Template:Short description Template:About Template:Distinguish Template:Infobox mineral Wurtzite is a zinc and iron sulfide mineral with the chemical formula Template:Chem2, a less frequently encountered structural polymorph form of sphalerite. The iron content is variable up to eight percent.<ref name=Dana>Palache, Charles, Harry Berman & Clifford Frondel (1944), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume I: Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, Inc., New York. 7th edition, revised and enlarged, pp. 226-228.</ref> It is trimorphous with matraite and sphalerite.<ref name=Handbook/>

It occurs in hydrothermal deposits associated with sphalerite, pyrite, chalcopyrite, barite and marcasite. It also occurs in low-temperature clay-ironstone concretions.<ref name=Handbook/>

It was first described in 1861 for an occurrence in the San José Mine, Oruro City, Cercado Province, Oruro Department, Bolivia, and named for French chemist Charles-Adolphe Wurtz.<ref name=Mindat/> It has widespread distribution. In Europe it is reported from Příbram, Czech Republic; Hesse, Germany; and Liskeard, Cornwall, England. In the US it is reported from Litchfield County, Connecticut; Butte, Silver Bow County, Montana; at Frisco, Beaver County, Utah; and from the Joplin district, Jasper County, Missouri.<ref name=Handbook/>

StructureEdit

File:Wurtzite.png
Wurtzite unit cell. The grey balls represent metal atoms, and yellow balls represent sulfur or selenium atoms.

The wurtzite group includes cadmoselite (CdSe), greenockite (CdS), mátraite (ZnS), and rambergite (MnS), in addition to wurtzite.<ref>Wurtzite group on Mindat.org</ref>

Its crystal structure is called the wurtzite crystal structure, to which it lends its name. This structure is a member of the hexagonal crystal system and consists of tetrahedrally coordinated zinc and sulfur atoms that are stacked in an ABABABABAB pattern.

The unit cell parameters of wurtzite are (-2H polytype):<ref>Template:Cite journal</ref>

  • a = b = 3.81 Å = 381 pm
  • c = 6.23 Å = 623 pm
  • V = 78.41 Å3
  • Z = 2

See alsoEdit

ReferencesEdit

Template:Reflist

External linksEdit

ja:閃亜鉛鉱#ウルツ鉱