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Ullmannite
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{{Short description|Nickel antimony sulfide mineral}} {{Other uses|Nickel glance (disambiguation)}} {{Infobox mineral | name = Ullmannite | category = [[Sulfide mineral]] | boxwidth = | boxbgcolor = | image = Ullmannite - Mt Narba - Sardinia.JPG | imagesize = 260px | caption = | formula = [[nickel|Ni]][[antimony|Sb]][[sulfur|S]] | IMAsymbol = Ull<ref>{{Cite journal|last=Warr|first=L.N.|date=2021|title=IMA–CNMNC approved mineral symbols|journal=Mineralogical Magazine|volume=85|issue=3|pages=291–320|doi=10.1180/mgm.2021.43|bibcode=2021MinM...85..291W|s2cid=235729616|doi-access=free}}</ref> | strunz = 2.EB.25 | system = [[cubic crystal system|Cubic]] | class = Tetartoidal (23) <br/>[[H-M symbol]]: (23) | symmetry = ''P''2<sub>1</sub>3 | unit cell = a = 5.91(2) Å; Z = 4 | molweight = | color = Steel-gray to tin white | habit = | twinning = Penetration twins about [110] | cleavage = Perfect on {001} | fracture = Uneven | tenacity = Brittle | mohs = 5–5.5 | luster = metallic | streak = | diaphaneity = Opaque | gravity = 6.65–6.85 | density = | polish = | opticalprop = | refractive = | birefringence = | pleochroism = | 2V = | dispersion = | extinction = | length fast/slow = | fluorescence= | absorption = | melt = | fusibility = | diagnostic = | solubility = | other = | alteration = | references = <ref name=HBM>[http://rruff.geo.arizona.edu/doclib/hom/ullmannite.pdf Handbook of Mineralogy]</ref><ref name=Webmin>[http://webmineral.com/data/Ullmannite.shtml Webmineral data]</ref><ref name=Mindat>[http://www.mindat.org/show.php?id=4086&ld=1&pho= Mindat with location data]</ref> }} '''Ullmannite''' or ''Nickel glance'' ([[trivial name]]) is a [[nickel]] [[antimony]] [[sulfide]] [[mineral]] with formula: NiSbS. Considerable substitution occurs with [[cobalt]] and [[iron]] in the nickel site along with [[bismuth]] and [[arsenic]] in the antimony site. A [[solid solution]] series exists with the high cobalt [[willyamite]]. ==Physical properties== Ullmannite is steel-gray to tin white in color with a metallic luster, has a [[Mohs hardness]] of 5 to 5.5 and a [[specific gravity]] of 6.65. Initially thought to be of two species, tetrahedral and cubic, it was later confirmed that both samples conformed to the 23 point group of the [[cubic (crystal system)|isometric crystal class]] and typically exhibits cubic, octahedral, or pyritohedral forms although euhedral crystals are rare.<ref name="Miers-1891">{{cite journal |last=Miers |first=A.H. |year=1891 |title=The Tetardohedrism of Ullmannite. |journal=Mineralogical Magazine |volume=9 |issue=43 |pages=211–213 |doi=10.1180/minmag.1891.009.43.03|bibcode=1891MinM....9..211M }}</ref> Variance in its chemical composition has been shown to be responsible for loss of symmetry and variations in striation patterns.<ref name="Takeuchi-1957">{{cite journal |last=Takeuchi |first=Y. |year=1957 |title=The Absolute Structure of Ullmannite, NiSbS. |journal=Mineralogical Journal |volume=2 |issue=2 |pages=90–102 |url=http://www.journalarchive.jst.go.jp/english/jnlabstract_en.php?cdjournal=minerj1953&cdvol=2&noissue=2&startpage=90 |doi=10.2465/minerj1953.2.90 |bibcode=1957MinJ....2...90T |doi-access=free }}{{Dead link|date=May 2024 |bot=InternetArchiveBot |fix-attempted=yes }}</ref> Ullmannite crystals are usually less than 2 mm, however larger have been identified in especially antimony rich environments.<ref name="Zhu-2010">{{cite journal |last=Zhu |first=Y. |author2=An, F. |year=2010 |title=Native Antimony in the Baogutu gold deposit( West Junggar, NW China): Its occurrence and origin |journal=Ore Geology Reviews |volume=37 |issue=3–4 |pages=214–223 |doi=10.1016/j.oregeorev.2010.03.005|bibcode=2010OGRv...37..214A }}</ref> Ullmannite commonly displays interpenetration twins as well as enantiomorphic twinning along [110].<ref name=HBM/> ==Occurrence== [[File:Ullmannite-169966.jpg|thumb|left|Ullmannite crystals from the Masaloni Mine, San Vito, Cagliari Province, Sardinia, Italy (size: 5.4 × 3.3 × 2.1 cm)]] It is a member of the [[cobaltite]] group and forms a series with [[willyamite]] ({{chem2|(Co,Ni)SbS}}). It occurs with [[nickeline]], [[gersdorffite]], [[pentlandite]], [[chalcopyrite]], [[pyrrhotite]], [[galena]], [[tetrahedrite]] and [[dyscrasite]] in [[hydrothermal]] deposits.<ref name=HBM/> Principal localities are in [[Germany]], it is also found in [[Austria]], [[Australia]], [[France]], [[England]], and [[Wales]]. It was first described in 1843 for an occurrence in the Storch und Schöneberg Mine, [[North Rhine-Westphalia]], Germany.<ref name=Mindat/> Specimens of ullmannite were found at [[Sarrabus]], [[Sardinia]], Italy in 1887. The crystals of the specimens from Sarrabus were described as [[hemipolyhedron|hemihedral]] with parallel faces, whereas specimens from [[Lölling]] in present-day Austria were hemihedral with inclined faces.<ref name="Klein-1888">{{cite journal |last=Klein |first=C. |author2=P. Jannasch |year=1888 |title=Ullmannite from Lölling and from Sarrabus. (''Jahrb. F. Min.'', 1887, ii, Mem., 169–173) |journal=Journal of the Chemical Society, Abstracts |volume=54 |page=31 |url=https://books.google.com/books?id=ldY4AAAAMAAJ&dq=Sarrabus&pg=PA31 |access-date=December 23, 2010}}</ref> ==Origin of name== Ullmannite was named for German [[chemist]] and [[mineralogist]], [[Johann Christoph Ullmann]] (1771–1821), one of the fathers of systematic mineralogy. Ullmann established a mineral collection (now the basis for the internationally renowned Museum of Mineralogy in Marburg<ref>{{cite web | url=http://www.uni-marburg.de/fb19/minmus | title=Geographie }}</ref>) and authored ''Ein Systematisch-Tabellarische Übersicht der Mineralogisch einfachen Fossilien'', one of the first attempts to provide a structured organization to the observed minerals of the day. ==See also== *[[List of minerals]] *[[List of minerals named after people]] ==References== {{Reflist}} * Palache, C., H. Berman, and C. Frondel (1944) ''Dana’s system of mineralogy'', (7th edition), v. I, 301–302. {{Commons category|Ullmannite}} {{Antimonides}} [[Category:Nickel minerals]] [[Category:Antimonide minerals]] [[Category:Sulfide minerals]] [[Category:Cubic minerals]] [[Category:Glances]] [[Category:Minerals in space group 198]] [[Category:Minerals described in 1843]]
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