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Solar still
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{{Short description|Water distillation and purification system using solar energy}} [[Image:Evapo still.svg|thumb|upright=1.35|Solar still built into a pit in the ground]] [[Image:Watercone on earth.svg|thumb|upright=1.35|"Watercone" solar still]] [[Image:Solar_Seawater_Still.svg|thumb|upright=1.35]] A '''solar still''' [[distillation|distills water]] with substances dissolved in it by using the [[Solar energy|heat of the Sun]] to evaporate water so that it may be cooled and collected, thereby purifying it. They are used in areas where drinking water is unavailable, so that clean water is obtained from dirty water or from plants by exposing them to sunlight. Still types include large scale [[concentrated solar still]]s and condensation traps'''.''' In a solar still, impure water is contained outside the collector, where it is evaporated by sunlight shining through a transparent collector. The pure [[water vapour]] condenses on the cool inside surface and drips into a tank. Distillation replicates the way nature makes rain. The sun's energy heats water to the point of evaporation. As the water evaporates, its vapour rises, condensing into water again as it cools. This process leaves behind impurities, such as salts and heavy metals, and eliminates microbiological organisms. The result is pure (potable) water. == History == Condensation traps have been in use since the pre-[[Incan]] peoples inhabited the [[Andes]].{{Cn|date=March 2025}} In 1952, the United States military developed a portable solar still for pilots stranded in the ocean. It featured an inflatable {{convert|24|in|order=flip|adj=on}} floating plastic ball, with a flexible tube in the side. An inner bag hangs from attachment points on the outer bag. Seawater is poured into the inner bag from an opening in the ball's neck. Fresh water is taken out using the side tube. Output ranged from {{convert|1.5|USqt|L|order=flip}} to {{convert|2.5|USqt|L|order=flip}} of fresh water per day.<ref name=":0">{{Cite magazine|url=https://books.google.com/books?id=8dwDAAAAMBAJ&pg=PA113|title=Solar Still|magazine=Popular Mechanics|date=February 1952|publisher=Hearst Magazines|page=113}}</ref> Similar stills are included in some [[Lifeboat (shipboard)|life raft]] [[survival kit]]s, though manual [[reverse osmosis]] desalinators have mostly replaced them.<ref>{{cite web|date=2012|title=Manual Reverse Osmosis Desalinator - Notice of Intent to Award Sole Source, USAF|url=https://www.fbo.gov/index?s=opportunity&mode=form&id=a0f2e9cd317c57ab0333b5da36c95319&tab=core&_cview=0|access-date=July 3, 2012|work=fbo.gov}}</ref> Today, a method for gathering water in moisture traps is taught within the [[Military of Argentina|Argentinian Army]] for use by specialist units expected to conduct extended patrols of more than a week's duration in the Andes' arid border areas.{{Cn|date=March 2025}} ==Methods== [[File:Puits Solaire.jpg|thumb|upright=1.2|Solar Well]] === Pit still === A collector is placed at the bottom of a pit. Branches are placed vertically in the pit. The branches are long enough to extend over the edge of the pit and form a funnel to direct the water into the collector. A lid is then built over this funnel, using more branches, leaves, grasses, etc. Water is collected each morning. This method relies on the formation of [[dew]] or [[frost]] on the receptacle, funnel, and lid. Forming dew collects on and runs down the outside of the funnel and into the receptacle. This water would typically [[evaporate]] with the morning sun and thus vanish, but the lid traps the evaporating water and raises the [[humidity]] within the trap, reducing the amount of lost water. The shade produced by the lid also reduces the temperature within the trap, which further reduces the rate of water loss to evaporation. A solar still can be constructed with two–four stones, plastic film or transparent [[glass]], a central weight to make the funnel and a container for the condensate.