |first2=Conghao |date=1993 |title=Exact solutions of the Schrödinger equation for some quantum-mechanical many-body systems |journal=Physical Review A |volume=47 |issue=1 |pages=71–77 |doi=10.1103/PhysRevA.47.71 |pmid=9908895 |bibcode=1993PhRvA..47...71Z |issn=1050-2947}}</ref><ref>{{Cite journal |last1=Li |first1=Jing |last2=Drummond |first2=N. D. |last3=Schuck |first3=Peter |last4=Olevano |first4=Valerio |date=2019-04-01 |title=Comparing many-body approaches against the helium atom exact solution |journal=SciPost Physics |volume=6 |issue=4 |page=40 |doi=10.21468/SciPostPhys.6.4.040 |doi-access=free |arxiv=1801.09977 |bibcode=2019ScPP....6...40L |issn=2542-4653}}</ref><ref>{{cite book |last=Drake |first=Gordon W. F. |chapter=High Precision Calculations for Helium |date=2023 |title=Springer Handbook of Atomic, Molecular, and Optical Physics |series=Springer Handbooks |pages=199–216 |editor-last=Drake |editor-first=Gordon W. F. |place=Cham |publisher=Springer International Publishing |doi=10.1007/978-3-030-73893-8_12 |isbn=978-3-030-73892-1}}</ref> However, there are techniques for finding approximate solutions. One method, called [[perturbation theory (quantum mechanics)|perturbation theory]], uses the analytic result for a simple quantum mechanical model to create a result for a related but more complicated model by (for example) the addition of a weak [[potential energy]].<ref name="Zwiebach2022" />{{rp|793}} Another approximation method applies to systems for which quantum mechanics produces only small deviations from classical behavior. These deviations can then be computed based on the classical motion.<ref name="Zwiebach2022" />{{rp|849}} === Uncertainty principle === One consequence of the basic quantum formalism is the uncertainty principle. In its most familiar form, this states that no preparation of a quantum particle can imply simultaneously precise predictions both for a measurement of its position and for a measurement of its momentum.<ref name="Cohen-Tannoudji">{{cite book |last1=Cohen-Tannoudji |first1=Claude |last2=Diu |first2=Bernard |last3=Laloë |first3=Franck |title=Quantum Mechanics |author-link1=Claude Cohen-Tannoudji |publisher=John Wiley & Sons |year=2005 |isbn=0-471-16433-X |translator-first1=Susan Reid |translator-last1=Hemley |translator-first2=Nicole |translator-last2=Ostrowsky |translator-first3=Dan |translator-last3=Ostrowsky}}</ref><ref name="L&L">{{cite book |last1=Landau |first1=Lev D. |author-link1=Lev Landau |url=https://archive.org/details/QuantumMechanics_104 |title=Quantum Mechanics: Non-Relativistic Theory |last2=Lifschitz |first2=Evgeny M. |author-link2=Evgeny Lifshitz |publisher=[[Pergamon Press]] |year=1977 |isbn=978-0-08-020940-1 |edition=3rd |volume=3 |oclc=2284121}}</ref> Both position and momentum are observables, meaning that they are represented by [[Hermitian operators]]. The position operator <math>\hat{X}</math> and momentum operator <math>\hat{P}</math> do not commute, but rather satisfy the [[canonical commutation relation]]: <math display=block>[\hat{X}, \hat{P}] = i\hbar.</math> Given a quantum state, the Born rule lets us compute expectation values for both <math>X</math> and <math>P</math>, and moreover for powers of them. Defining the uncertainty for an observable by a [[standard deviation]], we have <math display=block>\sigma_X={\textstyle \sqrt{\left\langle X^2 \right\rangle - \left\langle X \right\rangle^2}},</math> and likewise for the momentum: <math display=block>\sigma_P=\sqrt{\left\langle P^2 \right\rangle - \left\langle P \right\rangle^2}.</math> The uncertainty principle states that <math display=block>\sigma_X \sigma_P \geq \frac{\hbar}{2}.</math> Either standard deviation can in principle be made arbitrarily small, but not both simultaneously.<ref name="ballentine1970">Section 3.2 of {{Citation |last=Ballentine |first=Leslie E. |title=The Statistical Interpretation of Quantum Mechanics |journal=Reviews of Modern Physics |volume=42 |issue=4 |pages=358–381 |year=1970 |bibcode=1970RvMP...42..358B |doi=10.1103/RevModPhys.42.358 |s2cid=120024263}}. This fact is experimentally well-known for example in quantum optics; see e.g. chap. 2 and Fig. 2.1 {{Citation |last=Leonhardt |first=Ulf |title=Measuring the Quantum State of Light |year=1997 |url=https://archive.org/details/measuringquantum0000leon |location=Cambridge |publisher=Cambridge University Press |bibcode=1997mqsl.book.....L |isbn=0-521-49730-2}}.</ref> This inequality generalizes to arbitrary pairs of self-adjoint operators <math>A</math> and <math>B</math>. The [[commutator]] of these two operators is <math display=block>[A,B]=AB-BA,</math> and this provides the lower bound on the product of standard deviations: <math display=block>\sigma_A \sigma_B \geq \tfrac12 \left|\bigl\langle[A,B]\bigr\rangle \right|.</math> Another consequence of the canonical commutation relation is that the position and momentum operators are [[Fourier transform#Uncertainty principle|Fourier transforms]] of each other, so that a description of an object according to its momentum is the Fourier transform of its description according to its position. The fact that dependence in momentum is the Fourier transform of the dependence in position means that the momentum operator is equivalent (up to an <math>i/\hbar</math> factor) to taking the derivative according to the position, since in Fourier analysis [[Fourier transform#Differentiation|differentiation corresponds to multiplication in the dual space]]. This is why in quantum equations in position space, the momentum <math> p_i</math> is replaced by <math>-i \hbar \frac {\partial}{\partial x}</math>, and in particular in the [[Schrödinger equation#Equation|non-relativistic Schrödinger equation in position space]] the momentum-squared term is replaced with a Laplacian times <math>-\hbar^2</math>.<ref name="Cohen-Tannoudji" /> === Composite systems and entanglement === When two different quantum systems are considered together, the Hilbert space of the combined system is the [[tensor product]] of the Hilbert spaces of the two components. For example, let {{mvar|A}} and {{mvar|B}} be two quantum systems, with Hilbert spaces <math> \mathcal H_A </math> and <math> \mathcal H_B </math>, respectively. The Hilbert space of the composite system is then <math display=block> \mathcal H_{AB} = \mathcal H_A \otimes \mathcal H_B.</math> If the state for the first system is the vector <math>\psi_A</math> and the state for the second system is <math>\psi_B</math>, then the state of the composite system is <math display=block>\psi_A \otimes \psi_B.</math> Not all states in the joint Hilbert space <math>\mathcal H_{AB}</math> can be written in this form, however, because the superposition principle implies that linear combinations of these "separable" or "product states" are also valid. For example, if <math>\psi_A</math> and <math>\phi_A</math> are both possible states for system <math>A</math>, and likewise <math>\psi_B</math> and <math>\phi_B</math> are both possible states for system <math>B</math>, then <math display=block>\tfrac{1}{\sqrt{2}} \left ( \psi_A \otimes \psi_B + \phi_A \otimes \phi_B \right )</math> is a valid joint state that is not separable. States that are not separable are called [[quantum entanglement|entangled]].<ref name=":0">{{Cite book |last1=Nielsen |first1=Michael A. |last2=Chuang |first2=Isaac L. |title=Quantum Computation and Quantum Information |publisher=Cambridge University Press |year=2010 |edition=2nd |oclc=844974180 |isbn=978-1-107-00217-3 |author-link1=Michael Nielsen |author-link2=Isaac Chuang}}</ref><ref name=":1">{{Cite book |title-link=Quantum Computing: A Gentle Introduction |title=Quantum Computing: A Gentle Introduction |last1=Rieffel |first1=Eleanor G. |last2=Polak |first2=Wolfgang H. |year=2011 |publisher=MIT Press |isbn=978-0-262-01506-6 |author-link=Eleanor Rieffel}}</ref> If the state for a composite system is entangled, it is impossible to describe either component system {{mvar|A}} or system {{mvar|B}} by a state vector. One can instead define [[reduced density matrix|reduced density matrices]] that describe the statistics that can be obtained by making measurements on either component system alone. This necessarily causes a loss of information, though: knowing the reduced density matrices of the individual systems is not enough to reconstruct the state of the composite system.<ref name=":0" /><ref name=":1" /> Just as density matrices specify the state of a subsystem of a larger system, analogously, [[POVM|positive operator-valued measures]] (POVMs) describe the effect on a subsystem of a measurement performed on a larger system. POVMs are extensively used in quantum information theory.<ref name=":0" /><ref name="wilde">{{Cite book |last=Wilde |first=Mark M. |title=Quantum Information Theory |publisher=Cambridge University Press |year=2017 |isbn=978-1-107-17616-4 |edition=2nd |doi=10.1017/9781316809976.001 |arxiv=1106.1445 |s2cid=2515538 |oclc=973404322}}</ref> As described above, entanglement is a key feature of models of measurement processes in which an apparatus becomes entangled with the system being measured. Systems interacting with the environment in which they reside generally become entangled with that environment, a phenomenon known as [[quantum decoherence]]. This can explain why, in practice, quantum effects are difficult to observe in systems larger than microscopic.