List of thermodynamic properties

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In thermodynamics, a physical property is any property that is measurable, and whose value describes a state of a physical system. Thermodynamic properties are defined as characteristic features of a system, capable of specifying the system's state. Some constants, such as the ideal gas constant, Template:Mvar, do not describe the state of a system, and so are not properties. On the other hand, some constants, such as Template:Mvar (the freezing point depression constant, or cryoscopic constant), depend on the identity of a substance, and so may be considered to describe the state of a system, and therefore may be considered physical properties.

"Specific" properties are expressed on a per mass basis. If the units were changed from per mass to, for example, per mole, the property would remain as it was (i.e., intensive or extensive).

Regarding work and heatEdit

Work and heat are not thermodynamic properties, but rather process quantities: flows of energy across a system boundary. Systems do not contain work, but can perform work, and likewise, in formal thermodynamics, systems do not contain heat, but can transfer heat. Informally, however, a difference in the energy of a system that occurs solely because of a difference in its temperature is commonly called heat, and the energy that flows across a boundary as a result of a temperature difference is "heat".

Altitude (or elevation) is usually not a thermodynamic property. Altitude can help specify the location of a system, but that does not describe the state of the system. An exception would be if the effect of gravity need to be considered in order to describe a state, in which case altitude could indeed be a thermodynamic property.

Thermodynamic properties and their characteristics
Property Symbol Units Extensive? Intensive? Conjugate Potential?
Activity Template:Mvar Template:Spaced ndash Template:Aye
Chemical potential Template:Mvar kJ/mol Template:Aye Particle
number Template:Mvar
Compressibility (adiabatic) Template:Mvar, Template:Mvar Pa−1 Template:Aye
Compressibility (isothermal) Template:Mvar, Template:Mvar Pa−1 Template:Aye
Cryoscopic constant<ref>Template:Citation</ref> Template:Mvar K·kg/mol Template:Aye
Density Template:Mvar kg/m3 Template:Aye
Ebullioscopic constant Template:Mvar K·kg/mol Template:Aye
Enthalpy Template:Mvar J Template:Aye Template:Aye
Template:Space Specific enthalpy Template:Mvar J/kg Template:Aye
Entropy Template:Mvar J/K Template:Aye Temperature Template:Mvar Template:Aye (entropic)
Template:Space Specific entropy Template:Mvar J/(kg K) Template:Aye
Fugacity Template:Mvar N/m2 Template:Aye
Gibbs free energy Template:Mvar J Template:Aye Template:Aye
Template:Space Specific Gibbs free energy Template:Mvar J/kg Template:Aye
Gibbs free entropy Template:Math J/K Template:Aye Template:Aye (entropic)
Grand / Landau potential Template:Math J Template:Aye Template:Aye
Heat capacity (constant pressure) Template:Mvar J/K Template:Aye
Template:Space Specific heat capacity
Template:Space(constant pressure)
Template:Mvar J/(kg·K) Template:Aye
Heat capacity (constant volume) Template:Mvar J/K Template:Aye
Template:Space Specific heat capacity
Template:Space(constant volume)
Template:Mvar J/(kg·K) Template:Aye
Helmholtz free energy Template:Mvar, Template:Mvar J Template:Aye Template:Aye
Helmholtz free entropy Template:Math J/K Template:Aye Template:Aye (entropic)
Internal energy Template:Mvar J Template:Aye Template:Aye
Template:Space Specific internal energy Template:Mvar J/kg Template:Aye
Internal pressure Template:Mvar Pa Template:Aye
Mass Template:Mvar kg Template:Aye
Particle number Template:Mvar Template:Spaced ndash Template:Aye Chemical
potential Template:Mvar
Pressure Template:Mvar Pa Template:Aye Volume Template:Mvar
Temperature Template:Mvar K Template:Aye Entropy Template:Mvar
Thermal conductivity Template:Mvar W/(m·K) Template:Aye
Thermal diffusivity Template:Mvar m2/s Template:Aye
Thermal expansion (linear) Template:Mvar K−1 Template:Aye
Thermal expansion (area) Template:Mvar K−1 Template:Aye
Thermal expansion (volumetric) Template:Mvar K−1 Template:Aye
Vapor quality<ref name=boles>Template:Cite book</ref> Template:Mvar Template:Spaced ndash Template:Aye
Volume Template:Mvar m3 Template:Aye Pressure Template:Mvar
Template:Spaces Specific volume Template:Mvar m3/kg Template:Aye

See alsoEdit

ReferencesEdit

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