<ref>{{Cite web|title=Uncle John's Portable Solar Water Distiller ( for Survival )|url=https://www.instructables.com/Uncle-Johns-portable-solar-water-distiller-Fo/|website=Instructables}}</ref> Better materials improve efficiency. A single sheet of plastic can replace the branches and leaves. Greater efficiency arises because the plastic is waterproof, preventing water vapour from escaping. The sheet is attached to the ground on all sides with stones or earth. Weighting the centre of the sheet forms the funnel. Condensate runs down it into the receptacle. One study of pit distillation found that angling the lid at 30 degrees angle captured the most water. The optimal water depth was about {{convert|1|in|order=flip}}.<ref>{{cite journal|last1=Khalifa|first1=Abdul Jabbar N.|last2=Hamood|first2=Ahmad M.|date=November 2009|title=Performance correlations for basin type solar stills|journal=Desalination|volume=249|issue=1|pages=24–28|doi=10.1016/j.desal.2009.06.011|bibcode=2009Desal.249...24K }}</ref> === Transpiration === During photosynthesis plants release water through [[transpiration]]. Water can be obtained by enclosing a leafy tree branch in clear plastic,<ref>{{Cite web|title=Solar Still | website=Practical Survivor|url=http://www.practicalsurvivor.com/solarstill|access-date=2023-01-12}}</ref> capturing water vapour released by the tree.<ref>{{cite book|last1=O'Meagher|first1=Bert|url=http://www.vks737.on.net/pdfs/survival.pdf|title=Aids to survival: a handbook on outback survival|last2=Reid|first2=Dennis|last3=Harvey|first3=Ross|date=2007|publisher=Western Australia Police Academy|isbn=978-0-646-36303-5|edition=25th|location=Maylands, W.A.|page=24|access-date=7 February 2017}}</ref> The plastic allows photosynthesis to continue. In a 2009 study, variations to the angle of plastic and increasing the internal temperature versus the outside temperature improved output volumes. Unless relieved the vapour pressure around the branch can rise so high that the leaves can no longer transpire, requiring the water to be removed frequently. Alternatively, clumps of grass or small bushes can be placed inside the bag. The foliage must be replaced at regular intervals, particularly if the foliage is uprooted. Efficiency is greatest when the bag receives maximum sunshine. Soft, pulpy roots yield the greatest amount of liquid for the least amount of effort. === Wick === [[File:Wick solar still.png|thumb|Wick basin solar still.|upright=1.5]] The wick type solar still is a vapour-tight glass-topped box with an angled roof.<ref>{{cite journal|last1=Manikandan|first1=V.|last2=Shanmugasundaram|first2=K.|last3=Shanmugan|first3=S.|last4=Janarthanan|first4=B.|last5=Chandrasekaran|first5=J.|date=April 2013|title=Wick type solar stills: A review|journal=Renewable and Sustainable Energy Reviews|volume=20|pages=322–335|doi=10.1016/j.rser.2012.11.046|bibcode=2013RSERv..20..322M }}</ref> Water is poured in from the top. It is heated by sunlight and evaporates. It condenses on the underside of the glass and runs into the connecting pipe at the bottom. Wicks separate the water into banks to increase surface area. The more wicks, the more heat reaches the water. To aid in absorbing more heat, wicks can be blackened. Glass absorbs less heat than plastic at higher temperatures, although glass is not as flexible. A plastic net can catch the water before it falls into the container and give it more time to heat. === Additives === When distilling brine or other polluted water, adding a dye can increase the amount of solar radiation absorbed. === Reverse still === A reverse still uses the temperature difference between solar-heated ambient air and the device to condense ambient water vapour. One such device produces water without external power. It features an inverted cone on top to deflect ambient heat in the air, and to keep sunlight off the upper surface of the box. This surface is a sheet of glass coated with multiple layers of a polymer and silver.