<ref>{{Cite journal |last=Schlosshauer |first=Maximilian |date=October 2019 |title=Quantum decoherence |journal=Physics Reports |volume=831 |pages=1–57 |arxiv=1911.06282 |bibcode=2019PhR...831....1S |doi=10.1016/j.physrep.2019.10.001 |s2cid=208006050}}</ref> === Equivalence between formulations === There are many mathematically equivalent formulations of quantum mechanics. One of the oldest and most common is the "[[transformation theory (quantum mechanics)|transformation theory]]" proposed by [[Paul Dirac]], which unifies and generalizes the two earliest formulations of quantum mechanics – [[matrix mechanics]] (invented by [[Werner Heisenberg]]) and wave mechanics (invented by [[Erwin Schrödinger]]).<ref>{{cite journal |last=Rechenberg |first=Helmut |author-link=Helmut Rechenberg |year=1987 |title=Erwin Schrödinger and the creation of wave mechanics |url=http://www.actaphys.uj.edu.pl/fulltext?series=Reg&vol=19&page=683 |format=PDF |journal=[[Acta Physica Polonica B]] |volume=19 |issue=8 |pages=683–695 |access-date=13 June 2016}}</ref> An alternative formulation of quantum mechanics is [[Feynman]]'s [[path integral formulation]], in which a quantum-mechanical amplitude is considered as a sum over all possible classical and non-classical paths between the initial and final states. This is the quantum-mechanical counterpart of the [[action principle]] in classical mechanics.<ref>{{cite book |first1=Richard P. |last1=Feynman |first2=Albert R. |last2=Hibbs |title=Quantum Mechanics and Path Integrals |edition=Emended |editor-first=Daniel F. |editor-last=Steyer |year=2005 |publisher=McGraw-Hill |isbn=978-0-486-47722-0 |pages=v–vii}}</ref> === Symmetries and conservation laws === {{Main|Noether's theorem}} The Hamiltonian <math>H</math> is known as the ''generator'' of time evolution, since it defines a unitary time-evolution operator <math>U(t) = e^{-iHt/\hbar}</math> for each value of <math>t</math>. From this relation between <math>U(t)</math> and <math>H</math>, it follows that any observable <math>A</math> that commutes with <math>H</math> will be <em>conserved</em>: its expectation value will not change over time.<ref name="Zwiebach2022" />{{rp|471}} This statement generalizes, as mathematically, any Hermitian operator <math>A</math> can generate a family of unitary operators parameterized by a variable <math>t</math>. Under the evolution generated by <math>A</math>, any observable <math>B</math> that commutes with <math>A</math> will be conserved. Moreover, if <math>B</math> is conserved by evolution under <math>A</math>, then <math>A</math> is conserved under the evolution generated by <math>B</math>. This implies a quantum version of the result proven by [[Emmy Noether]] in classical ([[Lagrangian mechanics|Lagrangian]]) mechanics: for every [[differentiable]] [[Symmetry (physics)|symmetry]] of a Hamiltonian, there exists a corresponding [[conservation law]]. == Examples == === Free particle === {{Main|Free particle}} [[File:Guassian Dispersion.gif|360 px|thumb|right|Position space probability density of a Gaussian [[wave packet]] moving in one dimension in free space]] The simplest example of a quantum system with a position degree of freedom is a free particle in a single spatial dimension. A free particle is one which is not subject to external influences, so that its Hamiltonian consists only of its kinetic energy: <math display=block>H = \frac{1}{2m}P^2 = - \frac {\hbar ^2}{2m} \frac {d ^2}{dx^2}. </math> The general solution of the Schrödinger equation is given by <math display=block>\psi (x,t)=\frac {1}{\sqrt {2\pi }}\int _{-\infty}^\infty{\hat {\psi }}(k,0)e^{i(kx -\frac{\hbar k^2}{2m} t)}\mathrm{d}k,</math> which is a superposition of all possible [[plane wave]]s <math>e^{i(kx -\frac{\hbar k^2}{2m} t)}</math>, which are eigenstates of the momentum operator with momentum <math>p = \hbar k </math>. The coefficients of the superposition are <math> \hat {\psi }(k,0) </math>, which is the Fourier transform of the initial quantum state <math>\psi(x,0)</math>. It is not possible for the solution to be a single momentum eigenstate, or a single position eigenstate, as these are not normalizable quantum states.{{refn|group=note|A momentum eigenstate would be a perfectly monochromatic wave of infinite extent, which is not square-integrable. Likewise, a position eigenstate would be a [[Dirac delta distribution]], not square-integrable and technically not a function at all. Consequently, neither can belong to the particle's Hilbert space. Physicists sometimes introduce fictitious "bases" for a Hilbert space comprising elements outside that space. These are invented for calculational convenience and do not represent physical states.<ref name="Cohen-Tannoudji" />{{rp|100–105}}}} Instead, we can consider a Gaussian [[wave packet]]: <math display=block>\psi(x,0) = \frac{1}{\sqrt[4]{\pi a}}e^{-\frac{x^2}{2a}} </math> which has Fourier transform, and therefore momentum distribution <math display=block>\hat \psi(k,0) = \sqrt[4]{\frac{a}{\pi}}e^{-\frac{a k^2}{2}}. </math> We see that as we make <math>a</math> smaller the spread in position gets smaller, but the spread in momentum gets larger. Conversely, by making <math>a</math> larger we make the spread in momentum smaller, but the spread in position gets larger. This illustrates the uncertainty principle. As we let the Gaussian wave packet evolve in time, we see that its center moves through space at a constant velocity (like a classical particle with no forces acting on it). However, the wave packet will also spread out as time progresses, which means that the position becomes more and more uncertain. The uncertainty in momentum, however, stays constant.<ref>{{cite book |title=A Textbook of Quantum Mechanics |first1=Piravonu Mathews |last1=Mathews |first2=K. |last2=Venkatesan |publisher=Tata McGraw-Hill |year=1976 |isbn=978-0-07-096510-2 |page=[https://books.google.com/books?id=_qzs1DD3TcsC&pg=PA36 36] |chapter=The Schrödinger Equation and Stationary States |chapter-url=https://books.google.com/books?id=_qzs1DD3TcsC&pg=PA36}}</ref> === Particle in a box === [[File:Infinite potential well.svg|thumb|1-dimensional potential energy box (or infinite potential well)]] {{Main|Particle in a box}} The particle in a one-dimensional potential energy box is the most mathematically simple example where restraints lead to the quantization of energy levels. The box is defined as having zero potential energy everywhere <em>inside</em> a certain region, and therefore infinite potential energy everywhere <em>outside</em> that region.<ref name="Cohen-Tannoudji" />{{Rp|77–78}} For the one-dimensional case in the <math>x</math> direction, the time-independent Schrödinger equation may be written <math display=block> - \frac {\hbar ^2}{2m} \frac {d ^2 \psi}{dx^2} = E \psi.</math> With the differential operator defined by <math display=block> \hat{p}_x = -i\hbar\frac{d}{dx} </math>the previous equation is evocative of the [[Kinetic energy#Kinetic energy of rigid bodies|classic kinetic energy analogue]], <math display=block> \frac{1}{2m} \hat{p}_x^2 = E,</math> with state <math>\psi</math> in this case having energy <math>E</math> coincident with the kinetic energy of the particle. The general solutions of the Schrödinger equation for the particle in a box are <math display=block> \psi(x) = A e^{ikx} + B e ^{-ikx} \qquad\qquad E = \frac{\hbar^2 k^2}{2m}</math> or, from [[Euler's formula]], <math display=block> \psi(x) = C \sin(kx) + D \cos(kx).\!</math> The infinite potential walls of the box determine the values of <math>C, D, </math> and <math>k</math> at <math>x=0</math> and <math>x=L</math> where <math>\psi</math> must be zero. Thus, at <math>x=0</math>, <math display=block>\psi(0) = 0 = C\sin(0) + D\cos(0) = D</math> and <math>D=0</math>. At <math>x=L</math>, <math display=block> \psi(L) = 0 = C\sin(kL),</math> in which <math>C</math> cannot be zero as this would conflict with the postulate that <math>\psi</math> has norm 1. Therefore, since <math>\sin(kL)=0</math>, <math>kL</math> must be an integer multiple of <math>\pi</math>, <math display=block>k = \frac{n\pi}{L}\qquad\qquad n=1,2,3,\ldots.</math> This constraint on <math>k</math> implies a constraint on the energy levels, yielding <math display=block>E_n = \frac{\hbar^2 \pi^2 n^2}{2mL^2} = \frac{n^2h^2}{8mL^2}.</math> A [[finite potential well]] is the generalization of the infinite potential well problem to potential wells having finite depth. The finite potential well problem is mathematically more complicated than the infinite particle-in-a-box problem as the wave function is not pinned to zero at the walls of the well. Instead, the wave function must satisfy more complicated mathematical boundary conditions as it is nonzero in regions outside the well. Another related problem is that of the [[rectangular potential barrier]], which furnishes a model for the [[quantum tunneling]] effect that plays an important role in the performance of modern technologies such as [[flash memory]] and [[scanning tunneling microscopy]]. === Harmonic oscillator === {{Main|Quantum harmonic oscillator}} [[File:QuantumHarmonicOscillatorAnimation.gif|thumb|upright=1.35|right|Some trajectories of a [[harmonic oscillator]] (i.e. a ball attached to a [[Hooke's law|spring]]) in [[classical mechanics]] (A-B) and quantum mechanics (C-H). In quantum mechanics, the position of the ball is represented by a [[wave]] (called the wave function), with the [[real part]] shown in blue and the [[imaginary part]] shown in red. Some of the trajectories (such as C, D, E, and F) are [[standing wave]]s (or "[[stationary state]]s"). Each standing-wave frequency is proportional to a possible [[energy level]] of the oscillator. This "energy quantization" does not occur in classical physics, where the oscillator can have ''any'' energy.]] As in the classical case, the potential for the quantum harmonic oscillator is given by<ref name="Zwiebach2022" />{{rp|234}} <math display=block>V(x)=\frac{1}{2}m\omega^2x^2.