Aliphatic compound

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File:Butan Lewis.svg
Acyclic aliphatic/non-aromatic compound (butane)
File:Cyclobutane2.svg
Cyclic aliphatic/non-aromatic compound (cyclobutane)

In organic chemistry, hydrocarbons (compounds composed solely of carbon and hydrogen) are divided into two classes: aromatic compounds and aliphatic compounds (Template:IPAc-en; G. aleiphar, fat, oil). Aliphatic compounds can be saturated (in which all the C-C bonds are single, requiring the structure to be completed, or 'saturated', by hydrogen) like hexane, or unsaturated, like hexene and hexyne. Open-chain compounds, whether straight or branched, and which contain no rings of any type, are always aliphatic. Cyclic compounds can be aliphatic if they are not aromatic.<ref>Template:GoldBookRef</ref>

StructureEdit

Aliphatics compounds can be saturated, joined by single bonds (alkanes), or unsaturated, with double bonds (alkenes) or triple bonds (alkynes). If other elements (heteroatoms) are bound to the carbon chain, the most common being oxygen, nitrogen, sulfur, and chlorine, it is no longer a hydrocarbon, and therefore no longer an aliphatic compound. However, such compounds may still be referred to as aliphatic if the hydrocarbon portion of the molecule is aliphatic, e.g. aliphatic amines, to differentiate them from aromatic amines.

The least complex aliphatic compound is methane (CH4).

PropertiesEdit

Most aliphatic compounds are flammable, allowing the use of hydrocarbons as fuel, such as methane in natural gas for stoves or heating; butane in torches and lighters; various aliphatic (as well as aromatic) hydrocarbons in liquid transportation fuels like petrol/gasoline, diesel, and jet fuel; and other uses such as ethyne (acetylene) in welding.

Examples of aliphatic compoundsEdit

The most important aliphatic compounds are:

  • n-, iso- and cyclo-alkanes (saturated hydrocarbons)
  • n-, iso- and cyclo-alkenes and -alkynes (unsaturated hydrocarbons).

Important examples of low-molecular aliphatic compounds can be found in the list below (sorted by the number of carbon-atoms):

Formula Name Structural formula Chemical classification
Template:Chem2 Methane File:Methane-2D-stereo.svg Alkane
Template:Chem2 Acetylene File:Ethyne-2D-flat.png Alkyne
Template:Chem2 Ethylene File:Ethene structural.svg Alkene
Template:Chem2 Ethane File:Ethan Lewis.svg Alkane
Template:Chem2 Propadiene File:Structural formula of propadiene.svg Diene
Template:Chem2 Propyne File:Propyne-2D-flat.png Alkyne
Template:Chem2 Propylene File:Propene Structural Formula V1.svg Alkene
Template:Chem2 Propane File:Propan Lewis.svg Alkane
Template:Chem2 1,2-Butadiene File:Buta-1,2-dien.svg Diene
Template:Chem2 1-Butyne File:Ethylacetylene.svg Alkyne
Template:Chem2 1-Butene File:1-Butene.svg Alkene
Template:Chem2 Butane File:Butan Lewis.svg Alkane
Template:Chem2 Pentane File:Pentan Skelett.svg Alkane
Template:Chem2 Cyclohexene File:Cyclohexen - Cyclohexene.svg Cycloalkene
Template:Chem2 Cyclohexane File:Cyclohexane simple.svg Cycloalkane
Template:Chem2 Hexane File:Hexan Skelett.svg Alkane
Template:Chem2 Methylcyclohexane File:Methylcyclohexane.svg Cycloalkane
Template:Chem2 Cubane File:Cuban.svg Prismane, Platonic hydrocarbon
Template:Chem2 Octane File:Octan Skelett.svg Alkane
Template:Chem2 Dicyclopentadiene File:Di-Cyclopentadiene ENDO & EXO V.2.svg Diene, Cycloalkene
Template:Chem2 Terpinene File:Alpha-Terpinene.svgFile:Beta-Terpinene.svg Terpene, Diene, Cycloalkene
Template:Chem2 Phellandrene File:Phellandrene alpha.svgFile:Phellandrene beta.svg Terpene, Diene, Cycloalkene
Template:Chem2 Limonene File:(R)-Limonen.svgFile:(S)-Limonen.svg Terpene, Diene, Cycloalkene
Template:Chem2 Decane File:Decan Skelett.svg Alkane
Template:Chem2 Squalene File:Squalene.svg Terpene, Polyene
Template:Chem2 Polyethylene File:Polyethylene repeat unit.svg Alkane

ReferencesEdit

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