<ref name=":1">{{Cite web|last=Irving|first=Michael|date=June 24, 2021|title="Reverse solar still" keeps its cool to wring drinking water from air|url=https://newatlas.com/science/passive-drinking-water-harvester/|access-date=2021-06-27|website=New Atlas|language=en-US}}</ref> It reflects sunlight to reduce surface heating. Residual heat that is not reflected is reemitted in a specific ([[infrared]]) wavelength so that it passes through the atmosphere into space. The box can be as much as 15 °C (27 °F) cooler than the ambient temperature. That stimulates condensation, which gathers on the ceiling. This ceiling is coated in a [[Ultrahydrophobicity|superhydrophobic]] material, so that the condensate forms into droplets and falls into a collector. A test system yielded {{Convert|4.6|ml|usoz|abbr=on}} of water per day, using a {{Convert|10|cm|abbr=on}} surface or approximately 1.3 L/m<sup>2</sup> (0.28 gal/ft<sup>2)</sup> per day.<ref name=":1" /> === Inclined Solar Still === [[File:Sketch of an inclined basin-type solar still.jpg|thumb|Sketch of an inclined basin-type solar still]] An inclined solar still operates by allowing short-wave solar radiation to pass through a transparent glass plate while trapping the long-wave radiation emitted by the heated sand and water inside the still.<ref name=":2">{{cite journal|last1=Anjaneyulu|first1=L.|last2=Kumar|first2=E. Arun|last3=Sankannavar|first3=Ravi|last4=Rao|first4=K. Kesava|date=13 June 2012|title=Defluoridation of drinking water and rainwater harvesting using a solar still|journal=Industrial & Engineering Chemistry Research|volume=51|issue=23|pages=8040–8048|doi=10.1021/ie201692q}}</ref> This trapped heat raises the water temperature, increasing the evaporation rate. The resulting water vapor condenses on the inner surface of the glass plate and is collected using a channel. This type of still is utilized to produce potable water from brackish sources and to examine its effectiveness for defluoridation. A variation of this method, known as earth–water distillation, involves using wet sand or soil to extract water in arid regions. Sand is used within the inclined still to retain a stable water layer, preventing overflow. Without sand, feed water would spill over if its free surface height exceeded that of the collection channel.<ref name=":2" /> == Efficiency == Condensation traps are sources for extending or supplementing existing water sources or supplies. A trap measuring {{cvt|40|cm}} in diameter by {{cvt|30|cm}} deep yields around {{cvt|100|to|150|mL|USfloz}} per day. [[urinate|Urinating]] into the pit before adding the receptacle allows some of the urine's water content to be recovered. A pit still may be too inefficient as a survival still, because of the energy/water required for construction.<ref name="Alloway2000">{{cite book|last=Alloway|first=David|url=https://books.google.com/books?id=g0pXR2qylP0C&pg=PA63|title=Desert survival skills|date=2000|publisher=[[University of Texas Press]]|isbn=978-0-292-79226-5|pages=63–65|access-date=9 May 2013}}</ref> In desert environments water needs can exceed {{convert|1|gal|L|order=flip}} per day for a person at rest, while still production may average only {{convert|8|USfloz|mL|order=flip}}.<ref name="Alloway2000" /><ref name="Force2008">{{cite book|author=United States Air Force|url=https://books.google.com/books?id=uYz4ODJ5XhsC&pg=PA285|title=U.S. Air Force Survival Handbook|date=1 April 2008|publisher=[[Skyhorse Publishing]]|isbn=978-1-60239-245-8|page=285|access-date=9 May 2013}}</ref> Several days of water collection may be required to equal the water lost during construction.<ref name="Force2008" /> ==Applications== === Remote sites === Solar stills are used in cases where rain, piped, or well water is impractical, such as in remote homes or during power outages.<ref name=":2" /> In subtropical [[hurricane]] target areas that can lose power for days, solar distillation can provide an alternative source of clean water. Solar-powered desalination systems can be installed in remote locations where there is little or no infrastructure or energy grid. Solar is still affordable, eco-friendly, and considered an effective method amongst other conventional distillation techniques. Solar still is very effective, especially for supplying fresh water for islanders. This makes them ideal for use in rural areas or developing countries where access to clean water is limited. <ref>Özcan, Y., & Deniz, E. (2023). Solar thermal waste heat energy recovery in solar distillation systems by using thermoelectric generators. Engineering Science and Technology, an International Journal, 40, 101362. https://doi.org/10.1016/j.jestch.2023.101362</ref> <ref>Mohaisen, H. S., Esfahani, J. A., & Ayani, M. B. (2021). Improvement in the performance and cost of passive solar stills using a finned-wall/built-in condenser: An experimental study. Renewable Energy, 168, 170-180.