</math> This problem can either be treated by directly solving the Schrödinger equation, which is not trivial, or by using the more elegant "ladder method" first proposed by Paul Dirac. The [[eigenstate]]s are given by <math display=block> \psi_n(x) = \sqrt{\frac{1}{2^n\, n!}} \cdot \left(\frac{m\omega}{\pi \hbar}\right)^{1/4} \cdot e^{ - \frac{m\omega x^2}{2 \hbar}} \cdot H_n\left(\sqrt{\frac{m\omega}{\hbar}} x \right), \qquad </math> <math display=block>n = 0,1,2,\ldots. </math> where ''H<sub>n</sub>'' are the [[Hermite polynomials]] <math display=block>H_n(x)=(-1)^n e^{x^2}\frac{d^n}{dx^n}\left(e^{-x^2}\right),</math> and the corresponding energy levels are <math display=block> E_n = \hbar \omega \left(n + {1\over 2}\right).</math> This is another example illustrating the discretization of energy for [[bound state]]s. === Mach–Zehnder interferometer === [[File:Mach-Zehnder interferometer.svg|upright=1.3|thumb|right|Schematic of a Mach–Zehnder interferometer]] The [[Mach–Zehnder interferometer]] (MZI) illustrates the concepts of superposition and interference with linear algebra in dimension 2, rather than differential equations. It can be seen as a simplified version of the double-slit experiment, but it is of interest in its own right, for example in the [[delayed choice quantum eraser]], the [[Elitzur–Vaidman bomb tester]], and in studies of quantum entanglement.<ref name=Paris1999>{{cite journal |last=Paris |first=M. G. A. |title=Entanglement and visibility at the output of a Mach–Zehnder interferometer |journal=[[Physical Review A]] |date=1999 |volume=59 |issue=2 |pages=1615–1621 |arxiv=quant-ph/9811078 |bibcode=1999PhRvA..59.1615P |doi=10.1103/PhysRevA.59.1615 |s2cid=13963928}}</ref><ref name=Haack2010>{{Cite journal |last1=Haack |first1=G. R. |last2=Förster |first2=H. |last3=Büttiker |first3=M. |title=Parity detection and entanglement with a Mach-Zehnder interferometer |doi=10.1103/PhysRevB.82.155303 |journal=[[Physical Review B]] |volume=82 |issue=15 |pages=155303 |year=2010 |arxiv=1005.3976 |bibcode=2010PhRvB..82o5303H |s2cid=119261326}}</ref> We can model a photon going through the interferometer by considering that at each point it can be in a superposition of only two paths: the "lower" path which starts from the left, goes straight through both beam splitters, and ends at the top, and the "upper" path which starts from the bottom, goes straight through both beam splitters, and ends at the right. The quantum state of the photon is therefore a vector <math>\psi \in \mathbb{C}^2</math> that is a superposition of the "lower" path <math>\psi_l = \begin{pmatrix} 1 \\ 0 \end{pmatrix}</math> and the "upper" path <math>\psi_u = \begin{pmatrix} 0 \\ 1 \end{pmatrix}</math>, that is, <math>\psi = \alpha \psi_l + \beta \psi_u</math> for complex <math>\alpha,\beta</math>. In order to respect the postulate that <math>\langle \psi,\psi\rangle = 1</math> we require that <math>|\alpha|^2+|\beta|^2 = 1</math>. Both [[beam splitter]]s are modelled as the unitary matrix <math>B = \frac1{\sqrt2}\begin{pmatrix} 1 & i \\ i & 1 \end{pmatrix}</math>, which means that when a photon meets the beam splitter it will either stay on the same path with a probability amplitude of <math>1/\sqrt{2}</math>, or be reflected to the other path with a probability amplitude of <math>i/\sqrt{2}</math>. The phase shifter on the upper arm is modelled as the unitary matrix <math>P = \begin{pmatrix} 1 & 0 \\ 0 & e^{i\Delta\Phi} \end{pmatrix}</math>, which means that if the photon is on the "upper" path it will gain a relative phase of <math>\Delta\Phi</math>, and it will stay unchanged if it is in the lower path. A photon that enters the interferometer from the left will then be acted upon with a beam splitter <math>B</math>, a phase shifter <math>P</math>, and another beam splitter <math>B</math>, and so end up in the state <math display=block>BPB\psi_l = ie^{i\Delta\Phi/2} \begin{pmatrix} -\sin(\Delta\Phi/2) \\ \cos(\Delta\Phi/2) \end{pmatrix},</math> and the probabilities that it will be detected at the right or at the top are given respectively by <math display=block> p(u) = |\langle \psi_u, BPB\psi_l \rangle|^2 = \cos^2 \frac{\Delta \Phi}{2},</math> <math display=block> p(l) = |\langle \psi_l, BPB\psi_l \rangle|^2 = \sin^2 \frac{\Delta \Phi}{2}.</math> One can therefore use the Mach–Zehnder interferometer to estimate the [[Phase (waves)|phase shift]] by estimating these probabilities. It is interesting to consider what would happen if the photon were definitely in either the "lower" or "upper" paths between the beam splitters. This can be accomplished by blocking one of the paths, or equivalently by removing the first beam splitter (and feeding the photon from the left or the bottom, as desired). In both cases, there will be no interference between the paths anymore, and the probabilities are given by <math>p(u)=p(l) = 1/2</math>, independently of the phase <math>\Delta\Phi</math>. From this we can conclude that the photon does not take one path or another after the first beam splitter, but rather that it is in a genuine quantum superposition of the two paths.<ref name="vedral">{{cite book |first=Vlatko |last=Vedral |title=Introduction to Quantum Information Science |date=2006 |publisher=Oxford University Press |isbn=978-0-19-921570-6 |oclc=442351498 |author-link=Vlatko Vedral}}</ref> == Applications == {{Main|Applications of quantum mechanics}} Quantum mechanics has had enormous success in explaining many of the features of our universe, with regard to small-scale and discrete quantities and interactions which cannot be explained by [[Classical physics|classical methods]].{{refn|name= feynmanIII |group=note|See, for example, [[the Feynman Lectures on Physics]] for some of the technological applications which use quantum mechanics, e.g., [[transistor]]s (vol '''III''', pp. 14–11 ff), [[integrated circuit]]s, which are follow-on technology in solid-state physics (vol '''II''', pp. 8–6), and [[laser]]s (vol '''III''', pp. 9–13).}} Quantum mechanics is often the only theory that can reveal the individual behaviors of the subatomic particles that make up all forms of matter (electrons, [[proton]]s, [[neutron]]s, [[photon]]s, and others). [[Solid-state physics]] and [[materials science]] are dependent upon quantum mechanics.<ref name=marvincohen2008>{{cite journal |last=Cohen |first=Marvin L. |title=Essay: Fifty Years of Condensed Matter Physics |journal=Physical Review Letters |year=2008 |volume=101 |issue=25 |doi=10.1103/PhysRevLett.101.250001 |url=http://prl.aps.org/edannounce/PhysRevLett.101.250001 |access-date=31 March 2012 |bibcode=2008PhRvL.101y0001C |pmid=19113681 |page=250001}}</ref> In many aspects, modern technology operates at a scale where quantum effects are significant. Important applications of quantum theory include [[quantum chemistry]], [[quantum optics]], [[quantum computing]], [[superconducting magnet]]s, [[light-emitting diode]]s, the [[optical amplifier]] and the laser, the [[transistor]] and [[semiconductor]]s such as the [[microprocessor]], [[medical imaging|medical and research imaging]] such as [[magnetic resonance imaging]] and [[electron microscopy]].<ref>{{cite magazine |last1=Matson |first1=John |title=What Is Quantum Mechanics Good for? |url=http://www.scientificamerican.com/article/everyday-quantum-physics/ |magazine=Scientific American |access-date=18 May 2016}}</ref> Explanations for many biological and physical phenomena are rooted in the nature of the chemical bond, most notably the macro-molecule [[DNA]]. == Relation to other scientific theories == {{Modern physics}} === Classical mechanics === The rules of quantum mechanics assert that the state space of a system is a Hilbert space and that observables of the system are Hermitian operators acting on vectors in that space – although they do not tell us which Hilbert space or which operators. These can be chosen appropriately in order to obtain a quantitative description of a quantum system, a necessary step in making physical predictions. An important guide for making these choices is the [[correspondence principle]], a heuristic which states that the predictions of quantum mechanics reduce to those of [[classical mechanics]] in the regime of large [[quantum number]]s.<ref name="Tipler">{{cite book |last1=Tipler |first1=Paul |last2=Llewellyn |first2=Ralph |title=Modern Physics |edition=5th |year=2008 |publisher=W. H. Freeman and Company |isbn=978-0-7167-7550-8 |pages=160–161}}</ref> One can also start from an established classical model of a particular system, and then try to guess the underlying quantum model that would give rise to the classical model in the correspondence limit. This approach is known as [[Canonical quantization|quantization]].<ref name="Peres1993">{{cite book |last=Peres |first=Asher |author-link=Asher Peres |title=Quantum Theory: Concepts and Methods |title-link=Quantum Theory: Concepts and Methods |publisher=Kluwer |year=1993 |isbn=0-7923-2549-4}}</ref>{{rp|299}}<ref>{{cite magazine |first=John C. |last=Baez |author-link=John C. Baez |url=https://nautil.us/the-math-that-takes-newton-into-the-quantum-world-237339/ |title=The Math That Takes Newton Into the Quantum World |magazine=[[Nautilus Quarterly]] |date=2019-02-26 |access-date=2024-03-23}}</ref> When quantum mechanics was originally formulated, it was applied to models whose correspondence limit was [[theory of relativity|non-relativistic]] classical mechanics. For instance, the well-known model of the [[quantum harmonic oscillator]] uses an explicitly non-relativistic expression for the [[kinetic energy]] of the oscillator, and is thus a quantum version of the [[harmonic oscillator|classical harmonic oscillator]].<ref name="Zwiebach2022" />{{rp|234}} Complications arise with [[chaotic systems]], which do not have good quantum numbers, and [[quantum chaos]] studies the relationship between classical and quantum descriptions in these systems.<ref name="Peres1993" />{{rp|353}} [[Quantum decoherence]] is a mechanism through which quantum systems lose [[quantum coherence|coherence]], and thus become incapable of displaying many typically quantum effects: [[quantum superposition]]s become simply probabilistic mixtures, and quantum entanglement becomes simply classical correlations.<ref name="Zwiebach2022" />{{rp|687-730}} Quantum coherence is not typically evident at macroscopic scales, though at temperatures approaching [[absolute zero]] quantum behavior may manifest macroscopically.{{refn|group=note|See ''[[Macroscopic quantum phenomena]]'', ''[[Bose–Einstein condensate]]'', and ''[[Quantum machine]]''}} Many macroscopic properties of a classical system are a direct consequence of the quantum behavior of its parts. For example, the stability of bulk matter (consisting of atoms and [[molecule]]s which would quickly collapse under electric forces alone), the rigidity of solids, and the mechanical, thermal, chemical, optical and magnetic properties of matter are all results of the interaction of [[electric charge]]s under the rules of quantum mechanics.<ref>{{cite web |url=http://academic.brooklyn.cuny.edu/physics/sobel/Nucphys/atomprop.html |title=Atomic Properties |publisher=Academic.brooklyn.cuny.edu |access-date=18 August 2012}}</ref> === Special relativity and electrodynamics === Early attempts to merge quantum mechanics with [[special relativity]] involved the replacement of the Schrödinger equation with a covariant equation such as the [[Klein–Gordon equation]] or the [[Dirac equation]]. While these theories were successful in explaining many experimental results, they had certain unsatisfactory qualities stemming from their neglect of the relativistic creation and annihilation of particles. A fully relativistic quantum theory required the development of quantum field theory, which applies quantization to a field (rather than a fixed set of particles). The first complete quantum field theory, [[quantum electrodynamics]], provides a fully quantum description of the [[electromagnetic interaction]]. Quantum electrodynamics is, along with [[general relativity]], one of the most accurate physical theories ever devised.<ref>{{cite book |url=https://books.google.com/books?id=6a-agBFWuyQC&pg=PA61 |title=The Nature of Space and Time |date=2010 |isbn=978-1-4008-3474-7 |last1=Hawking |first1=Stephen |last2=Penrose |first2=Roger |publisher=Princeton University Press}}</ref><ref>{{cite journal |last1=Aoyama |first1=Tatsumi |last2=Hayakawa |first2=Masashi |last3=Kinoshita |first3=Toichiro |last4=Nio |first4=Makiko |year=2012 |title=Tenth-Order QED Contribution to the Electron g-2 and an Improved Value of the Fine Structure Constant |journal=[[Physical Review Letters]] |volume=109 |issue=11 |page=111807 |arxiv=1205.5368 |bibcode=2012PhRvL.109k1807A |doi=10.1103/PhysRevLett.109.111807 |pmid=23005618 |s2cid=14712017}}</ref> The full apparatus of quantum field theory is often unnecessary for describing electrodynamic systems. A simpler approach, one that has been used since the inception of quantum mechanics, is to treat [[electric charge|charged]] particles as quantum mechanical objects being acted on by a classical [[electromagnetic field]]. For example, the elementary quantum model of the [[hydrogen atom]] describes the [[electric field]] of the hydrogen atom using a classical <math>\textstyle -e^2/(4 \pi\epsilon_{_0}r)</math> [[Electric potential|Coulomb potential]].<ref name="Zwiebach2022" />{{rp|285}} Likewise, in a [[Stern–Gerlach experiment]], a charged particle is modeled as a quantum system, while the background magnetic field is described classically.<ref name="Peres1993" />{{rp|26}} This "semi-classical" approach fails if quantum fluctuations in the electromagnetic field play an important role, such as in the emission of photons by [[charged particle]]s. [[Field (physics)|Quantum field]] theories for the [[strong nuclear force]] and the [[weak nuclear force]] have also been developed. The quantum field theory of the strong nuclear force is called [[quantum chromodynamics]], and describes the interactions of subnuclear particles such as [[quark]]s and [[gluon]]s. The weak nuclear force and the electromagnetic force were unified, in their quantized forms, into a single quantum field theory (known as [[electroweak theory]]), by the physicists [[Abdus Salam]], [[Sheldon Glashow]] and [[Steven Weinberg]].<ref>{{cite web |url=http://nobelprize.org/nobel_prizes/physics/laureates/1979/index.html |title=The Nobel Prize in Physics 1979 |publisher=Nobel Foundation |access-date=16 December 2020}}</ref> === Relation to general relativity === Even though the predictions of both quantum theory and general relativity have been supported by rigorous and repeated [[empirical evidence]], their abstract formalisms contradict each other and they have proven extremely difficult to incorporate into one consistent, cohesive model. Gravity is negligible in many areas of particle physics, so that unification between general relativity and quantum mechanics is not an urgent issue in those particular applications. However, the lack of a correct theory of [[quantum gravity]] is an important issue in [[physical cosmology]] and the search by physicists for an elegant "[[Theory of Everything]]" (TOE). Consequently, resolving the inconsistencies between both theories has been a major goal of 20th- and 21st-century physics. This TOE would combine not only the models of subatomic physics but also derive the four fundamental forces of nature from a single force or phenomenon.<ref name="NYT-20221010">{{cite news |last=Overbye |first=Dennis |author-link=Dennis Overbye |title=Black Holes May Hide a Mind-Bending Secret About Our Universe – Take gravity, add quantum mechanics, stir. What do you get? Just maybe, a holographic cosmos |url=https://www.nytimes.com/2022/10/10/science/black-holes-cosmology-hologram.html |date=10 October 2022 |work=[[The New York Times]] |access-date=10 October 2022}}</ref> [[File:String Vibrations.gif|thumb|upright=0.8|In [[string theory]], particles are re-conceived of as strings, with properties such as mass and charge determined by the string's vibrational state.]] One proposal for doing so is [[string theory]], which posits that the [[Point particle|point-like particles]] of [[particle physics]] are replaced by [[Dimension (mathematics and physics)|one-dimensional]] objects called [[String (physics)|strings]]. String theory describes how these strings propagate through space and interact with each other. On distance scales larger than the string scale, a string looks just like an ordinary particle, with its [[mass]], [[charge (physics)|charge]], and other properties determined by the [[vibration]]al state of the string. In string theory, one of the many vibrational states of the string corresponds to the [[graviton]], a quantum mechanical particle that carries gravitational force.<ref>{{cite book |last1=Becker |first1=Katrin |last2=Becker |first2=Melanie |author-link2=Melanie Becker |last3=Schwarz |first3=John |title=String theory and M-theory: A modern introduction |date=2007 |publisher=Cambridge University Press |isbn=978-0-521-86069-7}}</ref><ref>{{cite book |last1=Zwiebach |first1=Barton |title=A First Course in String Theory |date=2009 |publisher=Cambridge University Press |isbn=978-0-521-88032-9 |author-link=Barton Zwiebach}}</ref> Another popular theory is [[loop quantum gravity]] (LQG), which describes quantum properties of gravity and is thus a theory of [[quantum spacetime]]. LQG is an attempt to merge and adapt standard quantum mechanics and standard general relativity. This theory describes space as an extremely fine fabric "woven" of finite loops called [[spin network]]s. The evolution of a spin network over time is called a [[spin foam]]. The characteristic length scale of a spin foam is the [[Planck length]], approximately 1.616×10<sup>−35</sup> m, and so lengths shorter than the Planck length are not physically meaningful in LQG.<ref>{{Cite book |last1=Rovelli |first1=Carlo |url=https://books.google.com/books?id=w6z0BQAAQBAJ |title=Covariant Loop Quantum Gravity: An Elementary Introduction to Quantum Gravity and Spinfoam Theory |last2=Vidotto |first2=Francesca |year=2014 |publisher=Cambridge University Press |isbn=978-1-316-14811-2}}</ref> == Philosophical implications == {{Main|Interpretations of quantum mechanics}} {{unsolved|physics|Is there a preferred interpretation of quantum mechanics? How does the quantum description of reality, which includes elements such as the "[[superposition principle|superposition]] of states" and "[[wave function collapse]]", give rise to the reality we perceive?}} Since its inception, the many counter-intuitive aspects and results of quantum mechanics have provoked strong [[philosophical]] debates and many [[interpretations of quantum mechanics|interpretations]]. The arguments centre on the probabilistic nature of quantum mechanics, the difficulties with [[wavefunction collapse]] and the related [[measurement problem]], and [[quantum nonlocality]]. Perhaps the only consensus that exists about these issues is that there is no consensus. [[Richard Feynman]] once said, "I think I can safely say that nobody understands quantum mechanics."