</ref> === Survival === Solar stills have been used by ocean-stranded pilots and included in life raft emergency kits.<ref name=":0" /> Using a condensation trap to [[distillation|distill]] urine will remove the urea and salt, recycling the body's water.<ref>{{cite book |last=Grantham|first=Donald F.|date=March 2, 2001|title=A Source of Wilderness Novice Survival Skills|publisher=Xlbris Corp|page=119|isbn=0738836826}}</ref> === Wastewater treatment === Solar stills have also been used for the [[Wastewater treatment|treatment of municipal wastewater]],<ref>R. Zarasvand Asadi, F. Suja, M.H. Ruslan, N.A. Jalil The application of a solar still in domestic and industrial wastewater treatment. (2013) Sol. Energy, 93, pp. 63-71, https://doi.org/10.1016/j.solener.2013.03.024</ref> the dewatering of sewage sludge <ref>D.A. Haralambopoulos, G. Biskos, C. Halvadakis, T.D. Lekkas (2022) Dewatering of wastewater sludge through a solar still. Renew. Energy, 26, pp. 247-256, https://doi.org/10.1016/S0960-1481(01)00114-8as</ref> as well as for olive mill wastewater management.<ref>{{Cite journal|last1=Mastoras|first1=Petros|last2=Vakalis|first2=Stergios|last3=Fountoulakis|first3=Michail S.|last4=Gatidou|first4=Georgia|last5=Katsianou|first5=Panagiota|last6=Koulis|first6=Georgios|last7=Thomaidis|first7=Nikolaos S.|last8=Haralambopoulos|first8=Dias|last9=Stasinakis|first9=Athanasios S.|date=2022-09-10|title=Evaluation of the performance of a pilot-scale solar still for olive mill wastewater treatment|url=https://www.sciencedirect.com/science/article/pii/S0959652622022934|journal=Journal of Cleaner Production|language=en|volume=365|pages=132695|doi=10.1016/j.jclepro.2022.132695|bibcode=2022JCPro.36532695M |s2cid=249722738 |issn=0959-6526|url-access=subscription}}</ref> ==Ion occurrence mechanism in distilled water from a solar still== Research indicates that ions such as {{chem2|F⁻}} and {{chem2|NO3-}} can be present in distillates from solar stills. Imaging and distillation experiments were performed to investigate this phenomenon.<ref>{{cite journal|last1=Balakrishnan|first1=Ramesh|last2=Sankannavar|first2=Ravi|last3=Rao|first3=K. Kesava|date=1 June 2011|title=A Mechanism for the Occurrence of Ions in Distilled Water|journal=Industrial & Engineering Chemistry Research|volume=50|issue=23|pages=13202–13209|doi=10.1021/ie2002022 }}</ref> White dots were observed in the vapor space above the interface of hot water poured into containers. The concentrations of ions such as {{chem2|F⁻}} and {{chem2|SO4(2-)}} in distillates from both thermal and solar distillation experiments were found to be similar when using deionized water as well as fluoride solutions with concentrations of 100 and 10,000 mg/L. These findings suggest that aerosols enter the distillation system through leaks, acting as nuclei for water vapor condensation. The water-soluble components of aerosols dissolve in the forming droplets, some of which are carried into the distillate by buoyancy-driven convection. == See also == {{Div col|small=yes}} * [[Concentrated solar still]] * [[Desalination]] * [[Freshwater]] * [[Mária Telkes]] * [[Solar cooker]] * [[Solar water disinfection]] * [[Steven Callahan]] * [[Watermaker]] * [[Wikiversity:Water|Wikiversity:Solar Seawater Still]] {{Div col end}} == References == {{Reflist}} ==Patents== * {{cite patent|country=US|number=3337418|title=Pneumatic solar still}} * {{cite patent|country=US|number=4235679|title=High performance solar still}} * {{cite patent|country=US|number=4966655|title=Plastic covered solar still}} ==External links== * [http://www.desertusa.com/mag98/dec/stories/water.html Making a solar still] * [https://web.archive.org/web/20130923232246/http://theenergylibrary.com/node/11693 Solar distillation] {{DEFAULTSORT:Solar Still}} [[Category:Distillation]] [[Category:Water technology]] [[Category:Water treatment]] [[Category:Solar power]] [[Category:Survival skills]]
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