<ref>{{Cite book |last=Feynman |first=Richard |title=The Character of Physical Law |title-link=The Character of Physical Law |publisher=MIT Press |year=1967 |isbn=0-262-56003-8 |pages=129 |author-link=Richard Feynman}}</ref> According to [[Steven Weinberg]], "There is now in my opinion no entirely satisfactory interpretation of quantum mechanics."<ref>{{Cite journal |arxiv=1109.6462 |doi=10.1103/PhysRevA.85.062116 |title=Collapse of the state vector |journal=Physical Review A |volume=85 |issue=6 |pages=062116 |year=2012 |last1=Weinberg |first1=Steven |bibcode=2012PhRvA..85f2116W |s2cid=119273840}}</ref> The views of [[Niels Bohr]], Werner Heisenberg and other physicists are often grouped together as the "[[Copenhagen interpretation]]".<ref>{{Cite journal |last=Howard |first=Don |date=December 2004 |title=Who Invented the 'Copenhagen Interpretation'? A Study in Mythology |url=https://www.journals.uchicago.edu/doi/10.1086/425941 |journal=Philosophy of Science |volume=71 |issue=5 |pages=669–682 |doi=10.1086/425941 |s2cid=9454552 |issn=0031-8248}}</ref><ref>{{Cite journal |last=Camilleri |first=Kristian |date=May 2009 |title=Constructing the Myth of the Copenhagen Interpretation |url=http://www.mitpressjournals.org/doi/10.1162/posc.2009.17.1.26 |journal=Perspectives on Science |volume=17 |issue=1 |pages=26–57 |doi=10.1162/posc.2009.17.1.26 |s2cid=57559199 |issn=1063-6145}}</ref> According to these views, the probabilistic nature of quantum mechanics is not a <em>temporary</em> feature which will eventually be replaced by a deterministic theory, but is instead a <em>final</em> renunciation of the classical idea of "causality". Bohr in particular emphasized that any well-defined application of the quantum mechanical formalism must always make reference to the experimental arrangement, due to the [[complementarity (physics)|complementary]] nature of evidence obtained under different experimental situations. Copenhagen-type interpretations were adopted by Nobel laureates in quantum physics, including Bohr,<ref name="BohrComo">{{Cite journal |last1=Bohr |first1=Neils |author-link=Niels Bohr |year=1928 |title=The Quantum Postulate and the Recent Development of Atomic Theory |journal=Nature |volume=121 |issue=3050 |pages=580–590 |bibcode=1928Natur.121..580B |doi=10.1038/121580a0 |doi-access=free}}</ref> Heisenberg,<ref>{{Cite book |last=Heisenberg |first=Werner |author-link=Werner Heisenberg |title=Physics and philosophy: the revolution in modern science |date=1971 |publisher=Allen & Unwin |isbn=978-0-04-530016-7 |edition=3 |series=World perspectives |location=London |oclc=743037461}}</ref> Schrödinger,<ref>{{Cite journal |last=Schrödinger |first=Erwin |year=1980 |orig-date=1935 |editor-last=Trimmer |editor-first=John |title=Die gegenwärtige Situation in der Quantenmechanik |trans-title=The Present Situation in Quantum Mechanics |journal=Naturwissenschaften |volume=23 |issue=50 |pages=844–849 |doi=10.1007/BF01491987 |jstor=986572 |s2cid=22433857 |language=de}}</ref> Feynman,<ref name="Feynman" /> and [[Anton Zeilinger|Zeilinger]]<ref name=MaKoflerZeilinger>{{Cite journal |last1=Ma |first1=Xiao-song |last2=Kofler |first2=Johannes |last3=Zeilinger |first3=Anton |date=2016-03-03 |title=Delayed-choice gedanken experiments and their realizations |journal=Reviews of Modern Physics |volume=88 |issue=1 |page=015005 |doi=10.1103/RevModPhys.88.015005 |issn=0034-6861 |arxiv=1407.2930 |bibcode=2016RvMP...88a5005M |s2cid=34901303}}</ref> as well as 21st-century researchers in quantum foundations.<ref name=":25">{{Cite journal |last1=Schlosshauer |first1=Maximilian |last2=Kofler |first2=Johannes |last3=Zeilinger |first3=Anton |date=1 August 2013 |title=A snapshot of foundational attitudes toward quantum mechanics |journal=Studies in History and Philosophy of Science Part B |volume=44 |issue=3 |pages=222–230 |arxiv=1301.1069 |bibcode=2013SHPMP..44..222S |doi=10.1016/j.shpsb.2013.04.004 |s2cid=55537196}}</ref> [[Albert Einstein]], himself one of the founders of [[Old quantum theory|quantum theory]], was troubled by its apparent failure to respect some cherished metaphysical principles, such as [[determinism]] and [[principle of locality|locality]]. Einstein's long-running exchanges with Bohr about the meaning and status of quantum mechanics are now known as the [[Bohr–Einstein debates]]. Einstein believed that underlying quantum mechanics must be a theory that explicitly forbids [[action at a distance]]. He argued that quantum mechanics was incomplete, a theory that was valid but not fundamental, analogous to how [[thermodynamics]] is valid, but the fundamental theory behind it is [[statistical mechanics]]. In 1935, Einstein and his collaborators [[Boris Podolsky]] and [[Nathan Rosen]] published an argument that the principle of locality implies the incompleteness of quantum mechanics, a [[thought experiment]] later termed the [[Einstein–Podolsky–Rosen paradox]].{{refn|group=note|The published form of the EPR argument was due to Podolsky, and Einstein himself was not satisfied with it. In his own publications and correspondence, Einstein used a different argument to insist that quantum mechanics is an incomplete theory.<ref name="spekkens">{{cite journal |author2-link=Robert Spekkens |first1=Nicholas |last1=Harrigan |first2=Robert W. |last2=Spekkens |title=Einstein, incompleteness, and the epistemic view of quantum states |journal=[[Foundations of Physics]] |volume=40 |issue=2 |pages=125 |year=2010 |doi=10.1007/s10701-009-9347-0 |arxiv=0706.2661 |bibcode=2010FoPh...40..125H |s2cid=32755624}}</ref><ref name="howard">{{cite journal |last1=Howard |first1=D. |title=Einstein on locality and separability |journal=Studies in History and Philosophy of Science Part A |date=1985 |volume=16 |issue=3 |pages=171–201 |doi=10.1016/0039-3681(85)90001-9 |bibcode=1985SHPSA..16..171H}}</ref><ref>{{Cite journal |last=Sauer |first=Tilman |date=1 December 2007 |title=An Einstein manuscript on the EPR paradox for spin observables |url=http://philsci-archive.pitt.edu/3222/ |journal=Studies in History and Philosophy of Science Part B: Studies in History and Philosophy of Modern Physics |volume=38 |issue=4 |pages=879–887 |doi=10.1016/j.shpsb.2007.03.002 |issn=1355-2198 |bibcode=2007SHPMP..38..879S |citeseerx=10.1.1.571.6089}}</ref><ref>{{cite encyclopedia |last=Einstein |first=Albert |title=Autobiographical Notes |encyclopedia=Albert Einstein: Philosopher-Scientist |year=1949 |publisher=Open Court Publishing Company |editor-last=Schilpp |editor-first=Paul Arthur}}</ref>}} In 1964, [[John Stewart Bell|John Bell]] showed that EPR's principle of locality, together with determinism, was actually incompatible with quantum mechanics: they implied constraints on the correlations produced by distance systems, now known as [[Bell inequalities]], that can be violated by entangled particles.<ref>{{Cite journal |last=Bell |first=John Stewart |author-link=John Stewart Bell |date=1 November 1964 |title=On the Einstein Podolsky Rosen paradox |journal=[[Physics Physique Fizika]] |volume=1 |issue=3 |pages=195–200 |doi=10.1103/PhysicsPhysiqueFizika.1.195 |doi-access=free}}</ref> Since then [[Bell test|several experiments]] have been performed to obtain these correlations, with the result that they do in fact violate Bell inequalities, and thus falsify the conjunction of locality with determinism.<ref name="wiseman15" /><ref name="wolchover17" /> [[Bohmian mechanics]] shows that it is possible to reformulate quantum mechanics to make it deterministic, at the price of making it explicitly nonlocal. It attributes not only a wave function to a physical system, but in addition a real position, that evolves deterministically under a nonlocal guiding equation. The evolution of a physical system is given at all times by the Schrödinger equation together with the guiding equation; there is never a collapse of the wave function. This solves the measurement problem.<ref>{{cite encyclopedia |url=https://plato.stanford.edu/entries/qm-bohm/ |last=Goldstein |first=Sheldon |title=Bohmian Mechanics |encyclopedia=Stanford Encyclopedia of Philosophy |year=2017 |publisher=Metaphysics Research Lab, Stanford University}}</ref> [[File:Schroedingers cat film.svg|thumb|upright=1|The [[Schrödinger's cat]] thought experiment can be used to visualize the many-worlds interpretation of quantum mechanics, where a branching of the universe occurs through a superposition of two quantum mechanical states.]] Everett's [[many-worlds interpretation]], formulated in 1956, holds that <em>all</em> the possibilities described by quantum theory <em>simultaneously</em> occur in a multiverse composed of mostly independent parallel universes.<ref>{{Cite encyclopedia |first=Jeffrey |last=Barrett |encyclopedia=Stanford Encyclopedia of Philosophy |publisher=Metaphysics Research Lab, Stanford University |year=2018 |editor-last=Zalta |editor-first=Edward N. |title=Everett's Relative-State Formulation of Quantum Mechanics |url=https://plato.stanford.edu/entries/qm-everett/}}</ref> This is a consequence of removing the axiom of the collapse of the wave packet. All possible states of the measured system and the measuring apparatus, together with the observer, are present in a real physical quantum superposition. While the multiverse is deterministic, we perceive non-deterministic behavior governed by probabilities, because we do not observe the multiverse as a whole, but only one parallel universe at a time. Exactly how this is supposed to work has been the subject of much debate. Several attempts have been made to make sense of this and derive the Born rule,<ref name=dewitt73>{{cite book |editor-last1=DeWitt |editor-first1=Bryce |editor-link1=Bryce DeWitt |editor-last2=Graham |editor-first2=R. Neill |last1=Everett |first1=Hugh |author-link1=Hugh Everett III |last2=Wheeler |first2=J. A. |author-link2=John Archibald Wheeler |last3=DeWitt |first3=B. S. |author-link3=Bryce DeWitt |last4=Cooper |first4=L. N. |author-link4=Leon Cooper |last5=Van Vechten |first5=D. |last6=Graham |first6=N. |title=The Many-Worlds Interpretation of Quantum Mechanics |series=Princeton Series in Physics |publisher=[[Princeton University Press]] |location=Princeton, NJ |year=1973 |isbn=0-691-08131-X |page=v}}</ref><ref name="wallace2003">{{cite journal |last1=Wallace |first1=David |year=2003 |title=Everettian Rationality: defending Deutsch's approach to probability in the Everett interpretation |journal=Stud. Hist. Phil. Mod. Phys. |volume=34 |issue=3 |pages=415–438 |arxiv=quant-ph/0303050 |bibcode=2003SHPMP..34..415W |doi=10.1016/S1355-2198(03)00036-4 |s2cid=1921913}}</ref> with no consensus on whether they have been successful.<ref name="ballentine1973">{{cite journal |first1=L. E. |last1=Ballentine |date=1973 |title=Can the statistical postulate of quantum theory be derived? – A critique of the many-universes interpretation |journal=Foundations of Physics |volume=3 |issue=2 |pages=229–240 |doi=10.1007/BF00708440 |bibcode=1973FoPh....3..229B |s2cid=121747282}}</ref><ref>{{cite book |first=N. P. |last=Landsman |chapter=The Born rule and its interpretation |chapter-url=http://www.math.ru.nl/~landsman/Born.pdf |quote=The conclusion seems to be that no generally accepted derivation of the Born rule has been given to date, but this does not imply that such a derivation is impossible in principle. |title=Compendium of Quantum Physics |editor-first1=F. |editor-last1=Weinert |editor-first2=K. |editor-last2=Hentschel |editor-first3=D. |editor-last3=Greenberger |editor-first4=B. |editor-last4=Falkenburg |publisher=Springer |year=2008 |isbn=978-3-540-70622-9}}</ref><ref name="kent2009">{{Cite book |last1=Kent |first1=Adrian |author-link=Adrian Kent |title=Many Worlds? Everett, Quantum Theory and Reality |publisher=Oxford University Press |year=2010 |editor=S. Saunders |chapter=One world versus many: The inadequacy of Everettian accounts of evolution, probability, and scientific confirmation |arxiv=0905.0624 |bibcode=2009arXiv0905.0624K |editor2=J. Barrett |editor3=A. Kent |editor4=D. Wallace}}</ref> [[Relational quantum mechanics]] appeared in the late 1990s as a modern derivative of Copenhagen-type ideas,<ref>{{Cite journal |last=Van Fraassen |first=Bas C. |author-link=Bas van Fraassen |date=April 2010 |title=Rovelli's World |url=http://link.springer.com/10.1007/s10701-009-9326-5 |journal=[[Foundations of Physics]] |volume=40 |issue=4 |pages=390–417 |doi=10.1007/s10701-009-9326-5 |bibcode=2010FoPh...40..390V |s2cid=17217776 |issn=0015-9018}}</ref><ref>{{cite journal|first1=Claudio |last1=Calosi |first2=Timotheus |last2=Riedel |title=Relational Quantum Mechanics at the Crossroads |journal=Foundations of Physics |volume=54 |page=74 |year=2024 |issue=6 |doi=10.1007/s10701-024-00810-5|doi-access=free |bibcode=2024FoPh...54...74C }}</ref> and [[QBism]] was developed some years later.<ref name=":23">{{Cite encyclopedia |last=Healey |first=Richard |encyclopedia=[[Stanford Encyclopedia of Philosophy]] |publisher=Metaphysics Research Lab, Stanford University |year=2016 |editor-last=Zalta |editor-first=Edward N. |title=Quantum-Bayesian and Pragmatist Views of Quantum Theory |url=https://plato.stanford.edu/entries/quantum-bayesian/}}</ref><ref>{{cite book|first=Blake C. |last=Stacey |chapter=Toward a World Game-Flavored as a Hawk's Wing |title=Phenomenology and QBism: New Approaches to Quantum Mechanics |pages=49–77 |editor-first1=Philipp |editor-last1=Berghofer |editor-first2=Harald A. |editor-last2=Wiltsche |year=2023 |publisher=Routledge |isbn=9781032191812 |doi=10.4324/9781003259008-3}}</ref> == History == {{Main|History of quantum mechanics|Atomic theory}} Quantum mechanics was developed in the early decades of the 20th century, driven by the need to explain phenomena that, in some cases, had been observed in earlier times. Scientific inquiry into the wave nature of light began in the 17th and 18th centuries, when scientists such as [[Robert Hooke]], [[Christiaan Huygens]] and [[Leonhard Euler]] proposed a wave theory of light based on experimental observations.<ref name="Born & Wolf">{{cite book |first1=Max |last1=Born |author-link1=Max Born |first2=Emil |last2=Wolf |author-link2=Emil Wolf |title=Principles of Optics |title-link=Principles of Optics |year=1999 |publisher=Cambridge University Press |isbn=0-521-64222-1 |oclc=1151058062}}</ref> In 1803 English [[polymath]] [[Thomas Young (scientist)|Thomas Young]] described the famous [[Young's interference experiment|double-slit experiment]].<ref>{{Cite journal |last=Scheider |first=Walter |date=April 1986 |title=Bringing one of the great moments of science to the classroom |url=http://www.cavendishscience.org/phys/tyoung/tyoung.htm |journal=[[The Physics Teacher]] |volume=24 |issue=4 |pages=217–219 |doi=10.1119/1.2341987 |bibcode=1986PhTea..24..217S |issn=0031-921X}}</ref> This experiment played a major role in the general acceptance of the [[wave theory of light]]. During the early 19th century, [[chemistry|chemical]] research by [[John Dalton]] and [[Amedeo Avogadro]] lent weight to the [[atomic theory]] of matter, an idea that [[James Clerk Maxwell]], [[Ludwig Boltzmann]] and others built upon to establish the [[kinetic theory of gases]]. The successes of kinetic theory gave further credence to the idea that matter is composed of atoms, yet the theory also had shortcomings that would only be resolved by the development of quantum mechanics.<ref name="Feynman-kinetic-theory">{{cite book |last1=Feynman |first1=Richard |last2=Leighton |first2=Robert |last3=Sands |first3=Matthew |title=The Feynman Lectures on Physics |volume=1 |publisher=California Institute of Technology |date=1964 |url=https://feynmanlectures.caltech.edu/I_40.html |access-date=30 September 2021}} Reprinted, Addison-Wesley, 1989, {{isbn|978-0-201-50064-6}} </ref> While the early conception of atoms from [[Greek philosophy]] had been that they were indivisible units{{snd}}the word "atom" deriving from the [[Greek language|Greek]] for 'uncuttable'{{snd}}the 19th century saw the formulation of hypotheses about subatomic structure. One important discovery in that regard was [[Michael Faraday]]'s 1838 observation of a glow caused by an electrical discharge inside a glass tube containing gas at low pressure. [[Julius Plücker]], [[Johann Wilhelm Hittorf]] and [[Eugen Goldstein]] carried on and improved upon Faraday's work, leading to the identification of [[cathode rays]], which [[J. J. Thomson]] found to consist of subatomic particles that would be called electrons.<ref>{{citation |first=Andre |last=Martin |contribution=Cathode Ray Tubes for Industrial and Military Applications |editor-last=Hawkes |editor-first=Peter |title=Advances in Electronics and Electron Physics, Volume 67 |publisher=Academic Press |year=1986 |isbn=978-0-08-057733-3 |page=183 |quote="Evidence for the existence of "cathode-rays" was first found by Plücker and Hittorf ..."}}</ref><ref>{{Cite book |last=Dahl |first=Per F. |url=https://books.google.com/books?id=xUzaWGocMdMC |title=Flash of the Cathode Rays: A History of J. J. Thomson's Electron |year=1997 |publisher=CRC Press |isbn=978-0-7503-0453-5 |pages=47–57}}</ref> [[File:Max Planck (1858-1947).jpg|thumb|upright|[[Max Planck]] is considered the father of the quantum theory.]] The [[black-body radiation]] problem was discovered by [[Gustav Kirchhoff]] in 1859. In 1900, Max Planck proposed the hypothesis that energy is radiated and absorbed in discrete "quanta" (or energy packets), yielding a calculation that precisely matched the observed patterns of black-body radiation.<ref>{{cite book |first1=J. |last1=Mehra |author-link1=Jagdish Mehra |first2=H. |last2=Rechenberg |title=The Historical Development of Quantum Theory, Vol. 1: The Quantum Theory of Planck, Einstein, Bohr and Sommerfeld. Its Foundation and the Rise of Its Difficulties (1900–1925) |location=New York |publisher=Springer-Verlag |year=1982 |isbn=978-0-387-90642-3}}</ref> The word ''quantum'' derives from the [[Latin]], meaning "how great" or "how much".<ref>{{cite dictionary |title=Quantum |url=http://www.merriam-webster.com/dictionary/quantum |access-date=18 August 2012 |dictionary=Merriam-Webster Dictionary |url-status=live |archive-url=https://web.archive.org/web/20121026104456/http://www.merriam-webster.com/dictionary/quantum |archive-date=Oct 26, 2012}}</ref> According to Planck, quantities of energy could be thought of as divided into "elements" whose size (''E'') would be proportional to their [[frequency]] (''ν''): <math display=block> E = h \nu\ </math>, where ''h'' is the [[Planck constant]]. Planck cautiously insisted that this was only an aspect of the processes of absorption and emission of radiation and was not the <em>physical reality</em> of the radiation.<ref>{{cite book |last=Kuhn |first=T. S. |title=Black-body theory and the quantum discontinuity 1894–1912 |publisher=Clarendon Press |year=1978 |isbn=978-0-19-502383-1 |location=Oxford |author-link=Thomas Samuel Kuhn}}</ref> In fact, he considered his quantum hypothesis a mathematical trick to get the right answer rather than a sizable discovery.<ref name="Kragh">{{cite magazine |last=Kragh |first=Helge |author-link=Helge Kragh |title=Max Planck: the reluctant revolutionary |date=1 December 2000 |url=https://physicsworld.com/a/max-planck-the-reluctant-revolutionary/ |magazine=[[Physics World]] |access-date=12 December 2020}}</ref> However, in 1905 Albert Einstein interpreted Planck's quantum hypothesis [[local realism|realistically]] and used it to explain the [[photoelectric effect]], in which shining light on certain materials can eject electrons from the material. Niels Bohr then developed Planck's ideas about radiation into a [[Bohr model|model of the hydrogen atom]] that successfully predicted the [[spectral line]]s of hydrogen.<ref>{{cite book |last=Stachel |first=John |title=Quantum Reality, Relativistic Causality, and Closing the Epistemic Circle |author-link=John Stachel |year=2009 |chapter=Bohr and the Photon |series=The Western Ontario Series in Philosophy of Science |volume=73 |location=Dordrecht |publisher=Springer |pages=69–83 |doi=10.1007/978-1-4020-9107-0_5 |isbn=978-1-4020-9106-3}}</ref> Einstein further developed this idea to show that an [[electromagnetic wave]] such as light could also be described as a particle (later called the photon), with a discrete amount of energy that depends on its frequency.<ref>{{cite journal |last=Einstein |first=Albert |year=1905 |title=Über einen die Erzeugung und Verwandlung des Lichtes betreffenden heuristischen Gesichtspunkt |trans-title=On a heuristic point of view concerning the production and transformation of light |journal=[[Annalen der Physik]] |volume=17 |issue=6 |pages=132–148 |bibcode=1905AnP...322..132E |doi=10.1002/andp.19053220607 |doi-access=free |language=de}} Reprinted in {{cite book |title=The Collected Papers of Albert Einstein |publisher=Princeton University Press |year=1989 |editor-last=Stachel |editor-first=John |editor-link=John Stachel |volume=2 |pages=149–166 |language=de}} See also "Einstein's early work on the quantum hypothesis", ibid. pp. 134–148.</ref> In his paper "On the Quantum Theory of Radiation", Einstein expanded on the interaction between energy and matter to explain the absorption and emission of energy by atoms. Although overshadowed at the time by his general theory of relativity, this paper articulated the mechanism underlying the stimulated emission of radiation,<ref>{{cite journal |first=Albert |last=Einstein |author-link=Albert Einstein |year=1917 |title=Zur Quantentheorie der Strahlung |trans-title=On the Quantum Theory of Radiation |language=de |journal=[[Physikalische Zeitschrift]] |volume=18 |pages=121–128 |bibcode=1917PhyZ...18..121E}} Translated in {{cite book |title=The Old Quantum Theory |date=1967 |pages=167–183 |chapter=On the Quantum Theory of Radiation |publisher=Elsevier |doi=10.1016/b978-0-08-012102-4.50018-8 |isbn=978-0-08-012102-4 |last1=Einstein |first1=A.}}</ref> which became the basis of the laser.<ref>{{cite news |first=Philip |last=Ball |url=https://physicsworld.com/a/a-century-ago-einstein-sparked-the-notion-of-the-laser/ |title=A century ago Einstein sparked the notion of the laser |author-link=Philip Ball |work=[[Physics World]] |date=2017-08-31 |access-date=2024-03-23}}</ref> [[File:Solvay conference 1927.jpg|left|thumb|upright=1.4|The 1927 [[Solvay Conference]] in [[Brussels]] was the fifth world physics conference.]] This phase is known as the [[old quantum theory]]. Never complete or self-consistent, the old quantum theory was rather a set of [[heuristic]] corrections to classical mechanics.<ref name="terHaar">{{cite book |last=ter Haar |first=D. |url=https://archive.org/details/oldquantumtheory0000haar |title=The Old Quantum Theory |publisher=Pergamon Press |year=1967 |isbn=978-0-08-012101-7 |lccn=66-29628 |pages=3–75 |url-access=registration}}</ref><ref>{{cite SEP |title=Bohr's Correspondence Principle |date=2020-08-13 |author-first1=Alisa |author-last1=Bokulich |author-first2=Peter |author-last2=Bokulich |url-id=bohr-correspondence}}</ref> The theory is now understood as a [[WKB approximation#Application to the Schrödinger equation|semi-classical approximation]] to modern quantum mechanics.<ref>{{cite encyclopedia |title=Semi-classical approximation |url=https://www.encyclopediaofmath.org/index.php?title=Semi-classical_approximation |access-date=1 February 2020 |encyclopedia=Encyclopedia of Mathematics}}</ref><ref>{{cite book |last1=Sakurai |first1=J. J. |title=Modern Quantum Mechanics |title-link=Modern Quantum Mechanics |last2=Napolitano |first2=J. |publisher=Pearson |year=2014 |isbn=978-1-292-02410-3 |chapter=Quantum Dynamics |oclc=929609283 |author-link1=J. J. Sakurai}}</ref> Notable results from this period include, in addition to the work of Planck, Einstein and Bohr mentioned above, Einstein and [[Peter Debye]]'s work on the [[specific heat]] of solids, Bohr and [[Hendrika Johanna van Leeuwen]]'s [[Bohr–Van Leeuwen theorem|proof]] that classical physics cannot account for [[diamagnetism]], and [[Arnold Sommerfeld]]'s extension of the Bohr model to include special-relativistic effects.<ref name="terHaar" /><ref name=Aharoni>{{cite book |last=Aharoni |first=Amikam |author-link=Amikam Aharoni |title=Introduction to the Theory of Ferromagnetism |publisher=[[Clarendon Press]] |year=1996 |isbn=0-19-851791-2 |pages=[https://archive.org/details/introductiontoth00ahar/page/6 6–7] |url=https://archive.org/details/introductiontoth00ahar/page/6}}</ref> In the mid-1920s quantum mechanics was developed to become the standard formulation for atomic physics. In 1923, the French physicist [[Louis de Broglie]] put forward his theory of matter waves by stating that particles can exhibit wave characteristics and vice versa. Building on de Broglie's approach, modern quantum mechanics was born in 1925, when the German physicists Werner Heisenberg, Max Born, and [[Pascual Jordan]]<ref name=Edwards79>David Edwards, "The Mathematical Foundations of Quantum Mechanics", ''Synthese'', Volume 42, Number 1/September, 1979, pp. 1–70.</ref><ref name="Edwards81">David Edwards, "The Mathematical Foundations of Quantum Field Theory: Fermions, Gauge Fields, and Super-symmetry, Part I: Lattice Field Theories", ''International Journal of Theoretical Physics'', Vol. 20, No. 7 (1981).</ref> developed [[matrix mechanics]] and the Austrian physicist Erwin Schrödinger invented [[Schrödinger equation|wave mechanics]]. Born introduced the probabilistic interpretation of Schrödinger's wave function in July 1926.<ref>{{Cite journal |last=Bernstein |first=Jeremy |author-link=Jeremy Bernstein |date=November 2005 |title=Max Born and the quantum theory |journal=[[American Journal of Physics]] |volume=73 |issue=11 |pages=999–1008 |doi=10.1119/1.2060717 |bibcode=2005AmJPh..73..999B |issn=0002-9505 |doi-access=free}}</ref> Thus, the entire field of quantum physics emerged, leading to its wider acceptance at the Fifth [[Solvay Conference]] in 1927.<ref name="pais1997">{{cite book |last=Pais |first=Abraham |author-link=Abraham Pais |title=A Tale of Two Continents: A Physicist's Life in a Turbulent World |year=1997 |publisher=Princeton University Press |location=Princeton, New Jersey |isbn=0-691-01243-1 |url-access=registration |url=https://archive.org/details/taleoftwocontine00pais}}</ref> By 1930, quantum mechanics had been further unified and formalized by [[David Hilbert]], Paul Dirac and [[John von Neumann]]<ref>{{cite journal |last=Van Hove |first=Leon |title=Von Neumann's contributions to quantum mechanics |journal=[[Bulletin of the American Mathematical Society]] |year=1958 |volume=64 |issue=3 |pages=Part 2:95–99 |url=https://www.ams.org/journals/bull/1958-64-03/S0002-9904-1958-10206-2/S0002-9904-1958-10206-2.pdf |doi=10.1090/s0002-9904-1958-10206-2 |doi-access=free |url-status=live |archive-url=https://web.archive.org/web/20240120073106/https://www.ams.org/journals/bull/1958-64-03/S0002-9904-1958-10206-2/S0002-9904-1958-10206-2.pdf |archive-date=Jan 20, 2024}}</ref> with greater emphasis on [[measurement in quantum mechanics|measurement]], the statistical nature of our knowledge of reality, and [[Interpretations of quantum mechanics|philosophical speculation about the 'observer']]. It has since permeated many disciplines, including quantum chemistry, [[quantum electronics]], [[quantum optics]], and [[quantum information science]]. It also provides a useful framework for many features of the modern [[periodic table of elements]], and describes the behaviors of [[atoms]] during [[chemical bond]]ing and the flow of electrons in computer [[semiconductor]]s, and therefore plays a crucial role in many modern technologies. While quantum mechanics was constructed to describe the world of the very small, it is also needed to explain some [[macroscopic]] phenomena such as [[superconductors]]<ref name="feynman2015">{{cite web |url=https://feynmanlectures.caltech.edu/III_21.html#Ch21-S5 |title=The Feynman Lectures on Physics Vol. III Ch. 21: The Schrödinger Equation in a Classical Context: A Seminar on Superconductivity, 21-4 |quote=...it was long believed that the wave function of the Schrödinger equation would never have a macroscopic representation analogous to the macroscopic representation of the amplitude for photons. On the other hand, it is now realized that the phenomena of superconductivity presents us with just this situation. |last=Feynman |first=Richard |author-link=Richard Feynman |publisher=[[California Institute of Technology]] |access-date=24 November 2015 |url-status=live |archive-url=https://archive.today/20161215225248/http://www.feynmanlectures.caltech.edu/III_21.html%23Ch21-S5 |archive-date=15 Dec 2016}}</ref> and [[superfluid]]s.<ref>{{cite web |url=http://physics.berkeley.edu/sites/default/files/_/lt24_berk_expts_on_macro_sup_effects.pdf |first=Richard |last=Packard |year=2006 |title=Berkeley Experiments on Superfluid Macroscopic Quantum Effects |publisher=Physics Department, University of California, Berkeley |archive-url=https://web.archive.org/web/20151125112132/http://research.physics.berkeley.edu/packard/publications/Articles/LT24_Berk_expts_on_macro_sup_effects.pdf |archive-date=25 November 2015 |access-date=24 November 2015}}</ref> == See also == {{cols|colwidth=35em}} * [[Bra–ket notation]] * [[Einstein's thought experiments]] * [[List of textbooks on classical mechanics and quantum mechanics]] * [[Macroscopic quantum phenomena]] * [[Phase-space formulation]] * [[Regularization (physics)]] * [[Two-state quantum system]] {{colend}} == Explanatory notes == {{reflist|group=note}} == References == {{reflist}} == Further reading == {{Refbegin|30em}} The following titles, all by working physicists, attempt to communicate quantum theory to lay people, using a minimum of technical apparatus: * [[Marvin Chester|Chester, Marvin]] (1987). ''Primer of Quantum Mechanics''. John Wiley. {{isbn|0-486-42878-8}} * {{cite book |first1=Brian |last1=Cox |author-link1=Brian Cox (physicist) |first2=Jeff |last2=Forshaw |author-link2=Jeff Forshaw |title=The Quantum Universe: Everything That Can Happen Does Happen |publisher=Allen Lane |year=2011 |isbn=978-1-84614-432-5 |title-link=The Quantum Universe}} * [[Richard Feynman]], 1985. ''[[QED: The Strange Theory of Light and Matter]]'', Princeton University Press. {{isbn|0-691-08388-6}}. Four elementary lectures on quantum electrodynamics and [[quantum field theory]], yet containing many insights for the expert. * [[Giancarlo Ghirardi|Ghirardi, GianCarlo]], 2004. ''Sneaking a Look at God's Cards'', Gerald Malsbary, trans. Princeton Univ. Press. The most technical of the works cited here. Passages using [[algebra]], [[trigonometry]], and [[bra–ket notation]] can be passed over on a first reading. * [[N. David Mermin]], 1990, "Spooky actions at a distance: mysteries of the QT" in his ''Boojums All the Way Through''. Cambridge University Press: 110–76. * [[Victor Stenger]], 2000. ''Timeless Reality: Symmetry, Simplicity, and Multiple Universes''. Buffalo, New York: Prometheus Books. Chpts. 5–8. Includes cosmological and philosophical considerations. {{Refend}} {{Refbegin|30em}} More technical: * {{cite book |last=Bernstein |first=Jeremy |author-link=Jeremy Bernstein |title=Quantum Leaps |publisher=Belknap Press of Harvard University Press |location=Cambridge, Massachusetts |year=2009 |isbn=978-0-674-03541-6 |url=https://books.google.com/books?id=j0Me3brYOL0C}} * {{cite book |last=Bohm |first=David |title=Quantum Theory |url=https://archive.org/details/quantumtheory0000bohm |url-access=registration |publisher=Dover Publications |year=1989 |isbn=978-0-486-65969-5 |author-link=David Bohm}} * {{cite book |last1=Binney |first1=James |author1-link=James Binney |last2=Skinner |first2=David |title=The Physics of Quantum Mechanics |year=2008 |publisher=Oxford University Press |isbn=978-0-19-968857-9}} * {{cite book |last1=Eisberg |first1=Robert |author2-link=Robert Resnick |last2=Resnick |first2=Robert |title=Quantum Physics of Atoms, Molecules, Solids, Nuclei, and Particles |edition=2nd |publisher=Wiley |year=1985 |isbn=978-0-471-87373-0 |url=https://archive.org/details/quantumphysicsof00eisb}} * [[Bryce DeWitt]], R. Neill Graham, eds., 1973. ''The Many-Worlds Interpretation of Quantum Mechanics'', Princeton Series in Physics, Princeton University Press. {{isbn|0-691-08131-X}} * {{cite journal |last1=Everett |first1=Hugh |author-link=Hugh Everett |year=1957 |title=Relative State Formulation of Quantum Mechanics |journal=Reviews of Modern Physics |volume=29 |issue=3 |pages=454–462 |doi=10.1103/RevModPhys.29.454 |bibcode=1957RvMP...29..454E |s2cid=17178479}} * {{cite book |last1=Feynman |first1=Richard P. |author-link1=Richard Feynman |last2=Leighton |first2=Robert B. |author-link2=Robert B. Leighton |last3=Sands |first3=Matthew |year=1965 |title=The Feynman Lectures on Physics |volume=1–3 |publisher=Addison-Wesley |isbn=978-0-7382-0008-8 |title-link=The Feynman Lectures on Physics}} * [[Daniel Greenberger|D. Greenberger]], [[Klaus Hentschel|K. Hentschel]], F. Weinert, eds., 2009. ''Compendium of quantum physics, Concepts, experiments, history and philosophy'', Springer-Verlag, Berlin, Heidelberg. Short articles on many QM topics. * {{cite book |last=Griffiths |first=David J. |author-link=David J. Griffiths |title=[[Introduction to Quantum Mechanics (book)|Introduction to Quantum Mechanics]] |edition=2nd |publisher=Prentice Hall |year=2004 |isbn=978-0-13-111892-8 |oclc=40251748}} A standard undergraduate text. * [[Max Jammer]], 1966. ''The Conceptual Development of Quantum Mechanics''. McGraw Hill. * [[Hagen Kleinert]], 2004. ''Path Integrals in Quantum Mechanics, Statistics, Polymer Physics, and Financial Markets'', 3rd ed. Singapore: World Scientific. [http://www.physik.fu-berlin.de/~kleinert/b5 Draft of 4th edition.] {{Webarchive|url=https://web.archive.org/web/20080615134934/http://www.physik.fu-berlin.de/~kleinert/b5 |date=2008-06-15 }} * {{cite book |first1=L. D. |last1=Landau |first2=E. M. |last2=Lifshitz |year=1977 |title=Quantum Mechanics: Non-Relativistic Theory |edition=3rd |volume=3 |publisher=[[Pergamon Press]] |isbn=978-0-08-020940-1}} [https://archive.org/details/QuantumMechanics_104 Online copy] * {{cite book |last=Liboff |first=Richard L. |title=Introductory Quantum Mechanics |publisher=Addison-Wesley |year=2002 |isbn=978-0-8053-8714-8 |author-link=Liboff, Richard}} * Gunther Ludwig, 1968. ''Wave Mechanics''. London: Pergamon Press. {{isbn|0-08-203204-1}} * [[George Mackey]] (2004). ''The mathematical foundations of quantum mechanics''. Dover Publications. {{isbn|0-486-43517-2}}. * {{cite book |last=Merzbacher |first=Eugen |author-link=Eugen Merzbacher |title=Quantum Mechanics |publisher=Wiley, John & Sons, Inc |year=1998 |isbn=978-0-471-88702-7}} * [[Albert Messiah]], 1966. ''Quantum Mechanics'' (Vol. I), English translation from French by G. M. Temmer. North Holland, John Wiley & Sons. Cf. chpt. IV, section III. [https://archive.org/details/QuantumMechanicsVolumeI online] * {{cite book |last=Omnès |first=Roland |title=Understanding Quantum Mechanics |publisher=Princeton University Press |year=1999 |isbn=978-0-691-00435-8 |oclc=39849482 |author-link=Roland Omnès |url=https://archive.org/details/understandingqua00omne}} * {{cite book |last=Scerri |first=Eric. R. |author-link=Eric R. Scerri |year=2006 |title=The Periodic Table: Its Story and Its Significance |publisher=Oxford University Press |isbn=0-19-530573-6}} Considers the extent to which chemistry and the periodic system have been reduced to quantum mechanics. * {{Cite book |last=Schiff |first=Leonard I. |author-link=Leonard I. Schiff |title=Quantum Mechanics |date=1955 |publisher=McGraw Hill}} * {{cite book |last=Shankar |first=R. |author-link=Ramamurti Shankar |title=Principles of Quantum Mechanics |publisher=Springer |year=1994 |isbn=978-0-306-44790-7}} * {{cite book |last=Stone |first=A. Douglas |author-link=A. Douglas Stone |title=Einstein and the Quantum |publisher=Princeton University Press |year=2013 |isbn=978-0-691-13968-5 |url-access=registration |url=https://archive.org/details/einsteinquantumq0000ston}} * {{cite book |publisher=[[Transnational College]], Language Research Foundation |title=What is Quantum Mechanics? A Physics Adventure |location=Boston |year=1996 |isbn=978-0-9643504-1-0 |oclc=34661512 |author-link=Transnational College of Lex}} * [[Martinus J. G. Veltman|Veltman, Martinus J. G.]] (2003), ''Facts and Mysteries in Elementary Particle Physics''. {{refend}} == External links == {{Sister project links|s=Quantum mechanics}} * [https://web.archive.org/web/20080913201312/http://www.quantiki.org/wiki/index.php/Introduction_to_Quantum_Theory Introduction to Quantum Theory at Quantiki.] * [http://bethe.cornell.edu/ Quantum Physics Made Relatively Simple]: three video lectures by [[Hans Bethe]]. ''' Course material ''' * [http://oyc.yale.edu/sites/default/files/notes_quantum_cookbook.pdf Quantum Cook Book] and [http://oyc.yale.edu/physics/phys-201#sessions PHYS 201: Fundamentals of Physics II] by [[Ramamurti Shankar]], Yale OpenCourseware. * ''[http://www.lightandmatter.com/mod/ Modern Physics: With waves, thermodynamics, and optics]'' – an online textbook. * [[MIT OpenCourseWare]]: [https://ocw.mit.edu/courses/chemistry/ Chemistry] and [https://ocw.mit.edu/courses/physics/ Physics]. See [https://ocw.mit.edu/courses/physics/8-04-quantum-physics-i-spring-2016/ 8.04], [https://ocw.mit.edu/courses/physics/8-05-quantum-physics-ii-fall-2013/index.htm 8.05] and [https://ocw.mit.edu/courses/physics/8-06-quantum-physics-iii-spring-2018/index.htm 8.06]. * [http://physics.csbsju.edu/QM/ {{sfrac|5|1|2}} Examples in Quantum Mechanics]. ''' Philosophy ''' * {{cite SEP |url-id=qm |title=Quantum Mechanics |last=Ismael |first=Jenann}} * {{cite SEP |url-id=qt-issues |title=Philosophical Issues in Quantum Theory}} {{Quantum mechanics topics}} {{Physics-footer}} {{Portal bar|Astronomy|Chemistry|Electronics|Energy|History of science|Mathematics|Physics|Science|Stars}} {{Authority control}} [[Category:Quantum mechanics| ]]
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